XPS技术在生物质材料研究中的应用
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摘要
X射线光电子能谱(XPS)是常用的表面分析技术,可有效的测试材料表面的化学成分、元素含量和元素价态,广泛应用于材料学、表面化学、催化剂、涂层、冶金等领域。文章总结了XPS在竹材、纤维素、生物炭材料等生物质材料表面分析中的应用,为生物质材料的深入研究提供科学的分析测试手段,也为今后拓展仪器的应用领域,在分析技术方面展开深入研究奠定基础。
X-Ray photoelectron spectroscopy( XPS) is a commonly used surface analysis technology,which can effectively test the chemical composition,element content and element valence of materials,and is widely used in materials science,surface chemistry,catalysts,coatings,metallurgy and other fields. The application of XPS in the research of bamboo,cellulose and biochar materials was summarized,and scientific analysis and testing methods were provided for the in-depth study of biomass energy. It also conducted in-depth research on analytical techniques for the foundation of the future application of instrument development.
X-Ray photoelectron spectroscopy( XPS) is a commonly used surface analysis technology,which can effectively test the chemical composition,element content and element valence of materials,and is widely used in materials science,surface chemistry,catalysts,coatings,metallurgy and other fields. The application of XPS in the research of bamboo,cellulose and biochar materials was summarized,and scientific analysis and testing methods were provided for the in-depth study of biomass energy. It also conducted in-depth research on analytical techniques for the foundation of the future application of instrument development.
引文
[1]鲍甫成.发展生物质材料与生物质材料科学[J].林产工业,2008,35(4):3-7.
[2]李家宁,段新芳,周冠武,等.生物质材料生物技术研究进展及展望[J].木材工业,2007,21(3):30-32.
[3] Fadley C S. X-ray photoelectron spectroscopy:Progress and perspectives[J]. Journal of Electron Spectroscopy and Related Phenomena,2010,178:2-32.
[4]黄惠忠.表面化学分析[M].上海:华东理工大学出版社,2007:7-18.
[5]贾贤.材料表面现代分析方法[M].北京:化学工业出版社,2009:105-107.
[6]杜官本,华毓坤.微波等离子体处理木材表面光电子能谱分析[J].林业科学,1999,35(5):104-109.
[7] Gao B, Zhao F, Miao Y, et al. Boron-and nitrogen-doped photoluminescent polymer carbon nanoparticles as nanosensors for imaging detection of Cu2+and biothiols in living cells[J]. RSC Advances,2017,75(7):47654-47661.
[8] Zhao X, Zhao Z, Miao Y. Chloride ion-doped polypyrrole nanocomposite as cathode material for rechargeable magnesium battery[J]. Materials Research Bulletin,2018,101:1-5.
[9]杜官本,杨忠,邱坚,等.微波等离子体活化木材表面的ESR分析[J].林业科技开发,2002,16(3):28-31.
[10]周晓芸.低温等离子体改性后竹材表界面特性的研究[D].南京:南京林业大学,2008.
[11]江泽慧,于文吉,余养伦.竹材化学成分分析和表面性能表征[J].东北林业大学学报,2006,34(4):1-6.
[12]侯伦灯,张齐生,苏团,等.竹重组材的X射线光电子能谱分析[J].林业科技开发,2012,26(1):47-49.
[13]王小青,任海青,赵荣军,等.毛竹材表面光化降解的FTIR和XPS分析[J].光谱学与光谱分析,2009,29(7):1864-1867.
[14]马红霞,江泽慧,任海青,等.漂白和热处理竹材的表面性能[J].林业科学,2010,46(11):131-137.
[15]吴伟兵,庄志良,戴红旗.纳晶纤维素的研究进展[J].中国造纸学报,2013(4):012.
[16]金二锁,杨芳,朱阳阳,等.碱处理后纤维素纳米晶体的XRD,FTIR和XPS分析[J].纤维素科学与技术,2016,24(3):1-6.
[17]潘明珠,周定国,周晓燕,等.聚乙二醇对稻秸纤维/PHBV复合材料性能的影响[J].南京林业大学学报(自然科学版),2014,38(4):123-126.
[18]王鹏,张坚,陈振国,等.基于XPS的纤维素热解焦表面结构分析[J].燃烧科学与技术,2015,21(4):378-381.
[19]何文,李吉平,金辉,等.毛竹纳米纤维素的烷基化改性[J].南京林业大学学报(自然科学版),2016(2):144-148.
[20]洪枢,程明娟,连海兰.[Bmim]Cl/Al Cl3离子液体改性麦草碱木质素的结构特征[J].林产工业,2013(6):29-34.
[21]尤纪雪,王玉秀.漆酶体系酶解马尾松浆表面性能的研究[J].中国造纸学报,2009(3):37-41.
[22]王永芳,左宋林.含磷活性炭作为双电层电容器电极材料的电化学性能[J].物理化学学报,2016,32(2):481-492.
