缓蚀剂研究进展简述
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- 英文论文题名：A Sketch of the Development of Corrosion Inhibitors
- 论文作者：陈振宇 ; 郭兴蓬
- 英文论文作者：CHEN Zhen-yu ; GUO Xing-peng ; School of Chemistry and Chemical Engineering ; Huazhong University of Science and Technology
- 年：2014
- 作者机构：华中科技大学化学与化工学院;
- 论文关键词：缓蚀剂 ; 研究 ; 进展 ; 发展趋势
- 英文论文关键词：corrosion inhibitors ; research ; progress ; development trend
- 会议召开时间：2014-07-28
- 会议录名称：第十八届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TG174.42
- 学会代码：ZGHA
- 会议名称：第十八届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国四川成都
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：7
- 文件大小：593k
- 原文格式：O
- 会议级别：全国
摘要
近年来,环境友好型缓蚀剂已成为缓蚀剂研究的热点之一。环境友好型缓蚀剂的开发主要通过合成有机化合物和从天然植物中提取两种方式,合成的环境友好型缓蚀剂主要有咪唑啉系列、氨基酸系列、曼尼烯碱、硫代磷酸酯类有机化合物。钢筋混凝土缓蚀剂、气相缓蚀剂、铝/镁及其合金缓蚀剂的研究都取得了一定的进展。当金属表面有腐蚀产物膜存在时,腐蚀产物膜与缓蚀剂之间的相互作用将成为影响缓蚀剂防护性能的重要因素。一方面,为了进一步探究缓蚀剂机理,需要结合新的原位分析手段,从分子尺度研究缓蚀剂的作用行为,阐明缓蚀剂的作用机制。另一方面,为了建立缓蚀剂现场应用的加注制度,需要完善缓蚀剂的快速、准确、原位评价的方法与技术。缓蚀剂的协同效应和基于量子化学的缓蚀剂的构效关系的研究也是缓蚀剂研究的前沿和热点领域。近些年,国际上缓蚀剂的研究工作主要集中在中国、印度、埃及和美国等国家,中国是在国际学术期刊上发表缓蚀剂研究论文最多的国家,约占同期世界发表的缓蚀剂研究论文的17%。本文简要回顾了近两年我国缓蚀剂研究的进展,简述了缓蚀剂研究的发展趋势。
In recent years,the study and development of environmental friendly inhibitors has become one of the hotspots in the research of corrosion inhibitors.The environmental friendly inhibitors can be developed through the synthesis of organic compounds and the extraction from natural plants.The synthesized environmental friendly inhibitors mainly include imidazoline,amino acids,Mannich alkali compounds and thiophosphate compounds.The researches on rebar inhibitors for reinforced concretes,volatile corrosion inhibitors and the inhibitors for Al,Mg and their alloys all have made some progress.In cases of the formation of a corrosion product film on the metal surface,the interaction between the corrosion product film and corrosion inhibitors will become an important factor to affect the inhibitor's performance.On one hand,new in-situ analysis tools are needed to explore the inhibitor's behavior and mechanism at molecular scale;and on the other hand,quick,accurate and in-situ methods are demanded for the field evaluation of inhibitors so as to establish practical field injection technology for inhibitors.The inhibitors7 synergistic effects and their structure-activity relationships based on quantum chemistry computation are also hot areas in the research of corrosion inhibitors.In recent years,a lot of research works about the corrosion inhibitors have been done in China,India,Egypt and United States etc,and the most of papers about corrosion inhibitors in international academic journals come from China,whose number is more than 17%of the total papers in this area published in the world.This paper reviews the progress in the research of corrosion inhibitors in recent years in China,and sketches the development trend of corrosion inhibitors.
