Reduced graphene oxide supported Pd-Cu-Co trimetallic catalyst:synthesis,characterization and methanol electrooxidation properties
|
摘要
Trimetallic palladium-copper-cobalt nanoparticles supported on reduced graphene oxide(PdCuCo/RGO)with different molar ratios of Pd,Cu and Co can be synthesized by facile chemical reduction with NaBH_4 as reductant and cetrimonium bromide as stabilizer.The morphology,structure and composition of the as-synthesized catalysts are characterized by transmission electron microscopy,X-ray diffraction and Xray photoelectron spectroscopy.The cyclic voltammetry and chronoamperometry are utilized to investigate the electrochemical activities and stabilities of the as-obtained catalysts.The results demonstrate that the PdCuCo/RGO catalyst shows superior catalytic activity and stability for methanol electrooxidation in alkaline media compared with PdCu/RGO,PdCo/RGO,and Pd/RGO catalysts.These findings suggest that the PdCuCo/RGO catalyst possesses a great potential as a promising anode catalyst for direct methanol fuel cells.
Trimetallic palladium-copper-cobalt nanoparticles supported on reduced graphene oxide(PdCuCo/RGO)with different molar ratios of Pd,Cu and Co can be synthesized by facile chemical reduction with NaBH_4 as reductant and cetrimonium bromide as stabilizer.The morphology,structure and composition of the as-synthesized catalysts are characterized by transmission electron microscopy,X-ray diffraction and Xray photoelectron spectroscopy.The cyclic voltammetry and chronoamperometry are utilized to investigate the electrochemical activities and stabilities of the as-obtained catalysts.The results demonstrate that the PdCuCo/RGO catalyst shows superior catalytic activity and stability for methanol electrooxidation in alkaline media compared with PdCu/RGO,PdCo/RGO,and Pd/RGO catalysts.These findings suggest that the PdCuCo/RGO catalyst possesses a great potential as a promising anode catalyst for direct methanol fuel cells.
Trimetallic palladium-copper-cobalt nanoparticles supported on reduced graphene oxide(PdCuCo/RGO)with different molar ratios of Pd,Cu and Co can be synthesized by facile chemical reduction with NaBH_4 as reductant and cetrimonium bromide as stabilizer.The morphology,structure and composition of the as-synthesized catalysts are characterized by transmission electron microscopy,X-ray diffraction and Xray photoelectron spectroscopy.The cyclic voltammetry and chronoamperometry are utilized to investigate the electrochemical activities and stabilities of the as-obtained catalysts.The results demonstrate that the PdCuCo/RGO catalyst shows superior catalytic activity and stability for methanol electrooxidation in alkaline media compared with PdCu/RGO,PdCo/RGO,and Pd/RGO catalysts.These findings suggest that the PdCuCo/RGO catalyst possesses a great potential as a promising anode catalyst for direct methanol fuel cells.
引文
[1]P.Thounthong,S.Ra?l,B.Davat,J.Power Sources 158(2006)806-814.
[2]Z.Yang,H.Nie,Xa.Chen,X.Chen,S.Huang,J.Power Sources 236(2013)238-249.
[3]L.Yang,X.Song,M.Qi,L.Xia,M.Jin,J.Mater.Chem.A.1(2013)7316-7320.
[4]X.Lou,J.Chen,M.Wang,J.Gu,P.Wu,D.Sun,Y.Tang,J.Power Sources 287(2015)203-210.
[5]Y.Yamauchi,A.Tonegawa,M.Komatsu,H.Wang,L.Wang,Y.Nemoto,N.Suzuki,K.Kuroda,J.Am.Chem.Soc.134(2012)5100-5109.
[6]H.Huang,X.Wang,J.Mater.Chem.22(2012)22533-22541.
[7]Z.Cai,Z.Lu,Y.Bi,Y.Li,Y.Kuang,X.Sun,Chem.Commun.52(2016)3903-3906.
[8]R.Carrera-Cerritos,V.Baglio,A.S.Aricò,J.Ledesma-García,M.F.Sgroi,D.Pullini,A.J.Prunaef,D.B.Mataixf,R.Fuentes-Ramíreza,L.G.Arriagag,IAppl.Catal B:Environ.144(2014)554-560.
