多级孔分子筛的合成研究进展
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摘要
多级孔分子筛由于其高的外比表面积、良好的传热及扩散性能,在重油裂化、异丙苯制备、加氢异构化等催化反应中显示出优良的性能。综述近年来多级孔分子筛的合成进展,着重介绍多级孔分子筛的合成方法、合成机理及性质特点。
Molecular sieves with hierarchical porosity have exhibited excellent catalysis performance in heavy oil cracking,cumene production,and alkane hydroisomerization and so on,for its high external surface area,good heat transfer performance and short diffusion path lengths. Advances in synthesis of molecular sieves with hierarchical porosity,mainly in synthesis method,synthesis mechanism,characterization of hierarchical molecular sieves were introduced.
Molecular sieves with hierarchical porosity have exhibited excellent catalysis performance in heavy oil cracking,cumene production,and alkane hydroisomerization and so on,for its high external surface area,good heat transfer performance and short diffusion path lengths. Advances in synthesis of molecular sieves with hierarchical porosity,mainly in synthesis method,synthesis mechanism,characterization of hierarchical molecular sieves were introduced.
引文
[1]Corma A. From microporous to mesoporous molecular sieve materials and their use in catalysis[J]. Chemical Reviews,1997,97(6):2373-2420.
[2]Davis M E. Ordered porous materials for emerging applications[J]. Nature,2002,417:813-821.
[3]Chen N Y,Smith C M. Molecular transport and reaction in zeolite[M]. New York:Wiley-VCH,1994.
[4]Tosheva L,Valtchev V P. Nanozeolites:synthesis,crystallization mechanism,and applications[J]. Chemistry of Materials,2005,17(10):2494-2513.
[5]Li C G,Lu Q,Wu H H,et al. A hierarchically core/shellstructured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes[J]. Chemical Communications,2015,51(80):14905-14908.
[6]Kresge C T,Leonowicz M E,Roth W J,et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J]. Nature,1992,359(6397):710-712.
[7]Verhoef M J,Kooyman P J,van der Waal J C,et al. Partial transformation of MCM-41 material into zeolites:formation of nanosized MFI type crystallites[J]. Chemistry of Materials,2001,13(2):683-687.
[8]Trong On D,Kaliaguine S. Ultrastable and highly acidic,zeolite-coated mesoporous aluminosilicates[J]. Angewandte Chemie International Edition,2002,41(6):1036-1040.
[9]Liu Y,Zhang W,Pinnavaia T J. MSU-S aluminosilicate mesostructures assembled from zeolite ZSM-5 and zeolite Beta seeds[J]. Angewandte Chemie International Edition,2001,40(7):1255-1258.
[10]Xiao F S,Han Y,Yu Y,et al. Hydrothermally stable ordered mesoporous titanosilicates with highly active catalytic sites[J]. Journal of the American Chemical Society,2002,124(6):888-889.
[11]Kloetstra K R,Zandbergen H W,Jansen J C,et al. Overgrowth of mesoporous MCM-41 on faujasite[J]. Microporous Materials,1996,6(5/6):287-293.
[12]Guo W,Huang L,Deng P,et al. Characterization of Beta/MCM-41 composites molecular sieve compared with the mechanical mixture[J]. Microporous and Mesoporous Materials,2001,44-45(6):427-434..
[13]Pinilla-Herrero I,Márquez-álvarez C,Sastre E. Methanol-to-olefin reaction on SAPO-35 catalysts synthesized with controlled crystal size and using mesoporogen additives[J]. Catalysis Today,2016,277:29-36.
[14]Tao S,Li X,Gong H,et al. Confined-space synthesis of hierarchical MgAPO-11 molecular sieves with good hydroisomerization performance[J]. Microporous&Mesoporous Materials,2018,262:182-190.
[15]Boisen A,Schmidt I,Carlsson A,et al. TEM stereo-imaging of mesoporous zeolite single crystals[J]. Chemical Communications,2003,(8):958-959.
[16]Janssen A H,Schmidt I,Jacobsen C J H,et al. Exploratory study of mesopore templating with carbon during zeolite synthesis[J]. Microporous and Mesoporous Materials,2003,65(1):59-75.
[17]Yang Z,Xia Y,Mokaya R. Zeolite ZSM-5 with unique supermicropores synthesized using mesoporous carbon as a template[J]. Advanced Materials,2004,16(8):727-732.
[18]Tao Y,Kanoh H,Kaneko K. Uniform mesopore-donated zeolite Y using carbon aerogel templating[J]. Journal of Physical Chemistry B,2003,107(40):10974-10976.
