磷化工区周边砷污染特征及形态分布研究
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- 论文作者：叶芝祥 ; 杨怀金 ; 朱羽蒙
- 年：2014
- 作者机构：成都信息工程学院资源环境学院;四川省环境保护科学研究院;
- 论文关键词：总砷 ; 总无机砷 ; As(Ⅲ) ; As(Ⅴ) ; DMA ; MMA
- 会议召开时间：2014-12-13
- 会议录名称：“第四届重金属污染防治及风险评价研讨会”暨重金属污染防治专业委员会2014年学术年会论文集
- 语种：中文
- 分类号：X78
- 学会代码：HJKP
- 会议名称：“第四届重金属污染防治及风险评价研讨会”暨重金属污染防治专业委员会2014年学术年会
- 会议地点：中国江苏盐城
- 主办单位：中国环境科学学会、同济大学
- 学会名称：中国环境科学学会
- 页数：8
- 文件大小：939k
- 原文格式：D
- 会议级别：全国
摘要
在磷化工区上下风向区域内采集空气、土壤、水、食物样品,样品经过预处理,用原子荧光光谱仪测定各样品中总砷、总无机砷、As(Ⅲ)、As(Ⅴ)、DMA、MMA的含量。磷化工区下风向饮用水、灌溉水和土壤中总砷浓度分别为10.08μg/L、4.113μg/L和18.95mg/kg,磷化工区生产对下风向有一定的影响。磷化工区下风向各种食物中含砷量:大米>叶菜类蔬菜>根茎类蔬菜,大米中砷的含量为0.879mg/kg是国标准限值的5.86倍;空心菜(0.111mg/kg)和红苕叶(0.096mg/kg)分别为国标限值的2.22、1.92倍。空气中砷的存在形态主要为无机砷且As(Ⅴ)>As(Ⅲ),其中As(Ⅴ)占无机砷总量的51.8~71.6%。土壤中无机砷主要以As(Ⅴ)的形态存在,并且占总砷的79.5~95.0%,As(Ⅲ)的含量较低,在土壤中还存在一定量的有机砷。大米和红苕叶中砷的形态主要以As(Ⅲ)为主,分别占总砷含量的46.2~92.4%、54.6~74.6%。大米中砷含有一定量的As(Ⅴ)(2.8~22.5%)和DMA(6.9~22.6%),存在微量的MMA。在红苕叶中DMA的平均含量并不高,MMA则基本未检出,在红苕叶中总无机砷的含量比大米的要高,并且DMA含量比较少。可以看出无论是大米还是红苕叶中砷主要还是以无机态存在,而且基本不含有MMA。
引文
[1]Gomez-Caminero A,Howe P,Hughes M,et al.Sources and occurrence of arsenic in the environment.Arsenic and arsenic compound.Environmental health criteria 224.International programme on chemical safety.Geneva:World Health Organization.2001,p.28-33.
[2]Garelick H,Jones H,Dybowska A,Valsami-Jones E.Arsenic pollution sources[J].Reviews of environmental contamination and toxicology.2008,197:17-60.
[3]Duker AA,Carranza EJ,Hale M.Arsenic geochemistry and health[J].Environment International.2005,31(5):631-41.
[4]Bhattacharya P,Welch AH,Stollenwerk KG,et al.Arsenic in the environment:Biology and Chemistry[J].Science of the Total Environment,2007,379:109-120.
[5]崔艳丽,王三祥,王正辉,等.砷中毒地区外环境砷暴露水平的研究现状[J].国外医学医学地理分册2011,32(2):75-78.
[6]北京吉天仪器有限公司.原子荧光分析方法手册.
[7]梁淑轩,吴虹,齐学先,等.氢化物发生-原子荧光光谱法测定大气颗粒物中的砷形态[J].河北大学学报(自然科学版)2011,21(1):42-47.
[8]梁淑轩,吴虹,孙汉文.氢化物发生原子荧光结合计算法测定大气颗粒物中砷的形态[J].分析试验室2012,31(8):86-89
[9]马戈,谢文兵,刘晶,等.氢化物发生原子荧光光谱法直接测定水样中砷(Ⅲ)和砷(V)[J].光谱学与光谱分析2007,27(4):807-809.
[10]杨莉丽,李娜,张德强,等.氢化物发生-原子吸收光谱法测定中药中砷(Ⅲ)和砷(Ⅴ)[J].分析科学学报,2004,20(5):483-485.
[11]马名扬,孙翠香,张朝阳,等.土壤中无机砷测定的三种前处理方法比较[J].光谱实验室,2007,24(3):239-242.
[12]唐增煦,薛颖,张勐,等.树脂分离-氢化物发生-原子荧光光谱法测定食品中无机砷、一甲基胂和二甲基胂[J].分析试验室.2007,26(9):106-109.
[13]Yang G,Ma L,Xu D,et al.Levels and speciation of arsenic in the atmosphere in Beijing,China[J].Chemosphere.2012,87(8):845-50
[14]Lewis AS,Reid KR,Pollock MC,et al.Speciated arsenic in air:measurement methodology and risk assessment considerations[J].Journal of the Air Waste Air&Waste Management Association 1995,2012,62(1):2-17
[15]Newton K,Amarasirivardena D,Xing B.Distribution of soil arsenic species,lead and arsenic bound to humic acid molar mass fractions in a contaminated apple orchard[J].Environmental Pollution,2006,143:197-205.
