锌基量子点的合成、表面修饰及其生物化学传感应用
详细信息    查看全文 | 推荐本文 |
  • 英文篇名:Synthesis,surface modification and biochemical sensing applications of zinc-based quantum dots
  • 作者:陈秋菊 ; 谢奇龙 ; 马莉萍 ; 王琼 ; 胡云楚 ; 王文磊
  • 英文作者:CHEN Qiuju;XIE Qilong;MA Liping;WANG Qiong;HU Yunchu;WANG Wenlei;School of Science,Central South University of Forestry and Technology;School of Materials Science and Engineering,Central South University of Forestry and Technology;
  • 关键词:锌基量子点 ; 合成 ; 修饰 ; 生物化学传感
  • 英文关键词:zinc-based quantum dots;;synthesis;;modification;;biochemical sensing
  • 中文刊名:GNCL
  • 英文刊名:Journal of Functional Materials
  • 机构:中南林业科技大学理学院;中南林业科技大学材料科学与工程学院;
  • 出版日期:2018-11-30
  • 出版单位:功能材料
  • 年:2018
  • 期:v.49;No.422
  • 基金:国家自然科学基金资助项目(21607176,31670563);; 湖南省教育厅资助项目(16C1653)
  • 语种:中文;
  • 页:GNCL201811009
  • 页数:9
  • CN:11
  • ISSN:50-1099/TH
  • 分类号:58-66
摘要
锌基量子点具有独特的光学特性、低毒性以及生物相容性好的优势,使锌基量子点在分析检测及生物标记中得到了广泛的应用。基于锌基量子点的研究进展,在阐述其合成方法、功能化修饰等基础上,系统论述了锌基量子点在生物化学传感领域的应用,并对其发展趋势和应用前景进行了展望。
        Zinc-based quantum dots have been widely used in analysis detection and biomarker due to their unique optical properties,low toxicity and good biocompatibility.Based on the research progress,in this paper,the synthesis methods and functionalized modifications,as well as the application of zinc-based quantum dots in the field of biochemical sensing were systematically described.The development trends and prospects of application of zinc-based quantum dots were also discussed in detail.
引文
[1] Joyce P B,Krzyzewski T J,Bell G R,et al.Effect of growth rate on the size,composition,and optical properties of InAs/GaAs quantum dots grown by molecularbeam epitaxy[J].Physical Review B Condensed Matter,2000,62(62):10891-10895.
    [2] Nakamura S,Mukai T,Senoh M.Candela-class highbrightness InGaN/AlGaN double-heterostructure bluelight-emitting diodes[J].Applied Physics Letters,1994,64(13):1687-1689.
    [3] Nakamura S.First III-V-nitride-based violet laser diodes[J].Journal of Crystal Growth,1997,170(1-4):11-15.
    [4] Zhu Y F,Zhou G H,Ding H Y,et al.Synthesis of highly-ordered hierarchical ZnO nanostructures and their application in dye-sensitized solar cells[J].Crystal Research&Technology,2010,45(10):1075-1078.
    [5] Cai Guangxia.Synthesis and the photoelectricproperties of one-dimensinal ZnO/ZnS core-shell nanowires[D].Nanjing:Southeast University,2017(in Chinese).曹广霞.一维ZnO@ZnS核壳结构纳米材料的制备及其性能研究[D].南京:东南大学,2017.
    [6] And M A H,Guyotsionnest P.Bright UV-blue luminescent colloidal ZnSe nanocrystals[J].Journal of Physical Chemistry B,1998,102(19):3655-3657.
    [7] Dai Q,Xiao N,Ning J,et al.Synthesis and mechanism of particle-and flower-shaped ZnSe nanocrystals:green chemical approaches toward green nanoproducts[J].Journal of Physical Chemistry C,2008,112(20):7567-7571.
    [8] Liu J,Shen W,Cui D,et al.Syngas methanation for substitute natural gas over Ni-Mg/Al2O3catalyst in fixed and fluidized bed reactors[J].Catalysis Communications,2013,38(38):35-39.