[9]Z.Xia,S.Wang,Y.Li,L.Jiang,H.Sun,S.Zhu,D.Su,G.Sun,J.Mater.Chem.A1(2013)491-494.
[10]Y.Zhao,L.Zhan,J.Tian,S.Nie,Z.Ning,Electrochim.Acta 56(2011)1967-1972.
[11]F.Yang,C.Wang,S.Dong,C.Chi,X.Jia,L.Zhang,Y.Li,Mater.Lett.174(2016)192-196.
[12]S.H.Hsieh,M.C.Hsu,W.L.Liu,W.J.Chen,Appl.Surf.Sci.277(2013)223-230.
[13]Z.Y.Shih,C.W.Wang,G.Xu,H.T.Chang,J.Mater.Chem.A 1(2013)4773-4778.
[14]S.Tominaka,T.Momma,T.Osaka,Electrochim.Acta 53(2008)4679-4686.
[15]Z.Yin,Y.Zhang,K.Chen,J.Li,W.Li,P.Tang,H.Zhao,Q.Zhu,X.Bao,D.Ma,Sci.Rep.4(2014)4228.
[16]C.Zhu,D.Wen,M.Oschatz,M.Holzschuh,W.Liu,A-K Herrmann,F.Simon,S.Kaskel,A.Eychmüller,Small 11(2015)1430-1434.
[17]S.Hu,F.Munoz,J.Noborikawa,J.Haan,L.Scudiero,S.Ha,180(2016)758-765.
[18]R.Wang,S.Liao,S.Ji,J.Power Sources 180(2008)205-208.
[19]C.Shang,W.Hong,J.Wang,E.Wang,J.Power Sources 285(2015)12-15.
[20]Y.Hao,X.Wang,Y.Zheng,J.Shen,J.Yuan,A-j.Wang,L.Niu,S.Huang,Electrochim.Acta 198(2016)127-134.
[21]E.Yoo,T.Okata,T.Akita,M.Kohyama,J.Nakamura,I.Honma,Nano.Lett.9(2009)2255-2259.
[22]J.Wang,J.Xi,Y.Bai,Y.Shen,J.Sun,L.Chen,W.Zhu,X.Qiu,J.Power Sources164(2007)555-560.
[23]J.Lu,Y.Zhou,X.Tian,X.Xu,H.Zhu,S.Zhang,T.Yuan,Appl.Surf.Sci.317(2014)284-293.
[24]Y.Guo,X.Sun,Y.Liu,W.Wang,H.Qiu,J.Gao,Carbon 50(2012)2513-2523.
[25]K.Kakaei,M.Zhiani,J.Power Sources 225(2013)356-363.
[26]S.S.Mehetre,S.S.Maktedar,M.Singh,Appl.Surf.Sci.366(2016)514-522.
[27]W.S.Hummers Jr.,R.E.Offeman,J.Am.Chem.Soc.80(1958)1339.
[28]A.S.Varela,C.Schlaup,Z.P.Jovanov,P.Malacrida,S.Horch,I.E.L Stephens,I.Chorkendorff,J.Phys.Chem.C 117(2013)20500-20508.
[29]J.H.Jang,C.Pak,Y.U.Kwon,J.Power Sources 201(2012)179-183.
[30]H.Na,L.Zhang,H.Qiu,T.Wu,M.Chen,N.Yang,L.Li,F.Xing,J.Gao,J.Power Sources 288(2015)160-167.
[31]S.Rej,H.J.Wang,M.X.Huang,S.C.Hsu,C.S.Tan,F.C.Lin,J.S.Huang,M.H.Huang,Nanoscale 7(2015)11135-11141.
[32]W.Cui,F.Wang,J.Wang,H.Liu,C.Wang,Y.Xia,J.Power Sources 196(2011)3633-3639.
[33]G.T.Fu,R.G.Ma,X.Q.Gao,Y Chen,Y.W.Tang,T.H.Lu,J.M.Lee,Nanoscale 6(2014)12310-12314.
[34]L.Zhang,Y.Tang,J.Bao,T.Lu,C.Li,J.Power Sources 162(2006)177-179.