[16]Balasoiu CF,Zagury GJ,Deschênes L.Partitioning and speciation of chromium,copper,and arsenic in CCA-contaminated soils:influence of soil composition[J]..The science of the total environment,2001,280:239-255.
[17]Roberts LC,Hug SJ,Voegelin A,et al.Arsenic dynamics in porewater of an intermittently irrigated paddy field in Bangladesh.[J].Environmental Science&Technology.2011,45(3):971-6.
[18](Maher W,Foster S,Krikowa F,et al.Measurement of inorganic arsenic species in rice after nitric acid extraction by HPLC-ICPMS:verification using XANES.[J].Environmental Science&Technology.2013.47(11):5821-7.6
[19]Vela NP,Heitkemper DT.Total arsenic determination and speciation in infant food products by ion chromatography-inductively coupled plasma-mass spectrometry.[J].Journal of AOAC international.2004 Jan-Feb;87(1):244-52.
[20]Moreno-Jiménez E,Esteban E,Pe?alosa JM.The fate of arsenic in soil-plant systems.[J].Reviews of environmental contamination and toxicology.2012,215:1-37.
[21]Lomax C,Liu WJ,Wu L,et al.Methylated arsenic species in plants originate from soil microorganisms[J].New Phytologist.2012,,193(3):665-72
[2]Garelick H,Jones H,Dybowska A,Valsami-Jones E.Arsenic pollution sources[J].Reviews of environmental contamination and toxicology.2008,197:17-60.
[3]Duker AA,Carranza EJ,Hale M.Arsenic geochemistry and health[J].Environment International.2005,31(5):631-41.
[4]Bhattacharya P,Welch AH,Stollenwerk KG,et al.Arsenic in the environment:Biology and Chemistry[J].Science of the Total Environment,2007,379:109-120.
[5]崔艳丽,王三祥,王正辉,等.砷中毒地区外环境砷暴露水平的研究现状[J].国外医学医学地理分册2011,32(2):75-78.
[6]北京吉天仪器有限公司.原子荧光分析方法手册.
[7]梁淑轩,吴虹,齐学先,等.氢化物发生-原子荧光光谱法测定大气颗粒物中的砷形态[J].河北大学学报(自然科学版)2011,21(1):42-47.
[8]梁淑轩,吴虹,孙汉文.氢化物发生原子荧光结合计算法测定大气颗粒物中砷的形态[J].分析试验室2012,31(8):86-89
[9]马戈,谢文兵,刘晶,等.氢化物发生原子荧光光谱法直接测定水样中砷(Ⅲ)和砷(V)[J].光谱学与光谱分析2007,27(4):807-809.
[10]杨莉丽,李娜,张德强,等.氢化物发生-原子吸收光谱法测定中药中砷(Ⅲ)和砷(Ⅴ)[J].分析科学学报,2004,20(5):483-485.
[11]马名扬,孙翠香,张朝阳,等.土壤中无机砷测定的三种前处理方法比较[J].光谱实验室,2007,24(3):239-242.
[12]唐增煦,薛颖,张勐,等.树脂分离-氢化物发生-原子荧光光谱法测定食品中无机砷、一甲基胂和二甲基胂[J].分析试验室.2007,26(9):106-109.
[13]Yang G,Ma L,Xu D,et al.Levels and speciation of arsenic in the atmosphere in Beijing,China[J].Chemosphere.2012,87(8):845-50
[14]Lewis AS,Reid KR,Pollock MC,et al.Speciated arsenic in air:measurement methodology and risk assessment considerations[J].Journal of the Air Waste Air&Waste Management Association 1995,2012,62(1):2-17
[15]Newton K,Amarasirivardena D,Xing B.Distribution of soil arsenic species,lead and arsenic bound to humic acid molar mass fractions in a contaminated apple orchard[J].Environmental Pollution,2006,143:197-205.
[16]Balasoiu CF,Zagury GJ,Deschênes L.Partitioning and speciation of chromium,copper,and arsenic in CCA-contaminated soils:influence of soil composition[J]..The science of the total environment,2001,280:239-255.
[17]Roberts LC,Hug SJ,Voegelin A,et al.Arsenic dynamics in porewater of an intermittently irrigated paddy field in Bangladesh.[J].Environmental Science&Technology.2011,45(3):971-6.
[18](Maher W,Foster S,Krikowa F,et al.Measurement of inorganic arsenic species in rice after nitric acid extraction by HPLC-ICPMS:verification using XANES.[J].Environmental Science&Technology.2013.47(11):5821-7.6
[19]Vela NP,Heitkemper DT.Total arsenic determination and speciation in infant food products by ion chromatography-inductively coupled plasma-mass spectrometry.[J].Journal of AOAC international.2004 Jan-Feb;87(1):244-52.
[20]Moreno-Jiménez E,Esteban E,Pe?alosa JM.The fate of arsenic in soil-plant systems.[J].Reviews of environmental contamination and toxicology.2012,215:1-37.
[21]Lomax C,Liu WJ,Wu L,et al.Methylated arsenic species in plants originate from soil microorganisms[J].New Phytologist.2012,,193(3):665-72