[19]Naydenov V,Tosheva L,Antzutkin Oleg N,et al. Meso/macroporous Al PO4-5 spherical macrostructures tailored by resin templating[J]. Microporous and Mesoporous Materials,2005,78(2/3):181-188.
[20]Valtchev V P,Smaihi M,Faust A C,et al. Equisetum arvense templating of zeolite Beta macrostructures with hierarchical porosity[J]. Chemistry of Materials,2004,16(7):1350-1355.
[21]Xiao F S,Wang L F,Yin C Y,et al. Catalytic properties of hierarchical mesoporous zeolites templated with a mixture of small organic ammonium salts and mesoscale cationic polymers[J]. Angewandte Chemie International Edition,2006,45(19):3090-3093.
[22]李玉平,孙翠娟,贾坤,等.软模板导向合成多级孔丝光沸石及其苯的苄基化催化性能[J].无机材料学报,2016,31(12):1355-1362.Li Yuping,Sun Cuijuan,Jia Kun,et al. Soft templatedirected hierarchical mordenites and their performance in benzylation of benzene with benzyl alcohol[J]. Journal of Inorganic Materials,2016,31(12):1355-1362.
[23]Wang H,Pinnavaia T J. MFI zeolite with small and uniform intracrystal mesopores[J]. Angewandte Chemie International Edition,2006,45(45):7603-7606.
[24]Choi M,Cho H S,Srivastava R,et al. Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity[J]. Nature Materials,2006,5(9):718-723.
[25]Dong A,Wang Y,Tang Y,et al. Hollow zeolite capsules:a novel approach for fabrication and guest encapsulation[J]. Chemistry of Materials,2002,14(8):3217-3219.
[26]Song W,Kanthasamy R,Grassian V H,et al. Hexagonal,hollow,aluminium-containing ZSM-5 tubes prepared from mesoporous silica templates[J]. Chemical Communications,2004,(17):1920-1921.
[27]Gao Y,Wu G,Ma F,et al. Modified seeding method for preparing hierarchical nanocrystalline ZSM-5 catalysts for methanol aromatization[J]. Microporous&Mesoporous Materials,2016,226:251-259.
[28]Serrano D P,Aguado J,Escola J M,et al. Hierarchical zeolites with enhanced textural and catalytic properties synthesized from organofunctionalized seeds[J]. Chemistry of Materials,2006,18(10):2462-2464.
[29]Corma A. From microporous to mesoporous molecular sieve materials and their use in catalysis[J]. Chemical Reviews,1997,(97):2373-2419.
[30]Li X M,Yan Z F. Optimization of nanopores and acidity of USY zeolite by citric modification[J]. Catalysis Today,2001,68(1/3):145-154.
[31]覃正兴,申宝剑.水热处理过程中Y分子筛的骨架脱铝、补硅及二次孔的形成[J].化工学报,2016,67(8):3160-3169.Qin Zhengxing,Shen Baojian. Dealumination,silicon reinsertion,and secondary pore formation in steaming of zeolite Y[J]. CIESC Jorunal,2016,67(8):3160-3169.
[32]孙书红,黄校亮,郑云锋,等.柠檬酸改性Y型分子筛的研究[J].石化技术与应用,2018,36(2):83-87.Sun Shuhong,Huang Xiaoliang,Zheng Yunfeng,et al.Research of Y type molecular sieve modified by citric acid[J]. Petrochemical Technology&Application,2018,36(2):83-87.
[33]Verboekend D,Chabaneix A M,Thomas K,et al. Mesoporous ZSM-22 zeolite obtained by desilication:peculiarities associated with crystal morphology and aluminium distribution[J]. Crystengcomm,2011,13(10):3408-3416.
[34]Sadowska K,Wach A,Olejniczak Z,et al. Hierarchic zeolites:zeolite ZSM-5 desilicated with Na OH and Na OH/tetrabutylamine hydroxide[J]. Microporous&Mesoporous Materials,2013,167(3):82-88.
[35]Fu T,Qi R,Wang X,et al. Facile synthesis of nanosized hollow ZSM5 zeolites with rich mesopores in shell[J].Microporous&Mesoporous Materials,2017,250:43-46.
[36]Groen J C,Moulijn J A,Pe'rez-Ram!'rez J. Decoupling mesoporosity formation and acidity modification in ZSM-5zeolites by sequential desilication-dealumination[J].Microporous&Mesoporous Materials,2005,87(2):153-161.
[37]申宝剑,覃正兴,高雄厚,等.碱处理脱硅与提高Y型分子筛硅铝比——矛盾的对立与统一[J].催化学报,2012,33(1):152-163.Shen Baojian,Qin Zhengxing,Gao Xionghou,et al. Desilication by alkaline treatment and increasing the silica to alumina ratio of zeolite Y[J]. Chinese Journal of Catalysis,2012,33(1):152-163.