    [9] Zeng Xiuni,Wang Xiaoyan.Advance on research of nanocomposite based on ZnO quantum dots[J].Plastics Additives,2017(1):6-12(in Chinese).曾秀妮,王晓燕.基于氧化锌量子点的纳米复合材料研究进展[J].塑料助剂,2017(1):6-12.
    [10] Peng Lingling,Wang Yuhua.The preparation of ZnSe nanocrystals via hydrothermal process and their photoluminescent characteristics[J].Materials Review,2013,27(6):104-107(in Chinese).彭玲玲,王育华.水热法合成ZnSe纳米晶及其发光性质的研究[J].材料导报,2013,27(6):104-107.
    [11] Wang Cuiping,He Qun,Ye Liu,et al.Preparation of PANI@ZnS quantum dots composite nanomaterials and its luminescent properties[J].Experiment Science and Technology,2015,13(5):18-20(in Chinese).王翠平,何群,叶柳,等.PANI@ZnS复合物的制备及荧光性能研究[J].实验科学与技术,2015,13(5):18-20.
    [12] Yang Liuqing,Huang Jianfeng,Li Jirong,et al.Preparation ofα-ZnS nanocrystallites by sonochemical-microwave hydrothermal process and its optical properties[J].Bulletin of the Chinese Ceramic Society,2013,32(4):000719-000722(in Chinese).杨柳青,黄剑锋,李吉蓉,等.声化学-微波水热法合成α-ZnS纳米晶及其光学性能[J].硅酸盐通报,2013,32(4):000719-000722.
    [13] Alaie Z,Nejad S M,Yousefi M H.Array of ZnO nanoparticle-sensitized ZnO nanorods for UV photodetection[J].Journal of Materials Science:Materials in Electronics,2014,25(2):852-856.
    [14] Li Li,Li Enshuai,Zhao Yuehong,et al.Microwave-assisted synthesis of nano-composite Ag/ZnO-ZnS and preliminary study of its photocatalytic degradation of rhodamine B[J].Chemistry,2012,75(6):540-546(in Chinese).李莉,李恩帅,赵月红,等.微波辅助合成纳米复合材料Ag/ZnO-ZnS及其光催化降解若丹明B初步研究[J].化学通报,2012,75(6):540-546.
    [15] Ding Ling,He Zhenyu,Zhou Peijiang,et al.Aqueous phase preparation method of ZnSe/ZnS core-shell structure quantum dots:CN 102127446A[P].2011(in Chinese).丁玲,何振宇,周培疆,等.Aqueous phase preparation method of ZnSe/ZnS core-shell structure quantum dots:CN 102127446A[P].2011.
    [16] Chen Xiuxiu,Liu Futian,Jiang Qinghui,et al.Synthesis and characterization of ZnSe/ZnS(core/shell)quantum dots[J].Journal of Synthetic Crystals,2011,40(1):170-175(in Chinese).陈秀秀,刘福田,姜庆辉,等.ZnSe/ZnS核壳结构量子点的制备与表征[J].人工晶体学报,2011,40(1):170-175.
    [17] Bang J,Park J,Ji H L,et al.ZnTe/ZnSe(core/shell)type-II quantum dots:their optical and photovoltaic properties[J].Chemistry of Materials,2010,22(1):233-240.
    [18] Karan N S,Sarma D D,Kadam R M,et al.Doping transition metal(Mn or Cu)ions in semiconductor nanocrystals[J].Journal of Physical Chemistry Letters,2010,1(19):2863-2866.
    [19] Sun Cong,Huang Fenghua.Synthesis and characterization of L-cysteine-modified ZnS∶Co/ZnS quantum dots[J].Journal of Synthetic Crystals,2013,42(10):2028-2032(in Chinese).孙聪,黄风华.L-半胱氨酸修饰的ZnS∶Co/ZnS量子点的合成及表征[J].人工晶体学报,2013,42(10):2028-2032.
    [20] Lin L P,Huang F H,Chen P F.Synthesis and fluorescence properties of water-soluble L-cysteine-modified ZnSe∶Ag quantum dots[J].Advanced Materials Research,2014,(1033-1034):1172-1175.
