新型磷腈盐类催化剂及其在合成聚醚多元醇中的应用
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- 英文论文题名：Novel Phosphazenium Catalysts and Their Applications in Preparation of Polyether Polyol
- 论文作者：于剑昆 ; 张俊良 ; 吕国会
- 英文论文作者：YU Jiankun ; ZHANG Junliang ; LYU Guohui ; Liming Research & Design Institute of Chemical Industry Co.Ltd. ; China Polyurethane Industry Association
- 年：2016
- 作者机构：黎明化工研究设计院有限责任公司;中国聚氨酯工业协会;
- 论文关键词：聚醚多元醇 ; 磷腈盐 ; 氧化磷腈 ; 环氧丙烷 ; 聚氨酯
- 英文论文关键词：polyether polyol ; phosphazenium ; phosphazene oxide ; propylene oxide ; polyurethane
- 会议召开时间：2016-07-30
- 会议录名称：中国聚氨酯工业协会第十八次年会论文集
- 语种：中文
- 分类号：TQ314.242
- 学会代码：JAZG
- 会议名称：中国聚氨酯工业协会第十八次年会
- 会议地点：中国上海
- 主办单位：中国聚氨酯工业协会
- 学会名称：中国聚氨酯工业协会
- 页数：8
- 文件大小：1140k
- 原文格式：D
- 会议级别：全国
摘要
介绍了东曹公司新型磷腈盐(PZN)催化剂的结构、合成工艺及其作为催化剂在制备聚醚多元醇(PPG)中的使用情况,以及该类催化剂的脱除与回收方法。此外,还介绍了新型氧化磷腈(PZO)催化剂的合成及其作为催化剂制备PPG的工艺。通过与传统的KOH催化剂和双金属氰化物(DMC)催化剂进行对比,指出PZN类催化剂是一类极具发展潜力的合成PPG用新型催化剂。
The structure,preparation processes of novel phosphazenium(PZN) catalysts from Tosoh Corp and their application situation in preparation of poly ether polyol(PPG) as catalyst are introduced in detail.The removal and recovery methods of such catalysts are also introduced in detail.In addition,the preparation of novel phosphazene oxide(PZO) catalyst and the process for preparing PPG using such catalyst are also introduced.By comparing with the conventional KOH catalyst and double metal cyanide(DMC) catalyst,it is pointed out that the PZN catalyst is a novel catalyst with great development potential for preparing PPG.
The structure,preparation processes of novel phosphazenium(PZN) catalysts from Tosoh Corp and their application situation in preparation of poly ether polyol(PPG) as catalyst are introduced in detail.The removal and recovery methods of such catalysts are also introduced in detail.In addition,the preparation of novel phosphazene oxide(PZO) catalyst and the process for preparing PPG using such catalyst are also introduced.By comparing with the conventional KOH catalyst and double metal cyanide(DMC) catalyst,it is pointed out that the PZN catalyst is a novel catalyst with great development potential for preparing PPG.
引文
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[28]宰少波,金晖,张志华.聚醚多元醇的制备方法:中国,104558583A[P].2015-04-29.
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[30]宰少波,金晖,张志华,等.环状单体开环聚合制备聚合物的方法:中国,104927035A[P].2015-09-23.
[2]#12
[3]于剑昆.磷腈类催化剂及其在聚醚多元醇合成中的应用[J].聚氨酯工业,2004,19(5):10-14.
[4]于剑昆.三井化学公司新型聚醚多元醇的制备与应用[J].化学推进剂与高分子材料,2005,3(5):8-13.
[5]于剑昆,陈运铎.用磷腈类催化剂合成的新型聚醚多元醇及其在聚氨酯泡沫制备中的应用新进展[J].化学推进剂与高分子材料,2012,10(2):1-7.
[6]NOBORI T,SUZUKI T,KIYONO S,et al.Phosphazenium salt and preparation process thereof,and process for producing poly(alkylene oxide):EP,0791600A2[P].1997-08-27.
[7]HANS-PETER K,THOMAS R,MARIO G,et al.Stickstoff-haltige phosphonium salze:DE,102006010034A1[P].2007-09-06.
[8]#12
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[27]宰少波,涂建军,宋虹霞.聚醚多元醇的制备方法:中国,104448287A[P].2015-03-25.
[28]宰少波,金晖,张志华.聚醚多元醇的制备方法:中国,104558583A[P].2015-04-29.
[29]宰少波,涂建军.氧化磷腈化合物催化环氧丙烷开环聚合[J].复旦学报:自然科学版,2013,52(1):39-43.
[30]宰少波,金晖,张志华,等.环状单体开环聚合制备聚合物的方法:中国,104927035A[P].2015-09-23.