In situ synthesis of potassium tungstophosphate supported on BEA zeolite and perspective application for pesticide removal
|
摘要
Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength.Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application.
Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength.Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application.
Potassium tungstophosphate is supported on BEA zeolite by in situ synthesis for glyphosate removal. Spectroscopic measurements identified hydrogen bonding as a primal interaction of potassium salt and BEA zeolite. Composites are evaluated for glyphosate herbicide removal and adsorption process is analyzed using two isotherm models. Obtained adsorption capacities for all prepared composites lay between 45.2 and 92.2 mg of glyphosate per gram of investigated composite. Suspension acidity revealed that glyphosate is adsorbed mainly in the zwitter-ion form at the composite surface while the amount of potassium salt in the composites is crucial for the adsorption application. Exceptional adsorption behavior is postulated to come from a high degree of homogeneity among surface active sites which is confirmed by different experimental methods. Temperature programmed desorption of glyphosate coupled with mass spectrometer detected one broad, high-temperature peak which represents overlapped desorption processes from active sights of similar strength.Introduction of potassium tungstophosphate affects active sites present in BEA zeolite for glyphosate desorption and significantly increases the amount of adsorbed pesticide in comparison to BEA zeolite. Supporting of potassium tungstophosphate on BEA zeolite via in situ synthesis procedure enables the formation of highly efficient adsorbents and revealed their perspective environmental application.
引文
Al-Zahrani,S.M.,Jibril,B.Y.,Abasaeed,A.E.,2001.Keggin-type polyoxotungstate as a catalyst in oxidative dehydrogenation of propane.J.Mol.Catal.A Chem.175,259-265.
Arroyave,J.M.,Waiman,C.C.,Zanini,G.P.,Avena,M.J.,2016.Effect of humic acid on the adsorption/desorption behavior of glyphosate on goethite.Isotherms and kinetics.Chemosphere145,34-41.
Bajuk-Bogdanovi?,D.,Jovi?,A.,Nedi?Vasiljevi?,B.,Milojevi?-Raki?,M.,Kragovi?,M.,Kraji?nik,D.,et al.,2017.12-Tungstophosphoric acid/BEA zeolite composites-characterization and application for pesticide removal.Mater.Sci.Eng.B225,60-67.
Barja,B.C.,dos Santos Afonso,M.,1998.An ATR-FTIR study of glyphosate and its Fe(III)complex in aqueous solution.Environ.Sci.Technol.32,3331-3335.
Blasco,T.,Corma,A.,Martínez,A.,Martínez-Escolano,P.,1998.Supported heteropolyacid(HPW)catalysts for the continuous alkylation of isobutane with 2-butene:the benefit of using MCM-41 with larger pore diameters.J.Catal.177,306-313.
Borggaard,O.K.,Gimsing,A.L.,2008.Fate of glyphosate in soil and the possibility of leaching to ground and surface waters:a review.Pest Manag.Sci.64,441-456.
Brauer,G.,1981.Handbook of Preparative Inorganic Chemistry.3rd ed.Ferdinand Enke Verlag,Stuttgart.
Bridgeman,A.J.,2003.Density functional study of the vibrational frequencies ofα-Keggin heteropolyanions.Chem.Phys.287,55-69.
Carberry,J.J.,1971.Chemical and catalytic reaction engineering.2nd ed.McGraw-Hill.Dover Publications,Mineola,New York.
Caullet,P.,Hazm,J.,Guth,J.L.,Joly,J.F.,Lynch,J.,Raatz,F.,1992.Synthesis of zeolite beta from nonalkaline fluoride aqueous aluminosilicate gels.Zeolites 12,240-250.
Chen,C.C.,Wang,Q.,Lei,P.X.,Song,W.J.,Ma,W.H.,Zhao,J.C.,2006.Photodegradation of dye pollutants catalyzed by porous K3PW12O40under visible irradiation.Environ.Sci.Technol.40,3965-3970.
Chen,F.-X.,Zhou,C.-R.,Li,G.-P.,2012.Study on thermal decomposition and the non-isothermal decomposition kinetics of glyphosate.J.Therm.Anal.Calorim.109,1457-1462.
De Jonge,H.,De Jonge,L.W.,1999.Influence of p H and solution composition on the sorption of glyphosate and prochloraz to a sandy loam soil.Chemosphere 39,753-763.
De Smedt,C.,Ferrer,F.,Leus,K.,Spanoghe,P.,2015.Removal of pesticides from aqueous solutions by adsorption on zeolites as solid adsorbents.Adsorpt.Sci.Technol.33,457-486.