    [21] Li Tingting.Synthesis and characterization of Zn Se,Zn Se∶Mn and ZnSe∶Mn/n Zn S nanocrystals[D].Wuhan:Huazhong University of Science,2014(in Chinese).李婷婷.ZnSe、ZnSe∶Mn及ZnSe∶Mn/nZnS纳米颗粒的制备和物性研究[D].武汉:华中科技大学,2014.
    [22] Song Y,Li Y,Wang X,et al.Novel aqueous synthesis methods for ZnTe/ZnSe and Mn2+-doped ZnTe/ZnSe type-Ⅱcore/shell quantum dots[J].Rsc Advances,2014,5(9):6271-6278.
    [23] Hu Zhiyang.Synthesis of co-doped aqueous ZnSe quantum dots and optical property tuning[D].Nanjing:Southeast University,2016(in Chinese).胡志扬.共掺杂型水溶性ZnSe量子点的制备与荧光调控[D].南京:东南大学,2016.
    [24] Sun Cong,Huang Fenghua,Huang Bifei,et al.Synthesis and fluorescence property of L-cysteine-modified water-soluble ZnS:Mn quantum dots[J].Chinese Journal of Synthetic Chemistry,2013,21(2):234-236(in Chinese).孙聪,黄风华,黄碧妃,等.L-半胱氨酸修饰的水溶性ZnS:Mn量子点的合成及其荧光性质[J].合成化学,2013,21(2):234-236.
    [25] Han Lili.Visible emission mechanism of ZnO quantum dots and thiol modification[D].Tianjin:Tianjin University,2011(in Chinese).韩丽丽.ZnO量子点的可见发光机制及巯基类有机物修饰研究[D].天津:天津大学,2011.
    [26] Jia Z.MAA-modified and luminescence properties of ZnO quantum dots[J].Science China Chemistry,2009,52(12):2125-2133.
    [27] Du Hongyan,Wei Zhipeng,Li Shuang,et al.Luminescent properties of surface modified ZnS∶Mn quantum dot and detection of biological molecules[J].Chinese Journal of Luminescence,2013,34(4):421-426(in Chinese).杜鸿延,魏志鹏,李霜,等.表面修饰的ZnS∶Mn量子点的发光性质及其对生物分子的检测[J].发光学报,2013,34(4):421-426.
    [28] Moghaddam E,Youzbashi A A,Kazemzadeh A,et al.Photoluminescence investigation of ZnO quantum dots surface modified with silane coupling agent as a capping agent[J].Journal of Luminescence,2015,168:158-162.
    [29] Xiong H M,Xu Y,Ren Q G,et al.Stable aqueous ZnO@polymer core-shell nanoparticles with tunable photoluminescence and their application in cell imaging[J].Journal of the American Chemical Society,2008,130(24):7522-7523.
    [30] Duan J,Jiang X,Ni S,et al.Facile synthesis of N-acetyl-cysteine capped ZnS quantum dots as an eco-friendly fluorescence sensor for Hg[J].Talanta,2011,85(4):1738-1743.
    [31] Sun Xuehua,Liu Fangling,Hu Haijing,et al.The synthesis of ZnO quantum dots as fluorescence probe for the detection of lead Ion[C].Beijing:Chinese Chemical Society National Conference on Organic Analysis and Bioanalysis,2013(in Chinese).孙雪花,刘芳玲,胡海婧,等.ZnO量子点的合成及其作为荧光探针对铅离子的测定[C].北京:中国化学会全国有机分析与生物分析学术研讨会,2013.
    [32] Du Baoan,Liu Cheng,Cao Yuhong,et al.Study of the Mn-doped ZnS quantum dots as the phosphorescence probes to detect the micro-quantity Hg2+[J].Spectroscopy and Spectral Analysis,2014,34(4):1070-1074(in Chinese).杜保安,刘澄,曹雨虹,等.ZnS∶Mn量子点作磷光探针定量检测微量汞[J].光谱学与光谱分析,2014,34(4):1070-1074.
    [33] Lu X,Zhang J,Xie Y N,et al.Ratiometric phosphorescent probe for thallium in serum,water,and soil samples based on long-lived,spectrally resolved,Mn-doped ZnSe quantum dots and carbon dots[J].Analytical Chemistry,2018,90(4):2939.
