基于吩噻嗪的红色有机发光材料
详细信息 查看官网全文
- 英文论文题名：Red organic light-emitting material based on phenothiazine
- 论文作者：汤小辉 ; 刘海超 ; 杨兵
- 英文论文作者：XiaoHui Tang ; HaiChao Liu ; Bing Yang ; State Key Laboratory of Supramolecular Structure and Materials ; Jilin University
- 年：2016
- 作者机构：吉林大学超分子结构与材料国家重点实验室;
- 论文关键词：吩噻嗪 ; 芴酮 ; 发光材料
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十一分会：π-共轭材料
- 语种：中文
- 分类号：TQ422
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：98k
- 原文格式：O
- 会议级别：全国
摘要
近三十年,有机电致发光(OLED)在理论研究、材料开发、期间制备工艺等各方面都取得了迅速的发展。OLED在显示及信息领域具有巨大的潜力,但是由于红光、蓝光材料的缺乏,导致OLED距离实用化程度仍有很大的差距。由于红光的带隙比较窄,因此红光激发态能量很容易通过非辐射跃迁的形式而耗损。~([1-2])设计红光材料常用的方法是合成具有电荷转移性质的给受体化合物和合成具有大的π体系的共轭稠环化合物。吩噻嗪类(PTZ)化合物是一个很好的电子给体,与芴酮的2、7号位利用SUZUKI反应进行偶联,得到了M1和M2。两种材料分别是橙黄光和红光的聚集诱导发光材料。粉末的最大发射峰位分别为556nm和660nm。
Organic light-emitting diodes(OLEDs) have found great success in theoretical researchs and materials over the past two decades.Organic light-emitting diodes(OLEDs) has advatages which has its promising in flat-panel displays and soild-state lighting applications.Red fluorescent molecules suffer from large,non-radiative internal conversion rates(k_(IC)) governed by the energy gap law.Herein,we have designed organic π-conjugated compounds with donor-acceptor(D-A) structres which developed intramolecular-charge-transfer molecules M1,M2 through Suzuki reaction,M1 and M2.The powders of M1,M2 exhibits a PL maximun peak at 556 nm and 660 nm,which M2 may be a promising red organic light-emitting material.
Organic light-emitting diodes(OLEDs) have found great success in theoretical researchs and materials over the past two decades.Organic light-emitting diodes(OLEDs) has advatages which has its promising in flat-panel displays and soild-state lighting applications.Red fluorescent molecules suffer from large,non-radiative internal conversion rates(k_(IC)) governed by the energy gap law.Herein,we have designed organic π-conjugated compounds with donor-acceptor(D-A) structres which developed intramolecular-charge-transfer molecules M1,M2 through Suzuki reaction,M1 and M2.The powders of M1,M2 exhibits a PL maximun peak at 556 nm and 660 nm,which M2 may be a promising red organic light-emitting material.
引文
[1]Liu,HC;Yang,B.;Ma,YG.Chem.Sci.2015,6:3797.
[2]Yao,L.;Yang,B.;Ma,YG.Angew Chem Inter Ed.2014,53:2119.
[2]Yao,L.;Yang,B.;Ma,YG.Angew Chem Inter Ed.2014,53:2119.