[35]Y.Huang,Y.Guo,Y.Wang,J.Power Sources 249(2014)9-12.
[36]F.Zhu,G.Ma,Z.Bai,R.Hang,B.Tang,Z.Zhang,X.Wang,J.Power Sources 242(2013)610-620.
[37]Y.Xiao,C.Hu,M.Cao,J.Power Sources 247(2014)49-56.
[38]I.Mintsouli,J.Georgieva,S.Armyanov,E.Valova,G.Avdeev,A.Hubin,O.Steenhaut,J.Dille,D.Tsiplakides,S.Balomenou,S.Sotiropoulos,Appl.Catal B:Environ.136-137(2013)160-167.
[39]W.Zhang,F.Dong,W.Zhang,Appl.Surf.Sci.358(2015)75-83 Part A.
[40]A.V.Bukhtiyarov,I.P.Prosvirin,V.I.Bukhtiyarov,Appl.Surf.Sci.367(2016)214-221.
[41]H.Huang,S.Yang,R.Vajtai,X.Wang,P.M.Ajayan 26(2014)5160-5165.
[42]N.D.Kim,W.Kim,J.B.Joo,S.Oh,P.Kim,Y.Kim,J.Yi,J.Power Sources 180(2008)671-675.
[43]M.Zhang,S.P.James,Polymer 46(2005)3639-3648.
[44]P.Zhang,Y.Gong,H.Li,Z.Chen,Y.Wang,Nat.Commun.4(2013)1593.
[45]S.Sitthisa,T.Pham,T.Prasomsri,T.Sooknoi,R.G.Mallinson,D.E.Resasco,J.Catal.280(2011)17-27.
[46]C.Xu,Y.Liu,J.Wang,H.R.Geng,H.J.Qiu,J.Power Sources 199(2012)124-131.
[47]J.Xu,T.White,P.Li,C.H.He,J.G.Yu,W.K.Yuan,Y.F.Han,J.Am.Chem.Soc.132(2010)10398-10406.
[48]M.Yun,M.S.Ahmed,S.Jeon,J.Power Sources 293(2015)380-387.
[49]B.Celik,Y.Yldz,H.Sert,E.Erken,Y.Koskun,F.Sen,RSC Adv.6(2016)24097-24102.
[50]Y.Qin,L.Chao,J.Yuan,Y.Liu,F.Chu,Y.Kong,Y.Tao,M.Liu,Chem.Commun.52(2016)382-385.
[51]J.N.Zheng,L.L.He,F.Y.Chen,A.J.Wang,M.W.Xue,J.J.Feng,J.Mater.Chem.A2(2014)12899-12906.
[52]W.Li,Y.Huang,D.Tang,T.Zhang,Y.Wang,Electro.Acta 174(2015)178-184.
[53]L.Yang,C.Hu,J.Wang,Z.Yang,Y.Guo,Z.Bai,K.Wang,Chem.Commun.47(2011)8581-8583.
[54]K.Eid,H.Wang,P.He,K.Wang,T.Ahamad,S.M.Alshehri,Y.Yamauchi,L.Wang,Nanoscale 7(2015)16860-16866.
[55]L.Zhang,L.Wan,Y.Ma,Y.Chen,Y.Zhou,Y.Tang,Y.Yamauchi,L.Wang,Appl.Catal B:Environ.138-139(2013)229-235.
[56]K.H.Ye,S.A.Zhou,X.C.Zhu,C-W.Xu,P.K.Shen,Electrochim.Acta 90(2013)108-111.
[2]Z.Yang,H.Nie,Xa.Chen,X.Chen,S.Huang,J.Power Sources 236(2013)238-249.
[3]L.Yang,X.Song,M.Qi,L.Xia,M.Jin,J.Mater.Chem.A.1(2013)7316-7320.
[4]X.Lou,J.Chen,M.Wang,J.Gu,P.Wu,D.Sun,Y.Tang,J.Power Sources 287(2015)203-210.
[5]Y.Yamauchi,A.Tonegawa,M.Komatsu,H.Wang,L.Wang,Y.Nemoto,N.Suzuki,K.Kuroda,J.Am.Chem.Soc.134(2012)5100-5109.