[23]陈继锡,左宋林,王永芳,等.磷酸法活性炭的三聚氰胺表面改性及其电化学性能研究[J].林产化学与工业,2016,36(2):37-44.
[24]吴光前,戴阳,万京林,等.氧等离子体对竹炭表面的改性研究[J].林业工程学报,2016,1(3):48-53.
[25]徐信武,周定国.等离子体改性稻秸的XPS分析[J].南京林业大学学报(自然科学版),2009,33(5):69-72.
[26]邓海君,王权.低温氧等离子体处理对单层石墨烯微观结构影响的研究[J].电子元件与材料,2016,35(2):9-13.
[27] Lai Q,Luo X,Zhu S. Titania nanotube-graphene oxide hybrids with excellent photocatalyticactivities[J]. New Carbon Materials,2016,31(2):121-128.
[2]李家宁,段新芳,周冠武,等.生物质材料生物技术研究进展及展望[J].木材工业,2007,21(3):30-32.
[3] Fadley C S. X-ray photoelectron spectroscopy:Progress and perspectives[J]. Journal of Electron Spectroscopy and Related Phenomena,2010,178:2-32.
[4]黄惠忠.表面化学分析[M].上海:华东理工大学出版社,2007:7-18.
[5]贾贤.材料表面现代分析方法[M].北京:化学工业出版社,2009:105-107.
[6]杜官本,华毓坤.微波等离子体处理木材表面光电子能谱分析[J].林业科学,1999,35(5):104-109.
[7] Gao B, Zhao F, Miao Y, et al. Boron-and nitrogen-doped photoluminescent polymer carbon nanoparticles as nanosensors for imaging detection of Cu2+and biothiols in living cells[J]. RSC Advances,2017,75(7):47654-47661.
[8] Zhao X, Zhao Z, Miao Y. Chloride ion-doped polypyrrole nanocomposite as cathode material for rechargeable magnesium battery[J]. Materials Research Bulletin,2018,101:1-5.
[9]杜官本,杨忠,邱坚,等.微波等离子体活化木材表面的ESR分析[J].林业科技开发,2002,16(3):28-31.
[10]周晓芸.低温等离子体改性后竹材表界面特性的研究[D].南京:南京林业大学,2008.
[11]江泽慧,于文吉,余养伦.竹材化学成分分析和表面性能表征[J].东北林业大学学报,2006,34(4):1-6.
[12]侯伦灯,张齐生,苏团,等.竹重组材的X射线光电子能谱分析[J].林业科技开发,2012,26(1):47-49.
[13]王小青,任海青,赵荣军,等.毛竹材表面光化降解的FTIR和XPS分析[J].光谱学与光谱分析,2009,29(7):1864-1867.
[14]马红霞,江泽慧,任海青,等.漂白和热处理竹材的表面性能[J].林业科学,2010,46(11):131-137.
[15]吴伟兵,庄志良,戴红旗.纳晶纤维素的研究进展[J].中国造纸学报,2013(4):012.
[16]金二锁,杨芳,朱阳阳,等.碱处理后纤维素纳米晶体的XRD,FTIR和XPS分析[J].纤维素科学与技术,2016,24(3):1-6.
[17]潘明珠,周定国,周晓燕,等.聚乙二醇对稻秸纤维/PHBV复合材料性能的影响[J].南京林业大学学报(自然科学版),2014,38(4):123-126.
[18]王鹏,张坚,陈振国,等.基于XPS的纤维素热解焦表面结构分析[J].燃烧科学与技术,2015,21(4):378-381.
[19]何文,李吉平,金辉,等.毛竹纳米纤维素的烷基化改性[J].南京林业大学学报(自然科学版),2016(2):144-148.
[20]洪枢,程明娟,连海兰.[Bmim]Cl/Al Cl3离子液体改性麦草碱木质素的结构特征[J].林产工业,2013(6):29-34.
[21]尤纪雪,王玉秀.漆酶体系酶解马尾松浆表面性能的研究[J].中国造纸学报,2009(3):37-41.
[22]王永芳,左宋林.含磷活性炭作为双电层电容器电极材料的电化学性能[J].物理化学学报,2016,32(2):481-492.
[23]陈继锡,左宋林,王永芳,等.磷酸法活性炭的三聚氰胺表面改性及其电化学性能研究[J].林产化学与工业,2016,36(2):37-44.
[24]吴光前,戴阳,万京林,等.氧等离子体对竹炭表面的改性研究[J].林业工程学报,2016,1(3):48-53.
[25]徐信武,周定国.等离子体改性稻秸的XPS分析[J].南京林业大学学报(自然科学版),2009,33(5):69-72.
[26]邓海君,王权.低温氧等离子体处理对单层石墨烯微观结构影响的研究[J].电子元件与材料,2016,35(2):9-13.
[27] Lai Q,Luo X,Zhu S. Titania nanotube-graphene oxide hybrids with excellent photocatalyticactivities[J]. New Carbon Materials,2016,31(2):121-128.