    [34] Song Y,Li Y,Liu Y,et al.Highly sensitive and selective detection of phosphate using novel highly photoluminescent water-soluble Mn-doped ZnTe/ZnSe quantum dots[J].Talanta,2015,144:680-685.
    [35] Li Yumei,Lu Yunxian,Ban Rui,et al.An “off-on”room temperature phosphorescence probe on Mn∶ZnS quantum dots/Cu2+complex for determination of pyrophosphate in water[J].Environmental Chemistry,2016,335(5):941-947(in Chinese).李玉美,卢运贤,班睿,等.基于Mn∶ZnS量子点-Cu2+体系室温磷光猝灭-恢复方法测定水体中焦磷酸根离子[J].环境化学,2016,35(5):941-947.
    [36] Choudhury M,Nath S S,Nath R K.ZnO:PVP quantum dot ethanol sensor[J].Journal of Sensor Technology,2011,1(3):86-90.
    [37] Li Fang,Yu Siying,Yin Wangmei,et al.Rapid detection of melamine in milk with the glutathione-coated Mndoped ZnS quantum dots as a phosphorescent probe[J].Contemporary Chemical Industry,2015,5:1185-1187(in Chinese).李芳,余思莹,尹王梅,等.硫化锌掺锰量子点磷光探针法快速检测牛奶中的三聚氰胺[J].当代化工,2015,5:1185-1187.
    [38] Demirhan B,Demirhan B E,Ertas N,et al.Correction to:rapid detection of acrylamide in food using Mn-doped ZnS quantum dots as a room temperature phosphorescent probe[J].Food Analytical Methods,2018,11(5):1542-1542.
    [39] Bian W,Ma J,Guo W,et al.Phosphorescence detection of L-ascorbic acid with surface-attached N-acetyl-L-cysteine and L-cysteine Mn doped ZnS quantum dots[J].Talanta,2013,116(22):794-800.
    [40] Hsu C L,Fang Y J,Hsueh T J,et al.Nonenzymatic glucose sensor based on Au/ZnO core-shell nanostructures decorated with Au nanoparticles and enhanced with blue and green light[J].Journal of Physical Chemistry B,2017,121(14):2919-3202.
    [41] Wei X,Yu M,Li C,et al.Magnetic nanoparticles coated with a molecularly imprinted polymer doped with manganese-doped ZnS quantum dots for the determination of 2,4,6-trichlorophenol[J].Microchimica Acta,2018,185(4):208.
    [42] Tu R,Liu B,Wang Z,et al.Amine-capped ZnS-Mn2+nanocrystals for fluorescence detection of trace TNT explosive[J].Analytical Chemistry,2008,80(9):3458-3465.
    [43] Wu W,Zhou T,Berliner A,et al.Glucose-mediated assembly of phenylboronic acid modified CdTe/ZnTe/ZnS quantum dots for intracellular glucose probing[J].Angewandte Chemie,2010,122(37):6554-6558.
    [44] Liu Zhengqing,Yin Pengfei,Gong Huiping,et al.Fluorescence spectral method for determination of fenaminosulf with ZnSe quantum dots as the probe[J].Journal of Southwest University(Natural Science Edition),2012,34(3):71-75(in Chinese).刘正清,殷鹏飞,龚会平,等.硒化锌量子点作探针荧光法检测农药敌磺钠[J].西南大学学报(自然科学版),2012,34(3):71-75.
    [45] Liu Chunling.Room temperature phosphorescence based on Mn doped ZnS quantum dots for detection of adriamycin[D].Chongqing:Chongqing University,2016(in Chinese).刘春玲.基于Mn掺杂ZnS量子点室温磷光法检测阿霉素研究[D].重庆:重庆大学,2016.
    [46] Arvand M,Mirroshandel A A.Fluorescent nanochemosensor for direct optosensing of butachlor based on l-cysteine-capped ZnS quantum dots[J].Journal of the Iranian Chemical Society,2017,14(11):2287-2297.
