氧化石墨烯/氯丁橡胶复合材料的制备及性能研究
详细信息 查看官网全文
- 论文作者：许宗超 ; 温世鹏 ; 彭同恺 ; 廖坤 ; 刘力 ; 张立群
- 年：2016
- 作者机构：北京化工大学北京市先进弹性体工程技术研究中心;北京化工大学化工资源有效利用国家重点实验室;北京化工大学有机无机复合材料国家重点实验室;北京北化新橡特种材料科技股份有限公司;
- 论文关键词：氯丁橡胶 ; 氧化石墨烯 ; 乳液复合 ; 物理性能 ; 填料分散性
- 会议召开时间：2016-04-22
- 会议录名称：“科迈杯”第12届全国橡胶助剂生产和应用技术研讨会论文集
- 语种：中文
- 分类号：TQ330.1;TB332
- 学会代码：ZGHG
- 会议名称：“科迈杯”第12届全国橡胶助剂生产和应用技术研讨会
- 会议地点：中国浙江温州
- 主办单位：中国化工学会橡胶专业委员会、全国橡胶工业信息中心
- 学会名称：中国化工学会
- 页数：5
- 文件大小：896k
- 原文格式：O
- 会议级别：全国
摘要
通过乳液复合方法制得氧化石墨烯/氯丁橡胶(CR)纳米复合材料,研究该复合材料的硫化特性、物理性能、动态力学性能和耐磨性能,并采用扫描电镜观察氧化石墨烯和无机填料在橡胶基体中的分散性。结果表明:氧化石墨烯在CR中具有良好的分散性并可改善其他无机填料的分散性,氧化石墨烯的加入可以明显改善加工安全性,提高CR的物理性能、储能模量和耐磨性能;当氧化石墨烯用量为5份时,氧化石墨烯/CR复合材料的综合性能最佳。
引文
[1]Martins A F,de Meneses S M,Visconte L L Y,et al.Mechanical and Dynamical Mechanical Properties of Chloroprene Rubber and Cellulose II.Composites[J].Journal of Applied Polymer Science,2004,92(4):2425-2430.
[2]张泗文.我国氯丁橡胶应用开发与市场前景[J].合成橡胶工业,1998,21(2):71-74.
[3]张安强,王炼石,周奕雨.CR混炼过程中焦烧性能的研究[J]_橡胶工业,2003,50(5):261-265.
[4]Geim A K,Novoselov K S.The Rise of Araphene[J].Nature Materials,2007,6(3):183-191.
[5]Eda G,Fanchini G,Chhowalla M.Large-Area Ultrathin Films of Reduced Graphene Oxide as a Transparent and Flexible Electronic Material[J].Nature Nanotechnology,2008,3(5):270-274.
[6]Loh K P,Bao Q,Eda G,et al.Graphene Oxide as a Chemically Tunable Platform for Optical Applications[J].Nature Chemistry,2010,2(12):1015-1024.
[7]Park S,Lee K S,Bozoklu G,et al.Graphene Oxide Papers Modified by Divalent Ions—Enhancing Mechanical Properties via Chemical Cross-linkingW.ACS Nano,2008,2(3):572-578.
[8]Dikin D A,Stankovich S,Zimney E J,et al.Preparation and Characterization of Graphene Oxide Paper[J].Nature,2007,448(7152):457-460.
[9]Dreyer D R,Park S,Bielawski C W,et al.The Chemistry of Graphene Oxide[J].Chemical Society Reviews,2010,39(1):228-240.
[10]Eda G,Fanchini G,Chhowalla M.Large-Area Ultrathin Films of Reduced Graphene Oxide as a Transparent and Flexible Electronic Material[J].Nature Nanotechnology,2008,3(5):270-274.
[11]唐征海,郭宝春,张立群,等.石墨烯/橡胶纳米复合材料[J].高分子学报,2014(7):865-877.
[12]Dong B,Liu C,Zhang L,et al.Preparation,Fracture,and Fatigue of Exfoliated Graphene Oxide/Natural Rubber Composites[J].RSC Advances,2015,5(22):17140-17148.
[13]Hernandez M,del Mar Bernal M,Verdejo R,et al.Overall Performance of Natural Rubber/Graphene Nanocomposites[J].Composites Science and Technology,2012,73:40-46.
