水性聚氨酯灌浆材料的制备
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- 英文论文题名：Preparation Development of Waterborne Polyurethane Grouting Materials
- 论文作者：李朋 ; 莫永金 ; 卢胜强 ; 魏柳荷 ; 张永胜 ; 刘锋
- 英文论文作者：LI Peng ; MUO Yongjin ; LU Shengqiang ; WEI Liuhe ; ZHANG Yongsheng ; LIU Feng ; Laboratory of Functional Materials ; College of Chemistry and Molecular Engineering of Zhengzhou University
- 年：2016
- 作者机构：郑州大学化学与分子工程学院郑州市弹性密封材料重点实验室;
- 论文关键词：聚氨酯 ; 灌浆材料 ; MDI-50
- 英文论文关键词：polyurethane ; grouting material ; MDI-50
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TV44
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：5
- 文件大小：1385k
- 原文格式：D
- 会议级别：全国
摘要
以低毒不易挥发的二苯基甲烷二异氰酸酯(MDI-50)代替甲苯-2,4-二异氰酸酯(TDI)为原料,与亲水性聚醚多元醇反应合成聚氨酯预聚体,再配以添加剂制备得到环保型水性聚氨酯灌浆材料。通过探究NCO基含量对浆液密度、黏度、遇水膨胀率的影响确定了最佳投料比,研究了催化剂、缓凝剂种类和用量对浆液凝胶时间的影响,确定了最佳催化剂及缓凝剂的种类和用量,制备出的浆液活性较高,性能良好。
Environmentally friendly waterborne polyurethane grouting material was prepared from some additives and polyurethane prepolymer which were synthesized using hydrophilic polyols and 4,4'-diphenylmethane diisocyanate(MDI)with low toxicity instead of toluene diisocyanate(TDI).The effects of the-NCO content on the density,viscosity and the water expansion rate were explored,the optimal inventory ratio was confirmed.Then we explored the influence of the kinds and amounts of the catalyst and retarder on the gel time of the slurry.The optimal kind and amount of the catalyst and retarder were confimed.The activity and the performance of the slurry were preferably.
Environmentally friendly waterborne polyurethane grouting material was prepared from some additives and polyurethane prepolymer which were synthesized using hydrophilic polyols and 4,4'-diphenylmethane diisocyanate(MDI)with low toxicity instead of toluene diisocyanate(TDI).The effects of the-NCO content on the density,viscosity and the water expansion rate were explored,the optimal inventory ratio was confirmed.Then we explored the influence of the kinds and amounts of the catalyst and retarder on the gel time of the slurry.The optimal kind and amount of the catalyst and retarder were confimed.The activity and the performance of the slurry were preferably.
引文
[1]刘益军,赵晖,黄国泓,等.聚氨酯灌浆材料评述[C].上海:中国聚氨酯工业协会第十二次年会论文集,中国聚氨酯工业协会年会.2004.:189-191,1.
[2]化学灌浆技术专题报道.全国防水材料技术交流大会[C].2013.
[3]赵晖,何凤,刘益军,等.水溶性聚氨酯化学灌浆材料的研制[J].化工新型材料,2005,33(8):61-63.
[4]范兆荣,刘运学,谷亚新,等.水性单组份聚氨酯灌浆材料的研制[J].中国胶黏剂,2007,16(22):36-38.
[5]秦道川.水性聚氨酯灌浆材料发展探讨[J].中国建筑防水,2014(21):17-22.
[6]戴进峰,李斌.水溶性聚氨酯堵料制备与性能表征[J].化学与黏合,2007,29(1):23-26.
[7]贺荣.MDI型水性聚氨酯的合成、表征及性能研究[D].广州:华南理工大学,2014.
[8]中华人民共和国建材行业标准JC/T2041-2010[Z].2010-11-22.
[9]刘玉亭,孙德文,冉千平等.高性能水活性聚氨酯灌浆堵漏材料的制备与性能研究[J].中国建筑防水,2015(1):11-14.
[10]郑先军,李红英,伊善科.单组份水溶性聚氨酯灌浆材料研究[J].新型建筑材料,2013,40(8):59-64.
[11]傅明源,孙酣经.聚氨酯弹性体及其应用[M].北京:化学工业出版社,2006.
[2]化学灌浆技术专题报道.全国防水材料技术交流大会[C].2013.
[3]赵晖,何凤,刘益军,等.水溶性聚氨酯化学灌浆材料的研制[J].化工新型材料,2005,33(8):61-63.
[4]范兆荣,刘运学,谷亚新,等.水性单组份聚氨酯灌浆材料的研制[J].中国胶黏剂,2007,16(22):36-38.
[5]秦道川.水性聚氨酯灌浆材料发展探讨[J].中国建筑防水,2014(21):17-22.
[6]戴进峰,李斌.水溶性聚氨酯堵料制备与性能表征[J].化学与黏合,2007,29(1):23-26.
[7]贺荣.MDI型水性聚氨酯的合成、表征及性能研究[D].广州:华南理工大学,2014.
[8]中华人民共和国建材行业标准JC/T2041-2010[Z].2010-11-22.
[9]刘玉亭,孙德文,冉千平等.高性能水活性聚氨酯灌浆堵漏材料的制备与性能研究[J].中国建筑防水,2015(1):11-14.
[10]郑先军,李红英,伊善科.单组份水溶性聚氨酯灌浆材料研究[J].新型建筑材料,2013,40(8):59-64.
[11]傅明源,孙酣经.聚氨酯弹性体及其应用[M].北京:化学工业出版社,2006.