    [47] Wang H F,He Y,Ji T R,et al.Surface molecular imprinting on Mn-doped ZnS quantum dots for room-temperature phosphorescence optosensing of pentachlorophenol in water[J].Analytical Chemistry,2009,81(4):1615-1621.
    [48] He Y,Wang H F,Yan X P.Exploring Mn-doped ZnS quantum dots for the room-temperature phosphorescence detection of enoxacin in biological fluids[J].Analytical Chemistry,2008,80(10):3832-3837.
    [49] Xu Mei, Li Dongxia, Yan Guiqin. Detection of promethazine based on the room temperature phosphorescence of MPA-capped Mn-doped ZnS quantum dot[J].Journal of Instrumental Analysis,2016,35(10):1301-1305(in Chinese).许梅,栗东霞,闫桂琴.基于Mn掺杂ZnS量子点的室温磷光检测盐酸异丙嗪[J].分析测试学报,2016,35(10):1301-1305.
    [50] Yu Jianmin,Li Dongxia,An Zhaoqi,et al.Detection of CEF based on the room temperature phosphorescence of MPA-capped Mn-doped ZnS quantum dots[J].Applied Chemical Industry,2017,46(12):2492-2496(in Chinese).于建敏,栗东霞,安昭琦,等.基于Mn掺杂ZnS量子点室温磷光检测头孢克肟[J].应用化工,2017,46(12):2492-2496.
    [51] Niu Juan,Zhang Zhifeng,Yan Guiqin.Detection method of lomefloxacin hydrochloride based on room temperature phosphorescence of quantum dots[J].Chemical Regents,2017,39(10):1044-1048(in Chinese).牛娟,张直峰,闫桂琴.基于Mn掺杂ZnS室温磷光量子点检测盐酸洛美沙星方法的研究[J].化学试剂,2017,39(10):1044-1048.
    [52] An Zhaoqi,Li Dongxia,Yan Guiqin,et al.Detection of hydrochloride by room temperature phosphorescence method based on Mn doped ZnS quantum dots[J].Joural of Analytical Science,2017,33(4):467-472(in Chinese).安昭琦,栗东霞,于建敏,等.基于Mn掺杂ZnS量子点室温磷光法检测盐酸巴马汀[J].分析科学学报,2017,33(4):467-472.
    [53] Wang Ailian,Luo Xiaowei,Wang Lezheng,et al.ZnSe quantum dots sensiblity-enhanced alkaline luminol-potassium periodate flow injection chemiluminescence determination of benzoic acid[J].Journal of Ningxia University(Natural Science Edition),2016,37(2):223-227(in Chinese).王爱连,罗晓伟,王乐政,等.ZnSe量子点增敏碱性鲁米诺-高碘酸钾流动注射化学发光法测定苯甲酸[J].宁夏大学学报(自然版),2016,37(2):223-227.
    [54] Guo Cheng,Gao Guiyuan,Ding Xiaojie,et al.Determination of diethylstilbestrol in milk with the enhanced chemiluminescence system of luminol-K3Fe(CN)6by using of ZnSe quantum-dots[J].Chinese Journal of Luminescence,2012,33(7):796-801(in Chinese).郭城,高桂园,丁小洁,等.ZnSe量子点增敏鲁米诺-铁氰化钾化学发光测定牛奶中的己烯雌酚[J].发光学报,2012,33(7):796-801.
    [55] Zhao X,Li F,Zhang Q,et al.Mn-doped ZnS quantum dots with a 3-mercaptopropionic acid assembly as a ratiometric fluorescence probe for the determination of curcumin[J].Rsc Advances,2015,5(28):21504-21510.
    [56] Zhang Z,Duan F,He L,et al.Electrochemical clenbuterol immunosensor based on a gold electrode modified with zinc sulfide quantum dots and polyaniline[J].Microchimica Acta,2016,183(3):1089-1097.
    [57] Wu P,Zhao T,Tian Y,et al.Protein-directed synthesis of Mn-doped ZnS quantum dots:a dual-channel biosensor for two proteins[J].Chemistry-A European Journal,2013,19(23):7473-7479.
    [58] Hemmateenejad B,Shamsipur M,Samari F,et al.Study of the interaction between human serum albumin and Mn-doped ZnS quantum dots[J].Journal of the Iranian Chemical Society,2015,12(10):1-10.