Essayem,N.,Holmqvist,A.,Gayraud,P.,Vedrine,J.,Ben Taarit,Y.,2001.In situ FTIR studies of the protonic sites of H3PW12O40and its acidic cesium salts MxH3-xPW12O40.J.Catal.197(2),273-280.
Flanigen,E.M.,Khatami,H.,Szymanski,H.A.,1974.Infrared structural studies of zeolite frameworks.In:Flanigen,E.M.(Ed.),Molecular Sieve Zeolites-I.American Chemical Society,pp.201-229.
Gimsing,A.L.,Szilas,C.,Borggaard,O.K.,2007.Sorption of glyphosate and phosphate by variable-charge tropical soils from Tanzania.Geoderma 138,127-132.
Glass,R.L.,1987.Adsorption of glyphosate by soils and clay minerals.J.Agric.Food Chem.35,497-500.
Grinenval,E.,Rozanska,X.,Baudouin,A.,Berrier,E.,Delbecq,F.,Sautet,P.,et al.,2010.Controlled interactions between anhydrous Keggin-type heteropolyacids and silica support:preparation and characterization of well-defined silicasupported polyoxometalate species.J.Phys.Chem.C 114,19024-19034.
Haber,J.,Pamin,K.,Matachowski,L.,Napruszewska,B.,Po?towicz,J.,2002.Potassium and silver salts of tungstophosphoric acid as catalysts in dehydration of ethanol and hydration of ethylene.J.Catal.207,296-306.
Haber,J.,Matachowski,L.,Mucha,D.,Stoch,J.,Sarv,P.,2005.New evidence on the structure of potassium salts of 12-tungstophosphoric acid,KxH3-xPW12O40.Inorg.Chem.44,6695-6703.
Holclajtner-Antunovi?,I.,Mio?,U.B.,Todorovi?,M.,Jovanovi?,Z.,Davidovi?,M.,Bajuk-Bogdanovi?,D.,et al.,2010.Characterization of potassium salts of 12-tungstophosphoric acid.Mater.Res.Bull.45,1679-1684.
Hu,Y.S.,Zhao,Y.Q.,Sorohan,B.,2011.Removal of glyphosate from aqueous environment by adsorption using water industrial residual.Desalination 271,150-156.
Ibrahim,S.M.,El-Shobaky,G.A.,2008.Catalytic efficiency of cesium and potassium salts of dodecatungstophosphoric acid supported on silica and comparison with H3PW12O40/SiO2.Kinet.Catal.49,484-492.
Jovi?,A.,Bajuk-Bogdanovi?,D.,Nedi?Vasiljevi?,B.,Milojevi?-Raki?,M.,Kraji?nik,D.,Dondur,V.,et al.,2017.Synthesis and characterization of 12-phosphotungstic acid supported on BEAzeolite.Mater.Chem.Phys.186,430-437.
Khoury,G.A.,Gehris,T.C.,Tribe,L.,Torres Sánchez,R.M.,dos Santos Afonso,M.,2010.Glyphosate adsorption on montmorillonite:an experimental and theoretical study of surface complexes.Appl.Clay Sci.50,167-175.
Kunkeler,P.J.,Zuurdeeg,B.J.,Van DerWaal,J.C.,Van Bokhoven,J.A.,Koningsberger,D.C.,van Bekkum,H.,1998.Zeolite beta:the relationship between calcination procedure,aluminum configuration,and Lewis acidity.J.Catal.180,234-244.
Marchena,C.L.,Frenzel,R.A.,Gomez,S.,Pierella,L.B.,Pizzio,L.R.,2013.Tungstophosphoric acid immobilized on ammonium Yand ZSM5 zeolites:synthesis,characterization and catalytic evaluation.Appl.Catal.B Environ.130-131,187-196.
Milojevi?-Raki?,M.,Jano?evi?,A.,Krsti?,J.,Nedi?Vasiljevi?,B.,Dondur,V.,?iri?-Marjanovi?,G.,2013.Polyaniline and its composites with zeolite ZSM-5 for efficient removal of glyphosate from aqueous solution.Micropor.Mesopor.Mater.180,141-155.
Milojevi?-Raki?,M.,Bajuk-Bogdanovi?,D.,Nedi?Vasiljevi?,B.,Raki?,A.,?krivanj,S.,Ignjatovi?,L.,et al.,2018a.Polyaniline/FeZSM-5 composites-synthesis,characterization and their high catalytic activity for the oxidative degradation of herbicide glyphosate.Micropor.Mesopor.Mater.267(1),68-79.