In recent years,the study and development of environmental friendly inhibitors has become one of the hotspots in the research of corrosion inhibitors.The environmental friendly inhibitors can be developed through the synthesis of organic compounds and the extraction from natural plants.The synthesized environmental friendly inhibitors mainly include imidazoline,amino acids,Mannich alkali compounds and thiophosphate compounds.The researches on rebar inhibitors for reinforced concretes,volatile corrosion inhibitors and the inhibitors for Al,Mg and their alloys all have made some progress.In cases of the formation of a corrosion product film on the metal surface,the interaction between the corrosion product film and corrosion inhibitors will become an important factor to affect the inhibitor's performance.On one hand,new in-situ analysis tools are needed to explore the inhibitor's behavior and mechanism at molecular scale;and on the other hand,quick,accurate and in-situ methods are demanded for the field evaluation of inhibitors so as to establish practical field injection technology for inhibitors.The inhibitors7 synergistic effects and their structure-activity relationships based on quantum chemistry computation are also hot areas in the research of corrosion inhibitors.In recent years,a lot of research works about the corrosion inhibitors have been done in China,India,Egypt and United States etc,and the most of papers about corrosion inhibitors in international academic journals come from China,whose number is more than 17%of the total papers in this area published in the world.This paper reviews the progress in the research of corrosion inhibitors in recent years in China,and sketches the development trend of corrosion inhibitors.
引文
[1]胡晓静,刘振法,武秀丽,等.环境友好型缓蚀阻垢剂的研制及性能研究[J].水处理技术,2010,36(3):39-42.
[2]张大全.缓蚀技术研究进展及在能源工业中的应用[J].上海电力学院学报,2013,29(4):355-363.
[3]左书瑞,刘瑞泉.双苯并三唑Mannich碱在5%NaHCO_3溶液中对Cu的缓蚀作用[J].中国腐蚀与防护学报,2011,31(2):106-112.
[4]罗媵,马喜平,韩洁,等.新型曼尼希碱酸化缓蚀剂HBBJ-1的研制[J].应用化工,2010,39(12):1898-1901.
[5]吕珂,谢学军食用植物G提取物用作碳钢盐酸酸洗缓蚀剂的研究[J].清洗世界,2013,29(11):29-32.
[6]李向红,付惠,邓书端,等.几种植物叶提取物在HCl中对锌的缓蚀作用[J].全面腐蚀控制,2010,24(12):14-18.
[7]ZHU Y L,GUO X P,Qiu Y B.Inhibition mechanism of sodium laurate to underdeposit corrosion of carbon steels in NaCl solutions[J].Corrosion Engineering Science and Technology,2010,45(6):442-448.
[8]吕民,张大全.一种新型复合钢筋阻锈剂[J].腐蚀与防护,2010,31(9):709-711.
[9]鞠玉琳,李焰.气相缓蚀剂的研究进展[J].中国腐蚀与防护学报,2014,34(1):271-36.
[10]CHEN J,CHEN Z Y,GUO X P.2-Propynylamine as a vapor corrosion inhibitor for carbon steel under adsorbed thin electrolyte layers[J].Journal of the Electrochemical Society,2014,161(3):151-155.
[11]LIU Y,CHENG Y F.Inhibition of corrosion of 3003aluminum alloy in ethylene glycol-water solutions[J].Journal of Materials Engineering and Performance,2011,20(2):271-275.
[12]HUANG D B,HU J Y,SONG G L,etaL Inhibition effect of inorganic and organic inhibitors on the corrosion of Mg-10Gd-3Y-0.5Zr alloy in an ethylene glycol solution at ambient and elevated temperatures[J].Electrochimica Acta,2011,56(27):10166-10178.
[13]QU J E,GUO X P,ZHANG J Z.Electrochemical behavior and micro adhesive force characteristic of corrosion inhibition film[J].Acta PhysicoChimica Sinica,2008,24(8):1507-1512.
[14]AI J Z,MEIP,CHEN W,etaL Investigation on imidazoline amide adsorption and electrochemical behaviour of coupled steels[J].Surface Engineering,2007,23(1):62-67.
[15]郭兴蓬,胡骞,陈振宇.酸性油气田管道腐蚀安全智能监测系统研究[C]//福州:经济发展方式转变与自主创新——第十二届中国科学技术协会年会(第二卷),2010.
[16]周渝,杜国佳,王东海,等.一种缓蚀剂残余浓度的定量分析方法及现场应用[J].石油与天然气化工,2008,37(6):527-531.