[38]Kasyanov I,Maerle A,Ivanova I,et al. Towards understanding ov the mechanism of stepwise zeolite recrystallization into micro/mesoporous materials[J]. Journal of Materials Chemistry A,2014,2(40):16978-16988.
[39]Guo D,Shen B,Qi G,et al. Unstable-Fe-site-induced formation of mesopores in microporous zeolite Y without using organic templates[J]. Chemical Communications,2014,50(20):2660-2663.
[2]Davis M E. Ordered porous materials for emerging applications[J]. Nature,2002,417:813-821.
[3]Chen N Y,Smith C M. Molecular transport and reaction in zeolite[M]. New York:Wiley-VCH,1994.
[4]Tosheva L,Valtchev V P. Nanozeolites:synthesis,crystallization mechanism,and applications[J]. Chemistry of Materials,2005,17(10):2494-2513.
[5]Li C G,Lu Q,Wu H H,et al. A hierarchically core/shellstructured titanosilicate with multiple mesopore systems for highly efficient epoxidation of alkenes[J]. Chemical Communications,2015,51(80):14905-14908.
[6]Kresge C T,Leonowicz M E,Roth W J,et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J]. Nature,1992,359(6397):710-712.
[7]Verhoef M J,Kooyman P J,van der Waal J C,et al. Partial transformation of MCM-41 material into zeolites:formation of nanosized MFI type crystallites[J]. Chemistry of Materials,2001,13(2):683-687.
[8]Trong On D,Kaliaguine S. Ultrastable and highly acidic,zeolite-coated mesoporous aluminosilicates[J]. Angewandte Chemie International Edition,2002,41(6):1036-1040.
[9]Liu Y,Zhang W,Pinnavaia T J. MSU-S aluminosilicate mesostructures assembled from zeolite ZSM-5 and zeolite Beta seeds[J]. Angewandte Chemie International Edition,2001,40(7):1255-1258.
[10]Xiao F S,Han Y,Yu Y,et al. Hydrothermally stable ordered mesoporous titanosilicates with highly active catalytic sites[J]. Journal of the American Chemical Society,2002,124(6):888-889.
[11]Kloetstra K R,Zandbergen H W,Jansen J C,et al. Overgrowth of mesoporous MCM-41 on faujasite[J]. Microporous Materials,1996,6(5/6):287-293.
[12]Guo W,Huang L,Deng P,et al. Characterization of Beta/MCM-41 composites molecular sieve compared with the mechanical mixture[J]. Microporous and Mesoporous Materials,2001,44-45(6):427-434..
[13]Pinilla-Herrero I,Márquez-álvarez C,Sastre E. Methanol-to-olefin reaction on SAPO-35 catalysts synthesized with controlled crystal size and using mesoporogen additives[J]. Catalysis Today,2016,277:29-36.
[14]Tao S,Li X,Gong H,et al. Confined-space synthesis of hierarchical MgAPO-11 molecular sieves with good hydroisomerization performance[J]. Microporous&Mesoporous Materials,2018,262:182-190.
[15]Boisen A,Schmidt I,Carlsson A,et al. TEM stereo-imaging of mesoporous zeolite single crystals[J]. Chemical Communications,2003,(8):958-959.
[16]Janssen A H,Schmidt I,Jacobsen C J H,et al. Exploratory study of mesopore templating with carbon during zeolite synthesis[J]. Microporous and Mesoporous Materials,2003,65(1):59-75.
[17]Yang Z,Xia Y,Mokaya R. Zeolite ZSM-5 with unique supermicropores synthesized using mesoporous carbon as a template[J]. Advanced Materials,2004,16(8):727-732.
[18]Tao Y,Kanoh H,Kaneko K. Uniform mesopore-donated zeolite Y using carbon aerogel templating[J]. Journal of Physical Chemistry B,2003,107(40):10974-10976.
[19]Naydenov V,Tosheva L,Antzutkin Oleg N,et al. Meso/macroporous Al PO4-5 spherical macrostructures tailored by resin templating[J]. Microporous and Mesoporous Materials,2005,78(2/3):181-188.
[20]Valtchev V P,Smaihi M,Faust A C,et al. Equisetum arvense templating of zeolite Beta macrostructures with hierarchical porosity[J]. Chemistry of Materials,2004,16(7):1350-1355.
[21]Xiao F S,Wang L F,Yin C Y,et al. Catalytic properties of hierarchical mesoporous zeolites templated with a mixture of small organic ammonium salts and mesoscale cationic polymers[J]. Angewandte Chemie International Edition,2006,45(19):3090-3093.