Milojevi?-Raki?,M.,Dondur,V.,Damjanovi?-Vasili?,L.,Rac,V.,Raki?,V.,2018b.The accessibility of sites active in the dissociative adsorption of aromatic hydrocarbons in FeZSM-5zeolite.React.Kinet.Mech.Catal.123,231-246.
Okamoto,H.,Yamanaka,K.,Kudo,T.,1986.Protonic conduction and electrochromism of amorphous peroxopolytungstic acid.Mater.Res.Bull.21,551-557.
Pope,M.T.,Müller,A.,2001.Introduction to polyoxometalate chemistry:from topology via self-assembly to applications.In:Pope,M.T.,Müller,A.(Eds.),Polyoxometalate Chemistry from Topology via Self-Assembly to Applications.Springer,Netherlands,Dordrecht,pp.101-116.
Rocchiccioli-Deltcheff,C.,Thouvenot,R.,Franck,R.T.,1976.Spectres i.r.et Raman d'hétéropolyanionsα-XM12O40n-de structure de type Keggin(X=BIII,SiIV,GeIV,PV,AsV et M=WVI et MoVI).Spectrochim.Acta Part A Mol.Spectrosc.32,587-597.
Rocchiccioli-Deltcheff,C.,Fournier,M.,Franck,R.,Thouvenot,R.,1983.Vibrational investigations of polyoxometalates.2.Evidence for anion-anion interactions in molybdenum(VI)and tungsten(VI)compounds related to the Keggin structure.Inorg.Chem.22,207-216.
Shen,L.-J.,Le,Q.-H.,Yang,Y.-Z.,Shi,Y.-H.,2006.Static absorption of glyphosate by active carbon.Chem.Eng.10,46-49.
Sprankle,P.,Meggitt,W.F.,Penner,D.,1975.Adsorption,mobility,and microbial degradation of glyphosate in the soil.Weed Sci.23(3),229-234.
Stuartt,A.V.,Sutherland,G.B.B.M.,1956.Effect of hydrogen bonding on the deformation frequencies of the hydroxyl group in alcohols.J.Chem.Phys.24,559-570.
Subramaniam,V.,Hoggard,P.E.,1988.Metal complexes of glyphosate.J.Agric.Food Chem.36,1326-1329.
Wang,R.,Ma,T.,Wu,D.,Vladimir,K.,2011.Performance of several Keggin heteropoly acids/salts for adsorption of NOxin:2011International Symposium on Water Resource and Environmental Protection.IEEE 3153-3154.
Yang,R.T.,2003.Adsorbents:Fundamentals and Applications.Wiley-Interscience.
Yu,Y.,Zhou,Q.-X.,2005.Adsorption characteristics of pesticides methamidophos and glyphosate by two soils.Chemosphere58,811-816.
Zhu,Z.,Yang,W.,2009.Preparation,characterization and shapeselective catalysis of supported heteropolyacid salts K2.5H0.5PW12O40,(NH4)2.5H0.5PW12O40,and Ce0.83H0.5PW12O40on MCM-41 mesoporous silica.J.Phys.Chem.C 113,17025-17031.
Arroyave,J.M.,Waiman,C.C.,Zanini,G.P.,Avena,M.J.,2016.Effect of humic acid on the adsorption/desorption behavior of glyphosate on goethite.Isotherms and kinetics.Chemosphere145,34-41.
Bajuk-Bogdanovi?,D.,Jovi?,A.,Nedi?Vasiljevi?,B.,Milojevi?-Raki?,M.,Kragovi?,M.,Kraji?nik,D.,et al.,2017.12-Tungstophosphoric acid/BEA zeolite composites-characterization and application for pesticide removal.Mater.Sci.Eng.B225,60-67.
Barja,B.C.,dos Santos Afonso,M.,1998.An ATR-FTIR study of glyphosate and its Fe(III)complex in aqueous solution.Environ.Sci.Technol.32,3331-3335.
Blasco,T.,Corma,A.,Martínez,A.,Martínez-Escolano,P.,1998.Supported heteropolyacid(HPW)catalysts for the continuous alkylation of isobutane with 2-butene:the benefit of using MCM-41 with larger pore diameters.J.Catal.177,306-313.
Borggaard,O.K.,Gimsing,A.L.,2008.Fate of glyphosate in soil and the possibility of leaching to ground and surface waters:a review.Pest Manag.Sci.64,441-456.
Brauer,G.,1981.Handbook of Preparative Inorganic Chemistry.3rd ed.Ferdinand Enke Verlag,Stuttgart.
