通过配体中心的电荷转移和配体间π–π相互作用的白光发射氮唑MOF
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- 英文论文题名：An Azole-Based Metal-Organic Framework toward Direct White-Light Emissions by the Synergism of Ligand-Centered Charge Transfer and Interligand π–π Interactions
- 论文作者：李荣 ; 郑发鲲
- 英文论文作者：Rong Li ; Fa-Kun Zheng ; State Key Laboratory of Structural Chemistry ; Fujian Institute of Research on the Structure of Matter ; Chinese Academy of Sciences
- 年：2016
- 作者机构：中科院福建物质结构研究所;
- 论文关键词：氮唑 ; MOF ; π–π相互作用 ; 可调发光 ; 白光发射
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第十六分会：晶体工程
- 语种：中文
- 分类号：O641.4
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第十六分会 ; 晶体工程
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：377k
- 原文格式：D
- 会议级别：全国
摘要
通过4-四氮唑-5-苯基-2,2':6',2"-三联吡啶和CdBr_2·4H_2O的水热反应合成了一例氮唑MOF[Cd(tzphtpy)_2]n·6.5nH_2O,它可以通过调节激发波长来调节蓝黄互补色的相对强度在一个很宽的范围内(286-386 nm)获得白光发射。这是首次在氮唑MOFs中使用配体中心的电荷转移和配体间π-π相互作用获得白光发射,我们的工作为获得氮唑或其他体系的白光发射材料提供了新的合成策略
An azole-based metal-organic framework[Cd(tzphtpy)_2]n·6.5nH_2O,hydrothermally synthesized from the reaction mixture of an azole ligand 4-(tetrazol-5-y1)phenyl-2,2':6',2"-terpyridine(Htzphtpy) and CdBr_2·4H_2O,displays direct white-light emissions at a wide range of excitation wavelengths(286-386 nm) through modulating the relative intensity of two complementary colors(blue and yellow).The synergism of ligand-centered charge transfer and interligand π-π interactions is firstly found in white-light emitting azole-based MOFs.Our work provides a new synthetic strategy for azole-based or other systems white-light emitting materials.
An azole-based metal-organic framework[Cd(tzphtpy)_2]n·6.5nH_2O,hydrothermally synthesized from the reaction mixture of an azole ligand 4-(tetrazol-5-y1)phenyl-2,2':6',2"-terpyridine(Htzphtpy) and CdBr_2·4H_2O,displays direct white-light emissions at a wide range of excitation wavelengths(286-386 nm) through modulating the relative intensity of two complementary colors(blue and yellow).The synergism of ligand-centered charge transfer and interligand π-π interactions is firstly found in white-light emitting azole-based MOFs.Our work provides a new synthetic strategy for azole-based or other systems white-light emitting materials.
引文
[1]Wang,M.-S.;Guo,S.-P.;Li,Y.;Cai,L.-Z.;Zou,J.-P.;Xu,G.;Zhou,W.-W.;Zheng,F.-K.;Guo,G.-C.J.Am.Chem.Soc.,2009,131:13572.
[2]Wu,Z.-F.;Tan,B.;Wang,J.-Y.;Du,C.-F.;Deng,Z.-H.;Huang,X.-Y.Chem.Commun.,2015,51:157.
[2]Wu,Z.-F.;Tan,B.;Wang,J.-Y.;Du,C.-F.;Deng,Z.-H.;Huang,X.-Y.Chem.Commun.,2015,51:157.