The 18-electron rule for main-group alkaline earth octacarbonyl complexes

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英文篇名：The 18-electron rule for main-group alkaline earth octacarbonyl complexes 作者：Xueming ; Yang 英文作者：Xueming Yang;Dalian Institute of Chemical Physics, Chinese Academy of Sciences and Department of Chemistry, Southern University of Science and Technology; 中文刊名：NASR 英文刊名：国家科学评论(英文版) 机构：Dalian Institute of Chemical Physics, Chinese Academy of Sciences and Department of Chemistry, Southern University of Science and Technology; 出版日期：2019-01-15 出版单位：National Science Review 年：2019 期：v.6 基金：supported by the National Natural Science Foundation of China(21688102) 语种：英文; 页：NASR201901006 页数：2 CN：01 ISSN：10-1088/N 分类号：14-15

摘要

<正>Elements in the periodic table are classified into s-and p-block main-group elements, d-block transition metals and f-block lanthanides and actinides according to the valence atomic orbitals (AOs).Main-group elements form bonds using their ns and np valence orbitals, following the octet rule—a well-known chemical rule which states that atoms tend to bond in such a way that each atom has a closed-shell 18-electron configuration like noble gases. Besides one ns and three np valence orbitals, transition metals have additional five (n-1)d orbitals. This leads
        

引文

1. Wu X, Zhao LL and Jiang DD et al. Angew Chem Int Ed 2018; 57:3974–80.
    2 . Wu X, Zhao LL and Jin JY et al. Science 2018; 361:912 –6.
    3 . Kaupp M. Angew Chem Int Ed 2001; 40:3534–65.
    4 . Gagliardi L and Pyykko P. Theoretical Chemistry Accounts:Theory, Computation, and Modeling(Theoretica Chimica Acta)2003; 110:205–10.
    5 . Jin J, Yang T and Xin K et al. Angew Chem Int Ed2018; 57:6236–41.