pH敏感型凝胶微球的发展及其在缓蚀剂中的应用
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- 英文论文题名：Development of pH Sensitive Polymeric Microspheres and Application in Corrosion Inhibitors as Carriers
- 论文作者：王春 ; 杨怀玉
- 英文论文作者：WANG Chun ; YANG Huai-yu ; State Key Laboratory for Corrosion and Protection ; Institute of Metal Research ; Chinese Academic of Sciences
- 年：2012
- 作者机构：中国科学院金属研究所金属腐蚀与防护国家重点实验室;
- 论文关键词：pH敏感性 ; 微球 ; 缓蚀剂
- 英文论文关键词：pH sensitivity ; microsphere ; corrosion inhibitor
- 会议召开时间：2012-07-25
- 会议录名称：第十七届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TQ427.26;TG174.42
- 学会代码：ZGHA
- 会议名称：第十七届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国重庆
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：4
- 文件大小：326k
- 原文格式：O
- 会议级别：全国
摘要
pH敏感型材料因其在缓释控释方面的优势受到越来越多的关注。本文介绍了pH敏感型材料的响应机制、重点介绍了pH敏感型微球的制备和药物包覆方式。并展望了pH敏感型凝胶微球包覆缓蚀剂的应用前景。
As its advantages in controlled release,pH sensitive material has gained more and more attention and offers a promising route to controlled release inhibitors.In this paper,synthesis and drug coating methods of pH sensitivie microspheres,as well as the response mechanism of pH sensitive materials were reviewed.The developing trend of its application in controlled release inhibitors was also given.
As its advantages in controlled release,pH sensitive material has gained more and more attention and offers a promising route to controlled release inhibitors.In this paper,synthesis and drug coating methods of pH sensitivie microspheres,as well as the response mechanism of pH sensitive materials were reviewed.The developing trend of its application in controlled release inhibitors was also given.
引文
[1]郑家燊,黄魁元.缓蚀剂科技发展历程的回顾与展望[J].材料保护,2000,33(5):11-15.
[2]王慧龙,郑家燊.环境友好缓蚀剂的研究进展[J].腐蚀科学与防护技术,2002,14(5):275-279.
[3]邓书端,李向红,付惠.几种植物叶提取物对铝的缓蚀性能研究[J].林产化学与工业,2011(3):65-70.
[4]王超,陶蕾,秦立娟,等.一种用于中碱中硬度水质的无磷缓蚀剂的应用研究[C]//第6届中国全国腐蚀大会.银川:2011:258-260.
[5]杨怀玉,朱澄云,汪黎.环境友好缓释微球的制备及释放机制[J].材料保护,2006,39(增刊):33-35.
[6]杨玉霞,杨怀玉.pH敏感型智能材料的研究进展及其在缓蚀剂中的应用[J].腐蚀与防护,2010,31(增刊):221-224.
[7]Dong L C,Yan Q,Hoffman A S.Controlled release of amylase from a thermal and Ph-sensitive,macroporous hydrogel[J].Control Release,1992,19(1-3):171-177.
[8]Soni M L,Namdeo K P,Jain,et al.pH-enzyme Didependent chronotherapeutic drug delivery system of theophylline for nocturnal asthma[J].Chemical&Pharmaceutical Bulletin,2011,59(2):191-195.
[9]陆大年,陈士安,鲍景旦,等.丙烯酸水凝胶的pH敏感性研究[J].华东理工大学学报,1994,20(6):818-823.
[10]Ni H M,Kawaguchi H,Endo T.Characteristics of pH-sensitive hydrogel microsphere of poly(acrylamide-co-meth acrylic acid)with sharp pH-volume transition[J].Colloid Polym Sci,2007,285(8):873-879.
[11]刘晓华,王晓工,刘德山.快速响应的温敏性聚(N-异丙基丙烯酰胺)水凝胶Ⅰ.以CaCO_3为成孔剂制备方法、表征及动力学研究[J].高分子学报,2002(3):354-357.
[12]徐雅玲,李宝芳,曹堃,等.粒状温敏性水凝胶的溶胀行为[J].高校化学工程学报,2004,18(6):762-765.
[13]Wu X S,Hoffman A S,Yager P.Synthesis and characterization of thermally reversible macroporous poly(n-isopropylacrylamide)hydrogels[J].Polym Sci Pol Chem,1992,30(10):2121-2129.
[14]周英辉,黄明智.明胶/海藻酸钠复合体系用于pH敏感智能药物释放体系的研究[J].北京化工大学学报(自然科学版),2003,30(5):75-78.
[15]Quan J S,Jiang H L,Kim E M,et al.pH-sensitive and mucoadhesive thiolated eudragit-coated chitosan microspheres[J].Int J Pharm,2008,359(1-2):205-210.
[16]Wu J,Wei W,Wang L Y,et al.Preparation of uniform-sized pH-sensitive quaternized chitosan microsphere by combining membrane emulsification technique and thermal-gelation method[J].Colloid Surface B,2008,63(2).164-175.
[17]岳斌,吴承训.聚丙烯酰胺水凝胶的PH敏感性研究[J].合成技术及应用,2006(1):8-11.
[18]李晓岚,冯玉军,孙静,等.聚丙烯酰胺微球制备工艺研究进展[J].精细石油化工进展,2009,10(5):48-54.