[14]Zhao L,Sun X,Liu Q,et al.Natural Rubber/Graphene Oxide Nanocomposites Prepared by Latex Mixing[J].Journal of Macromolecular Science.Part B,2015,54(5):581-592.
[15]Mao Y,Wen S,Chen Y,et al.High Performance Graphene Oxide Based Rubber Composites[J].Scientific Reports,2013,3.
[16]Wu J,Huang G,Li H,et al.Enhanced Mechanical and Gas Barrier Properties of Rubber Nanocomposites with Surface Functionalized Graphene Oxide at Low Content[J].Polymer,2013,54(7):1930-1937.
[17]Potts J R.Shankar 0,Du L,et al.Processing-Morphology-Property Relationships and Composite Theory Analysis of Reduced Graphene Oxide/Natural Rubber Nanocomposites[J].Macromolecules,2012,45(15):6045-6055.
[18]Hummers Jr W S,Offeman R E.Preparation of Graphitic Oxidep].Journal of the American Chemical Society,1958,80(6):1339-1339.
[19]Hu H,Wang X,Wang J,et al.Microwave-Assisted Covalent Modification of Graphene Nanosheets with Chitosan and Its Electrorheological Characteristics[J].Applied Surface Science,2011,257(7):2637-2642.
[20]Marcano D C,Kosynkin D V,Berlin J M,et al.Improved Synthesis of Graphene Oxide[J].ACS Nano,2010,4(8):4806-4814.
[21]Pei S,Cheng H M.The Reduction of Graphene Oxide[J].Carbon,2012,50(9):3210-3228.
[22]Allahbakhsh A,Mazinani S,Kalaee M R,et al.Cure Kinetics and Chemorheology of EPDM/Graphene Oxide Nanocomposites[J].Hermochimica Acta,2013,563:22-32.
[23]Cao Y,Zhang J,Feng J,et al.Compatibilization of Immiscible Polymer Blends Using Graphene Oxide Sheets[J].ACS Nano,2011,5(7):5920-5927.
[24]Sangwichien C,Sumanatrakool P,Patarapaiboolchai O.Effect of Filler Loading on Curing Characteristics and Mechanical Properties of Thermoplastic Vulcanizate[J].Chiang Mai J.Sci.,2008,35:141-149.
[25]Xing W,Wu J,Huang G,et al.Enhanced Mechanical Properties of Graphene/Natural Rubber Nanocomposites at Low Content[J].Polymer International,2014,63(9):1674-1681.
[26]Liu X,Kuang W,Guo B.Preparation of Rubber/Graphene Oxide Composites with In-Situ Interfacial Design[J].Polymer,2015,56:553-562.
[27]Das A,Kasaliwal G R,Jurk R,et al.Rubber Composites Based on Graphene Nanoplatelets,Expanded Graphite,Carbon Nanotubes and Their Combination:A Comparative Study[J].Composites Science and Technology,2012,72(16):1961-1967.
[28]Li Y,Wang Q,Wang T,et al.Preparation and Tribological Properties of Graphene Oxide/Nitrile Rubber Nanocomposites[J].Journal of Materials Science,2012,47(2):730-738.
[2]张泗文.我国氯丁橡胶应用开发与市场前景[J].合成橡胶工业,1998,21(2):71-74.
[3]张安强,王炼石,周奕雨.CR混炼过程中焦烧性能的研究[J]_橡胶工业,2003,50(5):261-265.
[4]Geim A K,Novoselov K S.The Rise of Araphene[J].Nature Materials,2007,6(3):183-191.
[5]Eda G,Fanchini G,Chhowalla M.Large-Area Ultrathin Films of Reduced Graphene Oxide as a Transparent and Flexible Electronic Material[J].Nature Nanotechnology,2008,3(5):270-274.
[6]Loh K P,Bao Q,Eda G,et al.Graphene Oxide as a Chemically Tunable Platform for Optical Applications[J].Nature Chemistry,2010,2(12):1015-1024.
[7]Park S,Lee K S,Bozoklu G,et al.Graphene Oxide Papers Modified by Divalent Ions—Enhancing Mechanical Properties via Chemical Cross-linkingW.ACS Nano,2008,2(3):572-578.