[22]李玉平,孙翠娟,贾坤,等.软模板导向合成多级孔丝光沸石及其苯的苄基化催化性能[J].无机材料学报,2016,31(12):1355-1362.Li Yuping,Sun Cuijuan,Jia Kun,et al. Soft templatedirected hierarchical mordenites and their performance in benzylation of benzene with benzyl alcohol[J]. Journal of Inorganic Materials,2016,31(12):1355-1362.
[23]Wang H,Pinnavaia T J. MFI zeolite with small and uniform intracrystal mesopores[J]. Angewandte Chemie International Edition,2006,45(45):7603-7606.
[24]Choi M,Cho H S,Srivastava R,et al. Amphiphilic organosilane-directed synthesis of crystalline zeolite with tunable mesoporosity[J]. Nature Materials,2006,5(9):718-723.
[25]Dong A,Wang Y,Tang Y,et al. Hollow zeolite capsules:a novel approach for fabrication and guest encapsulation[J]. Chemistry of Materials,2002,14(8):3217-3219.
[26]Song W,Kanthasamy R,Grassian V H,et al. Hexagonal,hollow,aluminium-containing ZSM-5 tubes prepared from mesoporous silica templates[J]. Chemical Communications,2004,(17):1920-1921.
[27]Gao Y,Wu G,Ma F,et al. Modified seeding method for preparing hierarchical nanocrystalline ZSM-5 catalysts for methanol aromatization[J]. Microporous&Mesoporous Materials,2016,226:251-259.
[28]Serrano D P,Aguado J,Escola J M,et al. Hierarchical zeolites with enhanced textural and catalytic properties synthesized from organofunctionalized seeds[J]. Chemistry of Materials,2006,18(10):2462-2464.
[29]Corma A. From microporous to mesoporous molecular sieve materials and their use in catalysis[J]. Chemical Reviews,1997,(97):2373-2419.
[30]Li X M,Yan Z F. Optimization of nanopores and acidity of USY zeolite by citric modification[J]. Catalysis Today,2001,68(1/3):145-154.
[31]覃正兴,申宝剑.水热处理过程中Y分子筛的骨架脱铝、补硅及二次孔的形成[J].化工学报,2016,67(8):3160-3169.Qin Zhengxing,Shen Baojian. Dealumination,silicon reinsertion,and secondary pore formation in steaming of zeolite Y[J]. CIESC Jorunal,2016,67(8):3160-3169.
[32]孙书红,黄校亮,郑云锋,等.柠檬酸改性Y型分子筛的研究[J].石化技术与应用,2018,36(2):83-87.Sun Shuhong,Huang Xiaoliang,Zheng Yunfeng,et al.Research of Y type molecular sieve modified by citric acid[J]. Petrochemical Technology&Application,2018,36(2):83-87.
[33]Verboekend D,Chabaneix A M,Thomas K,et al. Mesoporous ZSM-22 zeolite obtained by desilication:peculiarities associated with crystal morphology and aluminium distribution[J]. Crystengcomm,2011,13(10):3408-3416.
[34]Sadowska K,Wach A,Olejniczak Z,et al. Hierarchic zeolites:zeolite ZSM-5 desilicated with Na OH and Na OH/tetrabutylamine hydroxide[J]. Microporous&Mesoporous Materials,2013,167(3):82-88.
[35]Fu T,Qi R,Wang X,et al. Facile synthesis of nanosized hollow ZSM5 zeolites with rich mesopores in shell[J].Microporous&Mesoporous Materials,2017,250:43-46.
[36]Groen J C,Moulijn J A,Pe'rez-Ram!'rez J. Decoupling mesoporosity formation and acidity modification in ZSM-5zeolites by sequential desilication-dealumination[J].Microporous&Mesoporous Materials,2005,87(2):153-161.
[37]申宝剑,覃正兴,高雄厚,等.碱处理脱硅与提高Y型分子筛硅铝比——矛盾的对立与统一[J].催化学报,2012,33(1):152-163.Shen Baojian,Qin Zhengxing,Gao Xionghou,et al. Desilication by alkaline treatment and increasing the silica to alumina ratio of zeolite Y[J]. Chinese Journal of Catalysis,2012,33(1):152-163.
[38]Kasyanov I,Maerle A,Ivanova I,et al. Towards understanding ov the mechanism of stepwise zeolite recrystallization into micro/mesoporous materials[J]. Journal of Materials Chemistry A,2014,2(40):16978-16988.
[39]Guo D,Shen B,Qi G,et al. Unstable-Fe-site-induced formation of mesopores in microporous zeolite Y without using organic templates[J]. Chemical Communications,2014,50(20):2660-2663.