基于二茂铁的功能材料研究
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- 英文论文题名：Functional Materials Based Upon Ferrocene
- 论文作者：瞿建 ; 吉玮 ; 李城安 ; 冯文洁 ; 景苏
- 英文论文作者：Jian Qu ; Wei Ji ; Chengan Li ; Wenjie Feng ; Su Jing ; School of Chemistry and Molecular Engineering ; Nanjing Tech University ; Institute of Advanced Materials ; Nanjing Tech University
- 年：2016
- 作者机构：南京工业大学化学与分子工程学院;南京工业大学先进材料研究院;
- 论文关键词：二茂铁 ; 硒 ; 多通道分子探针 ; 光催化
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十七分会：光化学
- 语种：中文
- 分类号：O627.81;TB34
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十七分会 ; 光化学
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：201k
- 原文格式：D
- 会议级别：全国
摘要
二茂铁及其衍生物具有低毒、易修饰、良好氧化还原活性等特殊性质,在材料、催化、生物等方面具有广阔的应用前景。本研究小组开展了基于二茂铁的多通道分子探针和光催化研究:1)含荧光基团的二茂铁硒醚可作为光电多通道传感分子,对重金属离子产生不同线性、非线性光信号和电信号组合;2)二茂铁亚铜簇合物作为敏化剂,具有可见光催化性质。
Owing to the low toxicity, high stability, easy modification and favorable redox property, ferrocene chemistry has afforded a rapid expansion.Our research group has embarked upon functional materials based on ferrocene, in the field of multichannel chemosensor and photocatalyst. 1. Ferrocenylselenoethers with fluorescent unit are designed as multichannel chemosensors to probe heavy metal cations through linear, third-order nonlinear optical and electrical signals; 2. Ferrocenyl cuprous halide clusters are designed as sensitizer for visible-light photocatalytic study.
Owing to the low toxicity, high stability, easy modification and favorable redox property, ferrocene chemistry has afforded a rapid expansion.Our research group has embarked upon functional materials based on ferrocene, in the field of multichannel chemosensor and photocatalyst. 1. Ferrocenylselenoethers with fluorescent unit are designed as multichannel chemosensors to probe heavy metal cations through linear, third-order nonlinear optical and electrical signals; 2. Ferrocenyl cuprous halide clusters are designed as sensitizer for visible-light photocatalytic study.
引文
[1]Qu,J.;Song,Y.;Ji,W.;Jing,S.;Zhu,D.;Huang,W.;Zheng,M.;Li,Y.;Ma,J.Dalton Trans.2016,45,3417.