Bridgeman,A.J.,2003.Density functional study of the vibrational frequencies ofα-Keggin heteropolyanions.Chem.Phys.287,55-69.
Carberry,J.J.,1971.Chemical and catalytic reaction engineering.2nd ed.McGraw-Hill.Dover Publications,Mineola,New York.
Caullet,P.,Hazm,J.,Guth,J.L.,Joly,J.F.,Lynch,J.,Raatz,F.,1992.Synthesis of zeolite beta from nonalkaline fluoride aqueous aluminosilicate gels.Zeolites 12,240-250.
Chen,C.C.,Wang,Q.,Lei,P.X.,Song,W.J.,Ma,W.H.,Zhao,J.C.,2006.Photodegradation of dye pollutants catalyzed by porous K3PW12O40under visible irradiation.Environ.Sci.Technol.40,3965-3970.
Chen,F.-X.,Zhou,C.-R.,Li,G.-P.,2012.Study on thermal decomposition and the non-isothermal decomposition kinetics of glyphosate.J.Therm.Anal.Calorim.109,1457-1462.
De Jonge,H.,De Jonge,L.W.,1999.Influence of p H and solution composition on the sorption of glyphosate and prochloraz to a sandy loam soil.Chemosphere 39,753-763.
De Smedt,C.,Ferrer,F.,Leus,K.,Spanoghe,P.,2015.Removal of pesticides from aqueous solutions by adsorption on zeolites as solid adsorbents.Adsorpt.Sci.Technol.33,457-486.
Essayem,N.,Holmqvist,A.,Gayraud,P.,Vedrine,J.,Ben Taarit,Y.,2001.In situ FTIR studies of the protonic sites of H3PW12O40and its acidic cesium salts MxH3-xPW12O40.J.Catal.197(2),273-280.
Flanigen,E.M.,Khatami,H.,Szymanski,H.A.,1974.Infrared structural studies of zeolite frameworks.In:Flanigen,E.M.(Ed.),Molecular Sieve Zeolites-I.American Chemical Society,pp.201-229.
Gimsing,A.L.,Szilas,C.,Borggaard,O.K.,2007.Sorption of glyphosate and phosphate by variable-charge tropical soils from Tanzania.Geoderma 138,127-132.
Glass,R.L.,1987.Adsorption of glyphosate by soils and clay minerals.J.Agric.Food Chem.35,497-500.
Grinenval,E.,Rozanska,X.,Baudouin,A.,Berrier,E.,Delbecq,F.,Sautet,P.,et al.,2010.Controlled interactions between anhydrous Keggin-type heteropolyacids and silica support:preparation and characterization of well-defined silicasupported polyoxometalate species.J.Phys.Chem.C 114,19024-19034.
Haber,J.,Pamin,K.,Matachowski,L.,Napruszewska,B.,Po?towicz,J.,2002.Potassium and silver salts of tungstophosphoric acid as catalysts in dehydration of ethanol and hydration of ethylene.J.Catal.207,296-306.
Haber,J.,Matachowski,L.,Mucha,D.,Stoch,J.,Sarv,P.,2005.New evidence on the structure of potassium salts of 12-tungstophosphoric acid,KxH3-xPW12O40.Inorg.Chem.44,6695-6703.
Holclajtner-Antunovi?,I.,Mio?,U.B.,Todorovi?,M.,Jovanovi?,Z.,Davidovi?,M.,Bajuk-Bogdanovi?,D.,et al.,2010.Characterization of potassium salts of 12-tungstophosphoric acid.Mater.Res.Bull.45,1679-1684.
Hu,Y.S.,Zhao,Y.Q.,Sorohan,B.,2011.Removal of glyphosate from aqueous environment by adsorption using water industrial residual.Desalination 271,150-156.
Ibrahim,S.M.,El-Shobaky,G.A.,2008.Catalytic efficiency of cesium and potassium salts of dodecatungstophosphoric acid supported on silica and comparison with H3PW12O40/SiO2.Kinet.Catal.49,484-492.
Jovi?,A.,Bajuk-Bogdanovi?,D.,Nedi?Vasiljevi?,B.,Milojevi?-Raki?,M.,Kraji?nik,D.,Dondur,V.,et al.,2017.Synthesis and characterization of 12-phosphotungstic acid supported on BEAzeolite.Mater.Chem.Phys.186,430-437.
Khoury,G.A.,Gehris,T.C.,Tribe,L.,Torres Sánchez,R.M.,dos Santos Afonso,M.,2010.Glyphosate adsorption on montmorillonite:an experimental and theoretical study of surface complexes.Appl.Clay Sci.50,167-175.
