黄牛鞋面革湿态染整清洁生产工艺研究与实践
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摘要
为提高制革湿态染整清洁生产水平,减少黄牛鞋面革鞣后湿加工产生的污染,设计了基于植物鞣剂、多金属配合鞣剂与合成鞣剂结合的无铬复鞣工艺,以及多次削匀、末端染色、无铬固色等新技术,研究结果表明,采用多金属配合鞣剂、植物鞣剂与合成鞣剂相结合的无铬复鞣工艺,坯革感官性能良好,收缩温度超过90℃,物理机械性能均符合行业标准;采用在填充工序后进行2次或3次削匀工艺,可使皮革面积得率增加、松面率降低,并减少化工材料用量;采用末端染色和无铬固色工艺,可降低染料用量,减少含铬和含染料废水污染;对提高产品品质、降低生产成本、减少环境污染具有积极的作用。
For improving the leather engineering clean production level and reducing pollution of wet process after tanning,new cleaner production techniques were designed including chromium-free retanning,twice and more shaving,dyeing at the end,and color fixing without chrome.The research results showed that the retanning with free-chrome compound metal tanning agents,vegetable tanning agent and synthetic tanning agent,the leather sensory performance was good,the shrinkage temperature over 90 ℃,and the physical and mechanical properties were in line with the industry standard;twice and more shaving can increase the leather area yield,reduce loose surface rate and reduce the consumption of the chemical materials;dyeing at the end and color fixing without chrome,can reduce the dosage of dye,reduce the pollution of wastewater containing chromium or dye;which can improve product quality,reduce production cost and reduce environmental pollution.
引文

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