由TCNQ构筑、具有导电特性的层状分子磁体
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- 英文论文题名：Novel molecule-based magnet with layered topology constructed by TCNQ
- 论文作者：孔明 ; 韩媛 ; 宋友
- 英文论文作者：Ming Kong ; Yuan Han ; You Song ; School of Chemistry and Chemical Engineering ; State Key Lab of Coordination Chemistry ; Nanjing University
- 年：2016
- 作者机构：南京大学化学化工学院配位化学国家重点实验室;
- 论文关键词：分子磁体 ; 导电性 ; TCNQ ; 自旋交叉
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第十六分会：晶体工程
- 语种：中文
- 分类号：TN304
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第十六分会 ; 晶体工程
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：266k
- 原文格式：D
- 会议级别：全国
摘要
多功能的分子基材料鉴于其在特殊的光、电和磁性等方面的应用,受到了人们广泛的关注。最近,具有导体/半导体特性的分子磁性材料逐渐走入人们的视野~([1-3])。传统的无机固体材料中,在同一个晶格中想要构建具有协同效应的化合物比如导电和磁性比较困难,而通过设计新型的分子基磁性材料与有机自由基形成共晶,得到了一系列的自旋交叉半导体材料。构筑基元包括对称性的金属(铁、钌、镍和铜)三联吡啶配合物阳离子和带部分负电荷的TCNQ。对其构效关系进行了深入的研究。这些研究对电磁协同效应的探索提出新的思路。
The development of multifunctional molecular-based materials with special optical,conductive and magnetic property has been paid more and more attention.Among these materials,such this novel molecular magnet exhibiting conductivity is now coming to our eyes.For the difficulty to construct materials possessing both conductivity and magnetic ordering in traditional inorganic materials,we now synthesized a series of spin-crossover semiconductor materials combined terpyridyl coordination compounds with TCNQ.The relationships between structures and properties were explored in-depth.
The development of multifunctional molecular-based materials with special optical,conductive and magnetic property has been paid more and more attention.Among these materials,such this novel molecular magnet exhibiting conductivity is now coming to our eyes.For the difficulty to construct materials possessing both conductivity and magnetic ordering in traditional inorganic materials,we now synthesized a series of spin-crossover semiconductor materials combined terpyridyl coordination compounds with TCNQ.The relationships between structures and properties were explored in-depth.
引文
[1]Coronado,E.;Galan-Mascaros,J.;Gomez-Garcia,C.;Laukhin,V.Nature.2000,408:447.
[2]Phan,H.;Benjamin,S.;Steven,E.;Brooks,J.Angew.Chem.Int.Ed.2015,54:823.
[3]Zhang,X.;Wang,Z.;Xie,H.;Li,M.Chem.Sci.2016,7:1569.
[2]Phan,H.;Benjamin,S.;Steven,E.;Brooks,J.Angew.Chem.Int.Ed.2015,54:823.
[3]Zhang,X.;Wang,Z.;Xie,H.;Li,M.Chem.Sci.2016,7:1569.