Kunkeler,P.J.,Zuurdeeg,B.J.,Van DerWaal,J.C.,Van Bokhoven,J.A.,Koningsberger,D.C.,van Bekkum,H.,1998.Zeolite beta:the relationship between calcination procedure,aluminum configuration,and Lewis acidity.J.Catal.180,234-244.
Marchena,C.L.,Frenzel,R.A.,Gomez,S.,Pierella,L.B.,Pizzio,L.R.,2013.Tungstophosphoric acid immobilized on ammonium Yand ZSM5 zeolites:synthesis,characterization and catalytic evaluation.Appl.Catal.B Environ.130-131,187-196.
Milojevi?-Raki?,M.,Jano?evi?,A.,Krsti?,J.,Nedi?Vasiljevi?,B.,Dondur,V.,?iri?-Marjanovi?,G.,2013.Polyaniline and its composites with zeolite ZSM-5 for efficient removal of glyphosate from aqueous solution.Micropor.Mesopor.Mater.180,141-155.
Milojevi?-Raki?,M.,Bajuk-Bogdanovi?,D.,Nedi?Vasiljevi?,B.,Raki?,A.,?krivanj,S.,Ignjatovi?,L.,et al.,2018a.Polyaniline/FeZSM-5 composites-synthesis,characterization and their high catalytic activity for the oxidative degradation of herbicide glyphosate.Micropor.Mesopor.Mater.267(1),68-79.
Milojevi?-Raki?,M.,Dondur,V.,Damjanovi?-Vasili?,L.,Rac,V.,Raki?,V.,2018b.The accessibility of sites active in the dissociative adsorption of aromatic hydrocarbons in FeZSM-5zeolite.React.Kinet.Mech.Catal.123,231-246.
Okamoto,H.,Yamanaka,K.,Kudo,T.,1986.Protonic conduction and electrochromism of amorphous peroxopolytungstic acid.Mater.Res.Bull.21,551-557.
Pope,M.T.,Müller,A.,2001.Introduction to polyoxometalate chemistry:from topology via self-assembly to applications.In:Pope,M.T.,Müller,A.(Eds.),Polyoxometalate Chemistry from Topology via Self-Assembly to Applications.Springer,Netherlands,Dordrecht,pp.101-116.
Rocchiccioli-Deltcheff,C.,Thouvenot,R.,Franck,R.T.,1976.Spectres i.r.et Raman d'hétéropolyanionsα-XM12O40n-de structure de type Keggin(X=BIII,SiIV,GeIV,PV,AsV et M=WVI et MoVI).Spectrochim.Acta Part A Mol.Spectrosc.32,587-597.
Rocchiccioli-Deltcheff,C.,Fournier,M.,Franck,R.,Thouvenot,R.,1983.Vibrational investigations of polyoxometalates.2.Evidence for anion-anion interactions in molybdenum(VI)and tungsten(VI)compounds related to the Keggin structure.Inorg.Chem.22,207-216.
Shen,L.-J.,Le,Q.-H.,Yang,Y.-Z.,Shi,Y.-H.,2006.Static absorption of glyphosate by active carbon.Chem.Eng.10,46-49.
Sprankle,P.,Meggitt,W.F.,Penner,D.,1975.Adsorption,mobility,and microbial degradation of glyphosate in the soil.Weed Sci.23(3),229-234.
Stuartt,A.V.,Sutherland,G.B.B.M.,1956.Effect of hydrogen bonding on the deformation frequencies of the hydroxyl group in alcohols.J.Chem.Phys.24,559-570.
Subramaniam,V.,Hoggard,P.E.,1988.Metal complexes of glyphosate.J.Agric.Food Chem.36,1326-1329.
Wang,R.,Ma,T.,Wu,D.,Vladimir,K.,2011.Performance of several Keggin heteropoly acids/salts for adsorption of NOxin:2011International Symposium on Water Resource and Environmental Protection.IEEE 3153-3154.
Yang,R.T.,2003.Adsorbents:Fundamentals and Applications.Wiley-Interscience.
Yu,Y.,Zhou,Q.-X.,2005.Adsorption characteristics of pesticides methamidophos and glyphosate by two soils.Chemosphere58,811-816.
Zhu,Z.,Yang,W.,2009.Preparation,characterization and shapeselective catalysis of supported heteropolyacid salts K2.5H0.5PW12O40,(NH4)2.5H0.5PW12O40,and Ce0.83H0.5PW12O40on MCM-41 mesoporous silica.J.Phys.Chem.C 113,17025-17031.