Morphology and magnetic traits of strontium nanohexaferrites:Effects of manganese/yttrium co-substitution
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  • 英文篇名:Morphology and magnetic traits of strontium nanohexaferrites:Effects of manganese/yttrium co-substitution
  • 作者:M.A.Almessiere ; Y.Slimani ; H.S.El ; Sayed ; A.Baykal
  • 英文作者:M.A.Almessiere;Y.Slimani;H.S.El Sayed;A.Baykal;Department of Physics, College of Science, Imam Abdulrahman Bin Faisal University;Department of Nano-Medicine Research, Institute for Research & Medical Consultations (IRMC), Imam Abdulrahman Bin Faisal University;Department of Biophysics, Institute for Research & Medical Consultations (IRMC), Imam Abdulrahman Bin Faisal University;
  • 英文关键词:Strontium hexaferrite;;Sol-gel auto-combustion;;Microstructure;;Morphology;;Magnetic properties;;Rare earths
  • 中文刊名:YXTB
  • 英文刊名:稀土学报(英文版)
  • 机构:Department of Physics, College of Science, Imam Abdulrahman Bin Faisal University;Department of Nano-Medicine Research, Institute for Research & Medical Consultations (IRMC), Imam Abdulrahman Bin Faisal University;Department of Biophysics, Institute for Research & Medical Consultations (IRMC), Imam Abdulrahman Bin Faisal University;
  • 出版日期:2019-06-26
  • 出版单位:Journal of Rare Earths
  • 年:2019
  • 期:v.37
  • 基金:Institute for Research & Medical Consultations(IRMC)of Imam Abdulrahman Bin Faisal University(IAU-Saudi Arabia) for supporting this study through the Projects application number: [2017-IRMC-S-3];[2018-IRMC-S1]and[2018-IRMC-S-2]
  • 语种:英文;
  • 页:YXTB201907009
  • 页数:9
  • CN:07
  • ISSN:11-2788/TF
  • 分类号:62-70
摘要
Doped strontium(Sr) hexaferrites appeared potential candidates for microwave absorber applications.Driven by this idea, we examined the influence of manganese(Mn) and yttrium(Y) co-substitution on the microstructures,morphology and magnetic properties of Sr nanohexaferrites(Sr_(1-x)Mn_xFe_(12-y)Y_yO_(19),where 0.0 ≤ x = y ≤ 0.5) synthesized via citrate sol-gel auto-combustion technique. As-prepared samples were thoroughly characterized using diverse analytical tools. X-ray diffraction pattern reveals a single Mhexagonal crystalline phase. FE-SEM, TEM, HR-TEM show a hexagonal platelet-like structure. The magnetic hysteresis loops(measured at room and low temperature) of the as-prepared nanohexaferrites exhibit ferromagnetic(FM) behavior. Magnetic parameters including the saturation magnetization,remanence, coercive and magneto-crystalline anisotropy field are found to decrease with the increase in Mn~(2+) and Y~(3+) contents. Zero-and normal-field cooled magnetization measurements in the range of 2-400 K display the complete absence of blocking temperature, confirming the characteristic ferromagnetic behavior of the proposed composition.
        Doped strontium(Sr) hexaferrites appeared potential candidates for microwave absorber applications.Driven by this idea, we examined the influence of manganese(Mn) and yttrium(Y) co-substitution on the microstructures,morphology and magnetic properties of Sr nanohexaferrites(Sr_(1-x)Mn_xFe_(12-y)Y_yO_(19),where 0.0 ≤ x = y ≤ 0.5) synthesized via citrate sol-gel auto-combustion technique. As-prepared samples were thoroughly characterized using diverse analytical tools. X-ray diffraction pattern reveals a single Mhexagonal crystalline phase. FE-SEM, TEM, HR-TEM show a hexagonal platelet-like structure. The magnetic hysteresis loops(measured at room and low temperature) of the as-prepared nanohexaferrites exhibit ferromagnetic(FM) behavior. Magnetic parameters including the saturation magnetization,remanence, coercive and magneto-crystalline anisotropy field are found to decrease with the increase in Mn~(2+) and Y~(3+) contents. Zero-and normal-field cooled magnetization measurements in the range of 2-400 K display the complete absence of blocking temperature, confirming the characteristic ferromagnetic behavior of the proposed composition.
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