[17]吕伟德,饶君凤,刘玉秀.离子色谱法同时测定3种有机膦酸类阻垢缓蚀剂[J].浙江大学学报,2013,40(6):671-675.
[18]RAO B V A,RAO M V,RAO S S,etaL Tungstate as a synergist to phosphonate-based formulation for corrosion control of carbon steel in nearly neutral aqueous environment[J].Journal of Chemical Sciences,2010,122(4):639-649.
[19]屈菊平.稀土盐氯化铈、硝酸镧对防锈铝合金的缓蚀作用[J].腐蚀与防护,2013,34(10):893-895.
[20]MARIA F,MARIANNE S,BRUCE H.New'green'corrosion inhibitors based on rare earth compounds[J].Australian Journal of Chemistry,2011,64(6):812-819.
[21]LI X H,DENG S D,FU H,et aL Synergistic inhibition effect of rare earth cerium(Ⅳ)ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution[J].Corrosion Science,2010,52(4):1167-117.
[22]康永.氨基酸缓蚀剂缓蚀机理分子模拟分析及发展趋势[J].乙醛醋酸化工,2014,(3):20-24.
[23]KHALED K F.Modeling corrosion inhibition of iron in acid medium by genetic function approximation method;A QSAR model[J].Corrosion Science,2011,53(11):3457-3465.
[24]ZHANG J,QIAO G M,HU S Q,et aL Theoretical evaluation of corrosion inhibition performance of imidazoline compounds with different hydrophilic groups[J].Corrosion Science,2011,53(1):147-152.
[25]BREET E,NORTJ Y,GREUNING C V.Supercritical carbon dioxide extracted oil from Jatropha curcas:Directive for the biodiesel industry[J].The Journal of Supercritical Fluids,2011,60:38-44.
[26]KTAINA V Y,VEGA A,NOLASCO S M,et al.Supercritical carbon dioxide extraction of oil from Mexican chia seed(Salvia hispanica L.):Characterization and process optimization[J].The Journal of Supercritical Fluids,2010,55:192-199.
[27]FIROUZ A Q,TORABI F.Utilization of carbon dioxide and methane in huff-and-puff injection scheme to improve heavy oil recovery[J].Fuel,2014,117:966-973.
[28]ZHANG Y,GAO K W,SCHMITT G.Inhibition of steel corrosion under aqueous supercritical CO_2 conditions[A].Houston:NACE,Paper 11379.2011.
[29]王斌,商永滨,毛泾生,等.氧气对J55油管CO_2腐蚀机理影响[J].内蒙古石油化工,2014(6):54-57.
[2]张大全.缓蚀技术研究进展及在能源工业中的应用[J].上海电力学院学报,2013,29(4):355-363.
[3]左书瑞,刘瑞泉.双苯并三唑Mannich碱在5%NaHCO_3溶液中对Cu的缓蚀作用[J].中国腐蚀与防护学报,2011,31(2):106-112.
[4]罗媵,马喜平,韩洁,等.新型曼尼希碱酸化缓蚀剂HBBJ-1的研制[J].应用化工,2010,39(12):1898-1901.
[5]吕珂,谢学军食用植物G提取物用作碳钢盐酸酸洗缓蚀剂的研究[J].清洗世界,2013,29(11):29-32.
[6]李向红,付惠,邓书端,等.几种植物叶提取物在HCl中对锌的缓蚀作用[J].全面腐蚀控制,2010,24(12):14-18.
[7]ZHU Y L,GUO X P,Qiu Y B.Inhibition mechanism of sodium laurate to underdeposit corrosion of carbon steels in NaCl solutions[J].Corrosion Engineering Science and Technology,2010,45(6):442-448.
[8]吕民,张大全.一种新型复合钢筋阻锈剂[J].腐蚀与防护,2010,31(9):709-711.
[9]鞠玉琳,李焰.气相缓蚀剂的研究进展[J].中国腐蚀与防护学报,2014,34(1):271-36.
[10]CHEN J,CHEN Z Y,GUO X P.2-Propynylamine as a vapor corrosion inhibitor for carbon steel under adsorbed thin electrolyte layers[J].Journal of the Electrochemical Society,2014,161(3):151-155.