[6]H.Huang,X.Wang,J.Mater.Chem.22(2012)22533-22541.
[7]Z.Cai,Z.Lu,Y.Bi,Y.Li,Y.Kuang,X.Sun,Chem.Commun.52(2016)3903-3906.
[8]R.Carrera-Cerritos,V.Baglio,A.S.Aricò,J.Ledesma-García,M.F.Sgroi,D.Pullini,A.J.Prunaef,D.B.Mataixf,R.Fuentes-Ramíreza,L.G.Arriagag,IAppl.Catal B:Environ.144(2014)554-560.
[9]Z.Xia,S.Wang,Y.Li,L.Jiang,H.Sun,S.Zhu,D.Su,G.Sun,J.Mater.Chem.A1(2013)491-494.
[10]Y.Zhao,L.Zhan,J.Tian,S.Nie,Z.Ning,Electrochim.Acta 56(2011)1967-1972.
[11]F.Yang,C.Wang,S.Dong,C.Chi,X.Jia,L.Zhang,Y.Li,Mater.Lett.174(2016)192-196.
[12]S.H.Hsieh,M.C.Hsu,W.L.Liu,W.J.Chen,Appl.Surf.Sci.277(2013)223-230.
[13]Z.Y.Shih,C.W.Wang,G.Xu,H.T.Chang,J.Mater.Chem.A 1(2013)4773-4778.
[14]S.Tominaka,T.Momma,T.Osaka,Electrochim.Acta 53(2008)4679-4686.
[15]Z.Yin,Y.Zhang,K.Chen,J.Li,W.Li,P.Tang,H.Zhao,Q.Zhu,X.Bao,D.Ma,Sci.Rep.4(2014)4228.
[16]C.Zhu,D.Wen,M.Oschatz,M.Holzschuh,W.Liu,A-K Herrmann,F.Simon,S.Kaskel,A.Eychmüller,Small 11(2015)1430-1434.
[17]S.Hu,F.Munoz,J.Noborikawa,J.Haan,L.Scudiero,S.Ha,180(2016)758-765.
[18]R.Wang,S.Liao,S.Ji,J.Power Sources 180(2008)205-208.
[19]C.Shang,W.Hong,J.Wang,E.Wang,J.Power Sources 285(2015)12-15.
[20]Y.Hao,X.Wang,Y.Zheng,J.Shen,J.Yuan,A-j.Wang,L.Niu,S.Huang,Electrochim.Acta 198(2016)127-134.
[21]E.Yoo,T.Okata,T.Akita,M.Kohyama,J.Nakamura,I.Honma,Nano.Lett.9(2009)2255-2259.
[22]J.Wang,J.Xi,Y.Bai,Y.Shen,J.Sun,L.Chen,W.Zhu,X.Qiu,J.Power Sources164(2007)555-560.
[23]J.Lu,Y.Zhou,X.Tian,X.Xu,H.Zhu,S.Zhang,T.Yuan,Appl.Surf.Sci.317(2014)284-293.
[24]Y.Guo,X.Sun,Y.Liu,W.Wang,H.Qiu,J.Gao,Carbon 50(2012)2513-2523.
[25]K.Kakaei,M.Zhiani,J.Power Sources 225(2013)356-363.
[26]S.S.Mehetre,S.S.Maktedar,M.Singh,Appl.Surf.Sci.366(2016)514-522.
[27]W.S.Hummers Jr.,R.E.Offeman,J.Am.Chem.Soc.80(1958)1339.
[28]A.S.Varela,C.Schlaup,Z.P.Jovanov,P.Malacrida,S.Horch,I.E.L Stephens,I.Chorkendorff,J.Phys.Chem.C 117(2013)20500-20508.
[29]J.H.Jang,C.Pak,Y.U.Kwon,J.Power Sources 201(2012)179-183.
[30]H.Na,L.Zhang,H.Qiu,T.Wu,M.Chen,N.Yang,L.Li,F.Xing,J.Gao,J.Power Sources 288(2015)160-167.