    [59] Yao J,Han X,Zeng S,et al.Detection of femtomolar proteins by nonfluorescent ZnS nanocrystal clusters[J].Analytical Chemistry,2012,84(3):1645.
    [60] Xia Z,Xing Y,So M K,et al.Multiplex Detection of protease activity with quantum dot nanosensors prepared by intein-mediated specific bioconjugation[J].Analytical Chemistry,2008,80(22):8656-8661.
    [61] Zhao W W,Dong X Y,Wang J,et al.Immunogold labeling-induced synergy effect for amplified photoelectrochemical immunoassay of prostate-specific antigen[J].Chemical Communications,2012,48(43):5253.
    [62] Zhang L,Cui P,Zhang B,et al.Aptamer-based turn-on detection of thrombin in biological fluids based on efficient phosphorescence energy transfer from Mn-doped ZnS quantum dots to carbon nanodots[J].Chemistry,2013,19(28):9242-9250.
    [63] Zhang J,Lu X,Lei Y,et al.Exploring the tunable excitation of QDs to maximize the overlap with the absorber for inner filter effect-based phosphorescence sensing of alkaline phosphatase[J].Nanoscale,2017,9(40):
    [64] Liu J A,Wei X,Qu Y,et al.Aqueous synthesis and bio-imaging application of highly luminescent and low cytotoxicity Mn2+-doped ZnSe nanocrystals[J].Materials Letters,2011,65(14):2139-2141.
    [65] Gao X,Zhang H,Li Y,et al.Mn-doped ZnSe d-dotsbasedα-methylacyl-CoA racemase probe for human prostate cancer cell imaging[J].Analytical&Bioanalytical Chemistry,2012,402(5):1871-1877.
    [66] Chang S,Huang B,Chen X,et al.Facile synthesis and characterization of water soluble ZnSe/ZnS quantum dots for cellar imaging[J].Spectrochim Acta A Mol Biomol Spectrosc,2013,104(3):143-149.
    [67] Mirnajafizadeh F,Ramsey D,Mcalpine S,et al.Hydrothermal synthesis of highly luminescent blue-emitting ZnSe(S)quantum dots exhibiting low toxicity[J].Materials Science&Engineering C,2016,64:167-172.
    [68] Li L,Daou T J,Texier I,et al.Highly luminescent CuInS2/ZnS Core/Shell nanocrystals:cadmium-free quantum dots for in vivo imaging[J].Chemistry of Materials,2009,21(12):2422-2429.
    [69] Panthani M G,Khan T A,Reid D K,et al.In vivo whole animal fluorescence imaging of a microparticlebased oral vaccine containing(CuInSexS2-x)/ZnS core/shell quantum dots[J].Nano Letters,2013,13(9):4294-4298.
    [70] Vinayagam J,Chen G R,Huang T Y,et al.Aqueous synthesis of CuInZnS/ZnS quantum dots by using dual stabilizers:a targeting nanoprobe for cell imaging[J].Materials Letters,2016,173:242-247.
    [71] Chen H,Zhang M,Li B,et al.Versatile antimicrobial peptide-based ZnO quantum dots for invivo bacteria diagnosis and treatment with high specificity[J].Biomaterials,2015,53(532):532-544.
    [72] Cai X,Luo Y,Zhang W,et al.pH-sensitive ZnO quantum dots-doxorubicin nanoparticles for lung cancer targeted drug delivery[J].ACS Applied Materials&Interfaces,2016,8(34):22442.
    [73] Wang Qiong,Chen Jienan,Zhang Lin.Development of quantum dot in gene transfection[J].Acta Biophysica Sinica,2013,29(1):3-14(in Chinese).王琼,陈介南,张林.量子点在基因转染中的应用研究进展[J].生物物理学报,2013,29(1):3-14.

© 2004-2018 中国地质图书馆版权所有 京ICP备05064691号 京公网安备11010802017129号

地址:北京市海淀区学院路29号 邮编:100083

电话:办公室:(+86 10)66554848;文献借阅、咨询服务、科技查新:66554700