钙钛矿太阳能电池的形貌调控与界面工程
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- 英文论文题名：Morphology Control and Interface Engineering for High Performance Perovskite Solar Cells
- 论文作者：周祎 ; 刘晓东 ; 余浩 ; 董晴晴 ; 王兆伟 ; 李永舫
- 英文论文作者：Yi Zhou ; Xiaodong Liu ; Hao Yu ; Qingqing Dong ; Zhaowei Wang ; Yongfang Li ; Laboratory of Advanced Optoelectronic Materials ; College of Chemistry ; Chemical Engineering and Materials Science ; Key laboratory of Organic Solids ; Institute of Chemistry ; Chinese Academy of Sciences
- 年：2016
- 作者机构：苏州大学材料与化学化工学部先进光电材料实验室;中国科学院化学所有机固体重点实验室;
- 论文关键词：钙钛矿太阳能电池 ; 形貌调控 ; 界面修饰层 ; 常温溶剂退火
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十二分会：有机光伏的机遇和挑战
- 语种：中文
- 分类号：TM914.4
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十二分会 ; 有机光伏的机遇和挑战
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：119k
- 原文格式：D
- 会议级别：全国
摘要
有机/无机杂化钙钛矿太阳能电池因其具有合适的带隙、高的吸收系数、优异的载流子性能、弱的激子束缚能,较长的载流子扩散长度等优点,已经成为太阳能领域的研究热点。自2009年首次报道以来,能量转化效率(PCE)从不足4%,发展至今已超过20%。为了进一步深入理解制约钙钛矿太阳能电池的效率及稳定性的多种因素,我们以一步法溶液制备的CH3NH3IxCl1-x钙钛矿为主要研究对象,从钙钛矿形貌调控以及界面修饰入手,重点介绍以下几方面工作:1)在常温下通过混合溶剂退火控制钙钛矿结晶,替代通常采用的热退火,制备得到高结晶度和高PCE的钙钛矿太阳能电池;2)通过引入聚合物添加剂,调控钙钛矿的形貌以及结晶度,进而提高其PCE;3)以醇溶性的冠醚富勒烯衍生物、羟基富勒烯衍生物为电子传输层(ETL),或者以具有高空穴迁移率的二噻吩噻咯类聚合物作为空穴传输层(HTL),提高电子或者空穴的收集效率以及钙钛矿太阳能电池的PCE;4)通过引入双层或多层ETL,相应器件的PCE以及稳定性等都有显著的提升。
Hybrid organic/inorganic perovskite solar cells(Pero-SCs) have attracted a great deal of research attention due to the remarkable features such as large absorption coefficient, small exciton binding energy, high charge mobility, long carrier diffusion length. Up-to-date, the highest reported PCE of Pero-SCs has skyrocketed from 3.8% to over 20%. In order to further understand the inside mechanisms that influence the performance and stability of Pero-SCs, we focus on the morphology control and interfacial engineering two aspects to improve the device performance and stability of Pero-SCs.
Hybrid organic/inorganic perovskite solar cells(Pero-SCs) have attracted a great deal of research attention due to the remarkable features such as large absorption coefficient, small exciton binding energy, high charge mobility, long carrier diffusion length. Up-to-date, the highest reported PCE of Pero-SCs has skyrocketed from 3.8% to over 20%. In order to further understand the inside mechanisms that influence the performance and stability of Pero-SCs, we focus on the morphology control and interfacial engineering two aspects to improve the device performance and stability of Pero-SCs.
引文
[1]Yu,H.;Liu,X.D.;Xia,Y.J.;Dong,Q.Q.;Zhou,Y.;Song,B.;Li,Y.F.,J Mater Chem A 2016,4:321.
[2]Wang,Z.;Dong,Q.;Xia,Y.;Yu,H.;Guo,X.;Zhou,Y.;Zhang,M.;Song,B.,Org.Electron.2016,33:142.
[3]Dong,Q.;Wang,Z.;Zhang,K.;Yu,H.;Huang,P.;Liu,X.;Zhou,Y.;Chen,N.;Song,B.,Nanoscale 2016,8:5552.
[4]Liu,X.D.;Jiao,W.X.;Lei,M.;Zhou,Y.;Song,B.;Li,Y.F.,J Mater Chem A 2015,3:9278.
[5]Liu,X.;Yu,H.;Yan,L.;Dong,Q.;Zhou,Y.;Song,B.;Li,Y.,ACS applied materials&interfaces 2015,7:6230.
[2]Wang,Z.;Dong,Q.;Xia,Y.;Yu,H.;Guo,X.;Zhou,Y.;Zhang,M.;Song,B.,Org.Electron.2016,33:142.
[3]Dong,Q.;Wang,Z.;Zhang,K.;Yu,H.;Huang,P.;Liu,X.;Zhou,Y.;Chen,N.;Song,B.,Nanoscale 2016,8:5552.
[4]Liu,X.D.;Jiao,W.X.;Lei,M.;Zhou,Y.;Song,B.;Li,Y.F.,J Mater Chem A 2015,3:9278.
[5]Liu,X.;Yu,H.;Yan,L.;Dong,Q.;Zhou,Y.;Song,B.;Li,Y.,ACS applied materials&interfaces 2015,7:6230.