[31]S.Rej,H.J.Wang,M.X.Huang,S.C.Hsu,C.S.Tan,F.C.Lin,J.S.Huang,M.H.Huang,Nanoscale 7(2015)11135-11141.
[32]W.Cui,F.Wang,J.Wang,H.Liu,C.Wang,Y.Xia,J.Power Sources 196(2011)3633-3639.
[33]G.T.Fu,R.G.Ma,X.Q.Gao,Y Chen,Y.W.Tang,T.H.Lu,J.M.Lee,Nanoscale 6(2014)12310-12314.
[34]L.Zhang,Y.Tang,J.Bao,T.Lu,C.Li,J.Power Sources 162(2006)177-179.
[35]Y.Huang,Y.Guo,Y.Wang,J.Power Sources 249(2014)9-12.
[36]F.Zhu,G.Ma,Z.Bai,R.Hang,B.Tang,Z.Zhang,X.Wang,J.Power Sources 242(2013)610-620.
[37]Y.Xiao,C.Hu,M.Cao,J.Power Sources 247(2014)49-56.
[38]I.Mintsouli,J.Georgieva,S.Armyanov,E.Valova,G.Avdeev,A.Hubin,O.Steenhaut,J.Dille,D.Tsiplakides,S.Balomenou,S.Sotiropoulos,Appl.Catal B:Environ.136-137(2013)160-167.
[39]W.Zhang,F.Dong,W.Zhang,Appl.Surf.Sci.358(2015)75-83 Part A.
[40]A.V.Bukhtiyarov,I.P.Prosvirin,V.I.Bukhtiyarov,Appl.Surf.Sci.367(2016)214-221.
[41]H.Huang,S.Yang,R.Vajtai,X.Wang,P.M.Ajayan 26(2014)5160-5165.
[42]N.D.Kim,W.Kim,J.B.Joo,S.Oh,P.Kim,Y.Kim,J.Yi,J.Power Sources 180(2008)671-675.
[43]M.Zhang,S.P.James,Polymer 46(2005)3639-3648.
[44]P.Zhang,Y.Gong,H.Li,Z.Chen,Y.Wang,Nat.Commun.4(2013)1593.
[45]S.Sitthisa,T.Pham,T.Prasomsri,T.Sooknoi,R.G.Mallinson,D.E.Resasco,J.Catal.280(2011)17-27.
[46]C.Xu,Y.Liu,J.Wang,H.R.Geng,H.J.Qiu,J.Power Sources 199(2012)124-131.
[47]J.Xu,T.White,P.Li,C.H.He,J.G.Yu,W.K.Yuan,Y.F.Han,J.Am.Chem.Soc.132(2010)10398-10406.
[48]M.Yun,M.S.Ahmed,S.Jeon,J.Power Sources 293(2015)380-387.
[49]B.Celik,Y.Yldz,H.Sert,E.Erken,Y.Koskun,F.Sen,RSC Adv.6(2016)24097-24102.
[50]Y.Qin,L.Chao,J.Yuan,Y.Liu,F.Chu,Y.Kong,Y.Tao,M.Liu,Chem.Commun.52(2016)382-385.
[51]J.N.Zheng,L.L.He,F.Y.Chen,A.J.Wang,M.W.Xue,J.J.Feng,J.Mater.Chem.A2(2014)12899-12906.
[52]W.Li,Y.Huang,D.Tang,T.Zhang,Y.Wang,Electro.Acta 174(2015)178-184.
[53]L.Yang,C.Hu,J.Wang,Z.Yang,Y.Guo,Z.Bai,K.Wang,Chem.Commun.47(2011)8581-8583.
[54]K.Eid,H.Wang,P.He,K.Wang,T.Ahamad,S.M.Alshehri,Y.Yamauchi,L.Wang,Nanoscale 7(2015)16860-16866.
[55]L.Zhang,L.Wan,Y.Ma,Y.Chen,Y.Zhou,Y.Tang,Y.Yamauchi,L.Wang,Appl.Catal B:Environ.138-139(2013)229-235.
[56]K.H.Ye,S.A.Zhou,X.C.Zhu,C-W.Xu,P.K.Shen,Electrochim.Acta 90(2013)108-111.