[19]毕淑娴,雷忠利.聚丙烯酰胺反相悬浮聚合的研究[J].陕西师范大学学报(自然科学版),2006,34(1):63-66.
[20]郭锦棠,提岩,李丽娜,等.pH敏感聚衣康酸/丙烯酰胺水凝胶微球的制备与性能[J].天津大学学报,2007,40(4):427-431.
[21]贾文娟.药物缓释微球的制备、表征及性能研究[D].成都四川大学大雨学位论文,2007:4-5.
[22]Dry C,Corsaw M.A time-release technique for corrosion prevention[J].Cement and Concrete Research,1998,28(8):1133-1140.
[23]匡飞,王佳,贾方,等.亚硝酸钠微胶囊缓蚀剂研究[J].腐蚀科学与防护技术,2009,21(2):173-175.
[24]杨玉霞,杨怀玉.聚丙烯酸类水凝胶的制备及其在碱性溶液中的pH敏感性[J].材料研究学报,2012,26(1):85-90.
[2]王慧龙,郑家燊.环境友好缓蚀剂的研究进展[J].腐蚀科学与防护技术,2002,14(5):275-279.
[3]邓书端,李向红,付惠.几种植物叶提取物对铝的缓蚀性能研究[J].林产化学与工业,2011(3):65-70.
[4]王超,陶蕾,秦立娟,等.一种用于中碱中硬度水质的无磷缓蚀剂的应用研究[C]//第6届中国全国腐蚀大会.银川:2011:258-260.
[5]杨怀玉,朱澄云,汪黎.环境友好缓释微球的制备及释放机制[J].材料保护,2006,39(增刊):33-35.
[6]杨玉霞,杨怀玉.pH敏感型智能材料的研究进展及其在缓蚀剂中的应用[J].腐蚀与防护,2010,31(增刊):221-224.
[7]Dong L C,Yan Q,Hoffman A S.Controlled release of amylase from a thermal and Ph-sensitive,macroporous hydrogel[J].Control Release,1992,19(1-3):171-177.
[8]Soni M L,Namdeo K P,Jain,et al.pH-enzyme Didependent chronotherapeutic drug delivery system of theophylline for nocturnal asthma[J].Chemical&Pharmaceutical Bulletin,2011,59(2):191-195.
[9]陆大年,陈士安,鲍景旦,等.丙烯酸水凝胶的pH敏感性研究[J].华东理工大学学报,1994,20(6):818-823.
[10]Ni H M,Kawaguchi H,Endo T.Characteristics of pH-sensitive hydrogel microsphere of poly(acrylamide-co-meth acrylic acid)with sharp pH-volume transition[J].Colloid Polym Sci,2007,285(8):873-879.
[11]刘晓华,王晓工,刘德山.快速响应的温敏性聚(N-异丙基丙烯酰胺)水凝胶Ⅰ.以CaCO_3为成孔剂制备方法、表征及动力学研究[J].高分子学报,2002(3):354-357.
[12]徐雅玲,李宝芳,曹堃,等.粒状温敏性水凝胶的溶胀行为[J].高校化学工程学报,2004,18(6):762-765.
[13]Wu X S,Hoffman A S,Yager P.Synthesis and characterization of thermally reversible macroporous poly(n-isopropylacrylamide)hydrogels[J].Polym Sci Pol Chem,1992,30(10):2121-2129.
[14]周英辉,黄明智.明胶/海藻酸钠复合体系用于pH敏感智能药物释放体系的研究[J].北京化工大学学报(自然科学版),2003,30(5):75-78.
[15]Quan J S,Jiang H L,Kim E M,et al.pH-sensitive and mucoadhesive thiolated eudragit-coated chitosan microspheres[J].Int J Pharm,2008,359(1-2):205-210.
[16]Wu J,Wei W,Wang L Y,et al.Preparation of uniform-sized pH-sensitive quaternized chitosan microsphere by combining membrane emulsification technique and thermal-gelation method[J].Colloid Surface B,2008,63(2).164-175.
[17]岳斌,吴承训.聚丙烯酰胺水凝胶的PH敏感性研究[J].合成技术及应用,2006(1):8-11.
[18]李晓岚,冯玉军,孙静,等.聚丙烯酰胺微球制备工艺研究进展[J].精细石油化工进展,2009,10(5):48-54.
[19]毕淑娴,雷忠利.聚丙烯酰胺反相悬浮聚合的研究[J].陕西师范大学学报(自然科学版),2006,34(1):63-66.
[20]郭锦棠,提岩,李丽娜,等.pH敏感聚衣康酸/丙烯酰胺水凝胶微球的制备与性能[J].天津大学学报,2007,40(4):427-431.
[21]贾文娟.药物缓释微球的制备、表征及性能研究[D].成都四川大学大雨学位论文,2007:4-5.
[22]Dry C,Corsaw M.A time-release technique for corrosion prevention[J].Cement and Concrete Research,1998,28(8):1133-1140.
[23]匡飞,王佳,贾方,等.亚硝酸钠微胶囊缓蚀剂研究[J].腐蚀科学与防护技术,2009,21(2):173-175.
[24]杨玉霞,杨怀玉.聚丙烯酸类水凝胶的制备及其在碱性溶液中的pH敏感性[J].材料研究学报,2012,26(1):85-90.