光限幅性能增强的铂配合物功能化石墨烯杂化材料
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- 英文论文题名：Enhanced Optical Limiting Property of Graphene Hybrid Materials Functionalized by Pt Complexes
- 论文作者：胡锦阳 ; 刘睿 ; 舒明良 ; 朱森强 ; 朱红军
- 英文论文作者：Jinyang Hu ; Rui Liu ; Mingliang Shu ; Senqiang Zhu ; Hongjun Zhu ; College of Chemistry and Molecular Engineering ; Nanjing Tech University
- 年：2016
- 作者机构：南京工业大学化学与分子工程学院;
- 论文关键词：氧化石墨烯 ; 铂配合物 ; 光限幅
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十一分会：π-共轭材料
- 语种：中文
- 分类号：O641.4;O613.71
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：170k
- 原文格式：O
- 会议级别：全国
摘要
通过共价键和静电吸附方式分别制备了两种可溶性的氧化石墨烯-铂配合物杂化材料并经FT-IR、XPS、XRD、HRTEM、AFM、TGA、Raman光谱、紫外-可见吸收和荧光发射光谱对杂化材料的微观结构、形态及光物理性质进行了系统表征。Z-扫描与光限幅测试结果表明:与单一材料相比,铂配合物修饰的氧化石墨烯杂化材料可以有效地提高材料的光限幅性能,其原因归结为非线性散射、非线性吸收、以及从铂配合物到氧化石墨烯光诱导电子或能量转移的协同作用。
Two new graphene oxide(GO)-Pt complex hybrid materials were prepared by covalent functionalization and electrostatic adsorption.The microscopic structure,morphology,and photophysical properties of the resulting hybrid materials were characterized by FT-IR,XPS,XRD,HRTEM,AFM,TGA,Raman spectroscopic techniques, UV-Vis absorption and steady-state fluorescence.The nonlinear optical properties and optical limiting performance of GO,Pt complexes,and GO-Pt hybrid materials were investigated using Z-scan measurements at 532 nm with 4 ns laser pulses.The results show that the efficient functionalization of GO makes GO-Pt hybrid materials possess much better NLO properties and optical limiting performance than those of GO and Pt complexes alone,which was ascribed to a combination of nonlinear scattering,nonlinear absorption and photoinduced electron or energy transfer from the electron donor Pt complex moiety to the acceptor graphene oxide.
Two new graphene oxide(GO)-Pt complex hybrid materials were prepared by covalent functionalization and electrostatic adsorption.The microscopic structure,morphology,and photophysical properties of the resulting hybrid materials were characterized by FT-IR,XPS,XRD,HRTEM,AFM,TGA,Raman spectroscopic techniques, UV-Vis absorption and steady-state fluorescence.The nonlinear optical properties and optical limiting performance of GO,Pt complexes,and GO-Pt hybrid materials were investigated using Z-scan measurements at 532 nm with 4 ns laser pulses.The results show that the efficient functionalization of GO makes GO-Pt hybrid materials possess much better NLO properties and optical limiting performance than those of GO and Pt complexes alone,which was ascribed to a combination of nonlinear scattering,nonlinear absorption and photoinduced electron or energy transfer from the electron donor Pt complex moiety to the acceptor graphene oxide.
引文
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3.Liu,R.;Li,Y J.;Li,Y H.;Zhu,H.J.;Sun,W F.J.Phys.Chem.A 2010,114:12639.