[8]Dikin D A,Stankovich S,Zimney E J,et al.Preparation and Characterization of Graphene Oxide Paper[J].Nature,2007,448(7152):457-460.
[9]Dreyer D R,Park S,Bielawski C W,et al.The Chemistry of Graphene Oxide[J].Chemical Society Reviews,2010,39(1):228-240.
[10]Eda G,Fanchini G,Chhowalla M.Large-Area Ultrathin Films of Reduced Graphene Oxide as a Transparent and Flexible Electronic Material[J].Nature Nanotechnology,2008,3(5):270-274.
[11]唐征海,郭宝春,张立群,等.石墨烯/橡胶纳米复合材料[J].高分子学报,2014(7):865-877.
[12]Dong B,Liu C,Zhang L,et al.Preparation,Fracture,and Fatigue of Exfoliated Graphene Oxide/Natural Rubber Composites[J].RSC Advances,2015,5(22):17140-17148.
[13]Hernandez M,del Mar Bernal M,Verdejo R,et al.Overall Performance of Natural Rubber/Graphene Nanocomposites[J].Composites Science and Technology,2012,73:40-46.
[14]Zhao L,Sun X,Liu Q,et al.Natural Rubber/Graphene Oxide Nanocomposites Prepared by Latex Mixing[J].Journal of Macromolecular Science.Part B,2015,54(5):581-592.
[15]Mao Y,Wen S,Chen Y,et al.High Performance Graphene Oxide Based Rubber Composites[J].Scientific Reports,2013,3.
[16]Wu J,Huang G,Li H,et al.Enhanced Mechanical and Gas Barrier Properties of Rubber Nanocomposites with Surface Functionalized Graphene Oxide at Low Content[J].Polymer,2013,54(7):1930-1937.
[17]Potts J R.Shankar 0,Du L,et al.Processing-Morphology-Property Relationships and Composite Theory Analysis of Reduced Graphene Oxide/Natural Rubber Nanocomposites[J].Macromolecules,2012,45(15):6045-6055.
[18]Hummers Jr W S,Offeman R E.Preparation of Graphitic Oxidep].Journal of the American Chemical Society,1958,80(6):1339-1339.
[19]Hu H,Wang X,Wang J,et al.Microwave-Assisted Covalent Modification of Graphene Nanosheets with Chitosan and Its Electrorheological Characteristics[J].Applied Surface Science,2011,257(7):2637-2642.
[20]Marcano D C,Kosynkin D V,Berlin J M,et al.Improved Synthesis of Graphene Oxide[J].ACS Nano,2010,4(8):4806-4814.
[21]Pei S,Cheng H M.The Reduction of Graphene Oxide[J].Carbon,2012,50(9):3210-3228.
[22]Allahbakhsh A,Mazinani S,Kalaee M R,et al.Cure Kinetics and Chemorheology of EPDM/Graphene Oxide Nanocomposites[J].Hermochimica Acta,2013,563:22-32.
[23]Cao Y,Zhang J,Feng J,et al.Compatibilization of Immiscible Polymer Blends Using Graphene Oxide Sheets[J].ACS Nano,2011,5(7):5920-5927.
[24]Sangwichien C,Sumanatrakool P,Patarapaiboolchai O.Effect of Filler Loading on Curing Characteristics and Mechanical Properties of Thermoplastic Vulcanizate[J].Chiang Mai J.Sci.,2008,35:141-149.
[25]Xing W,Wu J,Huang G,et al.Enhanced Mechanical Properties of Graphene/Natural Rubber Nanocomposites at Low Content[J].Polymer International,2014,63(9):1674-1681.
[26]Liu X,Kuang W,Guo B.Preparation of Rubber/Graphene Oxide Composites with In-Situ Interfacial Design[J].Polymer,2015,56:553-562.
[27]Das A,Kasaliwal G R,Jurk R,et al.Rubber Composites Based on Graphene Nanoplatelets,Expanded Graphite,Carbon Nanotubes and Their Combination:A Comparative Study[J].Composites Science and Technology,2012,72(16):1961-1967.
[28]Li Y,Wang Q,Wang T,et al.Preparation and Tribological Properties of Graphene Oxide/Nitrile Rubber Nanocomposites[J].Journal of Materials Science,2012,47(2):730-738.