零ODP、低GWP的聚氨酯环保发泡剂Opteon 1100
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- 英文论文题名：Zero ODP and Low GWP Polyurethane Environment Friendly Blowing Agent Opteon 1100
- 论文作者：李江屏 ; LOH G ; CREAZZO J A ; RUBIN M L ; ATA S A
- 英文论文作者：LI Jiangpin ; LOH G ; CREAZZO J A ; RUBIN M L ; ATA S A ; The Chemours Chemical(Shanghai) Co.Ltd ; The Chemours Company FC ; LCC
- 年：2016
- 作者机构：科慕化学上海有限公司;科慕化学有限公司;
- 论文关键词：Opteon 1100 ; 六氟丁烯 ; 硬质聚氨酯泡沫塑料 ; 发泡剂 ; 保温性能
- 英文论文关键词：Opteon 1100 ; hexafluorobutene ; rigid polyurethane foam ; blowing agent ; insulation performance
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TQ314.259
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：7
- 文件大小：1148k
- 原文格式：D
- 会议级别：全国
摘要
科慕公司开发的新型发泡剂Opteon 1100(HFO-1336mzz、六氟丁烯)具有零ODP、低GWP,属于第四代发泡剂,具有环保性、优异的性能表现和低的转换成本的最佳性能组合。主要介绍了近期在实验中取得的一系列的研究成果和客户的评价结果,包括物理和化学稳定性,用于聚氨酯硬泡的保温性能和泡沫的其它性能。
The new blowing agent Opteon 1100(HFO-1336 mzzZ,hexafluorobutene) developed by Chemours has unique characteristics such as zero ODP,low GWP,non-VOC,non-flammability,and suitable boiling point.It is the fourth generation blowing agent provides a balanced option for environmental sustainability,excellent performance and low-cost conversion.The results from recent laboratory studies and customer evaluations,including physical and chemical stability,insulation performance and other properties of rigid polyurethane foam are introduced in this paper.
The new blowing agent Opteon 1100(HFO-1336 mzzZ,hexafluorobutene) developed by Chemours has unique characteristics such as zero ODP,low GWP,non-VOC,non-flammability,and suitable boiling point.It is the fourth generation blowing agent provides a balanced option for environmental sustainability,excellent performance and low-cost conversion.The results from recent laboratory studies and customer evaluations,including physical and chemical stability,insulation performance and other properties of rigid polyurethane foam are introduced in this paper.
引文
[1]BAASANDORJ M,RAVISHANKARA A R,BURKHOLDER J B.Atmospheric chemistry of(Z)-CFCH=CHCF:OH radical reaction rate coefficient and global warming potential[J].Journal of Physical Chemistry:A,2011,115(38):10539-10549.
[2]CARTER W P L.Estimation of the Ground-Level Atmospheric Ozone Formation Potential of cis-1,1,1,4,4,4-Hexafluoro-2-butene.Draft Report to DuPont,2011-07-22.
[3]California Office of Administrative Law(OAL),Final Regulation Order:Amendments to the Tables of Maximum Incremental Reactivity(MIR),Values,3 September 2010;available at http://www.arb.ca.gov/research/reactivity/regulation.htm
[4]Federal Register,2008,73(57):15607.2008-03-24.
[5]RICHARD G D,MICHAEL E J,SANDRA S.Photochemical ozone creation potentials for organic compounds in northwest Europe calculated with a master chemical mechanism,Atmosphere Environ,1998,32(14):2429.
[6]WALLINGTON T J,ANDERSEN M P S,NIELSEN O J,et.al.Estimated photo chemical ozone creation potentials(POCPs)of CFCF=CH(HFO-1234yf)and related hydrofluoroolefins(HFOs),Atmos Environ,2010,44:1478.
[7]LOH G,CREAZZO J,ROBIN M L.Continued development of FEA-1100 a zero ODP and low GWP Foam expansion agent with desired properties[C].Nashville,TN,USA:Proceedings of Polyurethanes 2011 Technical Conference,2011.
[8]LOH G,CREAZZO J,ROBIN M L.Further development of low GWP foam expansion agent with improved insulating performance vs commercially available options today[C].Cologne,Germany:Proceedings of 12th Blowing Agents and Foaming Process,2010.
[9]ROSE M,ALTOE P,PARENTIV,et al.Assessment of Formacel 1100(FEA-1100)blowing agent in rigid polyurethane insulating foams for domestic appliance.USA:Proceedings of Polyurethane Technical Conference,2012.
[2]CARTER W P L.Estimation of the Ground-Level Atmospheric Ozone Formation Potential of cis-1,1,1,4,4,4-Hexafluoro-2-butene.Draft Report to DuPont,2011-07-22.
[3]California Office of Administrative Law(OAL),Final Regulation Order:Amendments to the Tables of Maximum Incremental Reactivity(MIR),Values,3 September 2010;available at http://www.arb.ca.gov/research/reactivity/regulation.htm
[4]Federal Register,2008,73(57):15607.2008-03-24.
[5]RICHARD G D,MICHAEL E J,SANDRA S.Photochemical ozone creation potentials for organic compounds in northwest Europe calculated with a master chemical mechanism,Atmosphere Environ,1998,32(14):2429.
[6]WALLINGTON T J,ANDERSEN M P S,NIELSEN O J,et.al.Estimated photo chemical ozone creation potentials(POCPs)of CFCF=CH(HFO-1234yf)and related hydrofluoroolefins(HFOs),Atmos Environ,2010,44:1478.
[7]LOH G,CREAZZO J,ROBIN M L.Continued development of FEA-1100 a zero ODP and low GWP Foam expansion agent with desired properties[C].Nashville,TN,USA:Proceedings of Polyurethanes 2011 Technical Conference,2011.
[8]LOH G,CREAZZO J,ROBIN M L.Further development of low GWP foam expansion agent with improved insulating performance vs commercially available options today[C].Cologne,Germany:Proceedings of 12th Blowing Agents and Foaming Process,2010.
[9]ROSE M,ALTOE P,PARENTIV,et al.Assessment of Formacel 1100(FEA-1100)blowing agent in rigid polyurethane insulating foams for domestic appliance.USA:Proceedings of Polyurethane Technical Conference,2012.