[11]LIU Y,CHENG Y F.Inhibition of corrosion of 3003aluminum alloy in ethylene glycol-water solutions[J].Journal of Materials Engineering and Performance,2011,20(2):271-275.
[12]HUANG D B,HU J Y,SONG G L,etaL Inhibition effect of inorganic and organic inhibitors on the corrosion of Mg-10Gd-3Y-0.5Zr alloy in an ethylene glycol solution at ambient and elevated temperatures[J].Electrochimica Acta,2011,56(27):10166-10178.
[13]QU J E,GUO X P,ZHANG J Z.Electrochemical behavior and micro adhesive force characteristic of corrosion inhibition film[J].Acta PhysicoChimica Sinica,2008,24(8):1507-1512.
[14]AI J Z,MEIP,CHEN W,etaL Investigation on imidazoline amide adsorption and electrochemical behaviour of coupled steels[J].Surface Engineering,2007,23(1):62-67.
[15]郭兴蓬,胡骞,陈振宇.酸性油气田管道腐蚀安全智能监测系统研究[C]//福州:经济发展方式转变与自主创新——第十二届中国科学技术协会年会(第二卷),2010.
[16]周渝,杜国佳,王东海,等.一种缓蚀剂残余浓度的定量分析方法及现场应用[J].石油与天然气化工,2008,37(6):527-531.
[17]吕伟德,饶君凤,刘玉秀.离子色谱法同时测定3种有机膦酸类阻垢缓蚀剂[J].浙江大学学报,2013,40(6):671-675.
[18]RAO B V A,RAO M V,RAO S S,etaL Tungstate as a synergist to phosphonate-based formulation for corrosion control of carbon steel in nearly neutral aqueous environment[J].Journal of Chemical Sciences,2010,122(4):639-649.
[19]屈菊平.稀土盐氯化铈、硝酸镧对防锈铝合金的缓蚀作用[J].腐蚀与防护,2013,34(10):893-895.
[20]MARIA F,MARIANNE S,BRUCE H.New'green'corrosion inhibitors based on rare earth compounds[J].Australian Journal of Chemistry,2011,64(6):812-819.
[21]LI X H,DENG S D,FU H,et aL Synergistic inhibition effect of rare earth cerium(Ⅳ)ion and sodium oleate on the corrosion of cold rolled steel in phosphoric acid solution[J].Corrosion Science,2010,52(4):1167-117.
[22]康永.氨基酸缓蚀剂缓蚀机理分子模拟分析及发展趋势[J].乙醛醋酸化工,2014,(3):20-24.
[23]KHALED K F.Modeling corrosion inhibition of iron in acid medium by genetic function approximation method;A QSAR model[J].Corrosion Science,2011,53(11):3457-3465.
[24]ZHANG J,QIAO G M,HU S Q,et aL Theoretical evaluation of corrosion inhibition performance of imidazoline compounds with different hydrophilic groups[J].Corrosion Science,2011,53(1):147-152.
[25]BREET E,NORTJ Y,GREUNING C V.Supercritical carbon dioxide extracted oil from Jatropha curcas:Directive for the biodiesel industry[J].The Journal of Supercritical Fluids,2011,60:38-44.
[26]KTAINA V Y,VEGA A,NOLASCO S M,et al.Supercritical carbon dioxide extraction of oil from Mexican chia seed(Salvia hispanica L.):Characterization and process optimization[J].The Journal of Supercritical Fluids,2010,55:192-199.
[27]FIROUZ A Q,TORABI F.Utilization of carbon dioxide and methane in huff-and-puff injection scheme to improve heavy oil recovery[J].Fuel,2014,117:966-973.
[28]ZHANG Y,GAO K W,SCHMITT G.Inhibition of steel corrosion under aqueous supercritical CO_2 conditions[A].Houston:NACE,Paper 11379.2011.
[29]王斌,商永滨,毛泾生,等.氧气对J55油管CO_2腐蚀机理影响[J].内蒙古石油化工,2014(6):54-57.