电气石可降解功能材料的研制
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摘要
电气石因其具备释放负离子辐射远红外线等保健功能受到广泛关注,可作为填料添加到聚合物复合材料中。先用改性剂山梨醇酐单硬脂酸酯(Span-60)对电气石粉进行表面有机改性,改善了电气石表面的亲油性,通过熔融共混法制备了热塑性淀粉(TPS)/聚己二酸对苯二甲酸丁二酯(PBAT)/电气石复合材料。实验结果表明,随着改性电气石含量的增加,TPS/PBAT/电气石复合材料的拉伸强度和弹性模量均先升高后降低,当电气石含量为3%的时候,电气石在基体中的分散稳定性最好,复合材料的拉伸强度和弹性模量达到最大,分别为13.22MPa和346MPa;且TPS/PBAT/电气石复合材料具有优异的负离子释放功能,较高的远红外辐射率,其远红外辐射率达到0.95以上。
引文
[1]陈旭波,胡应模,汤明茹,等.电气石粉体表面改性及其应用研究进展[J].无机盐工业,2013,45(5):5-8.
    [2]穆锐,王猛,邓爱民.电气石表面改性的研究[J].沈阳理工大学学报,2013,32(l):l-3.
    [3]Li M,Hu Y,Li Y,et al.Synthesis and Characterization of Polymerizable Tourmaline Methacrylate[J].e-Journal of Surface Science and Nanotechnology,2015,13:422-425.
    [4]Wang H,Wei D,Zheng A,et al.Soil burial biodegradation of antimicrobial biodegradable PBAT films[J].Polymer Degradation and Stability,2015,116:14-22.
    [5]Raghavan D.Characterization of Biodegradable Plastics[J].Polymer-Plastics Technology and Engineering,1995,34(l):41-63.
    [6]Witt U,Muller R J,Augusta J,et al.Synthesis,properties and biodegradability of polyesters based on l,3-propanediol[J].Macromolecular Chemistry&Physics,1994,195(2):793-802.
    [7]Wei D,Wang H,Xiao H,et al.Morphology and mechanical properties of poly(butylene adipate-co-terephthalate)/potato starch blends in the presence of synthesized reactive compatibilizer or modified poly(butylene adipate-co-terephthalate)[J].Carbohydrate polymers,2015,123:275-282.
    [8]Nabar Y,Raquez J M,Dubois P,et al.Production of starch foams by twin-screw extrusion:Effect of maleated poly(butylene adipate-co-terephthalate)as a compatibilizer[J].Biomacromolecules,2005,6(2):807-817.
    [9]Fukushima K,Rasyida A,Yang M C.Biocompatibility of organically modified nanocomposites based on PBAT[J].Journal of Polymer Research,2013,20(11):1-12.
    [10]Brandelero R P H,Grossmann M V,Yamashita F.Films of starch and poly(butylene adipate co-terephthalate)added of soybean oil(SO)and Tween 80[J].Carbohydrate polymers,2012,90(4):1452-1460.
    [11]Schwach E,Averous L.Starch-based biodegradable blends:morphology and interface properties[J].Polymer International,2004,53(12):2115-2124.
    [12]Garcia P S,Grossmann M V E,Yamashita F,et al.Citric acid as multifunctional agent in blowing films of starch/PBAT[J].QuimicaNova,2011,34(9):1507-1510.
    [13]Hu Y,Yang X.The surface organic modification of tourmaline powder by span-60 and its composite[J].Applied Surface Science,2012,258(19):7540-7545.

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