含铁多级孔ZSM-5沸石分子筛的合成与催化性能
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- 英文论文题名：Synthesis and catalytic performance of iron-containing hierarchical ZSM-5
- 论文作者：徐娓 ; 杜佳
- 英文论文作者：Xu Wei ; Du Jia ; State Key Laboratory of Inorganic Synthesis and Preparative Chemistry ; College of Chemistry ; Jilin University ; Control Laboratory of Changchun Water Affairs Group Center
- 年：2016
- 作者机构：吉林大学化学学院无机合成与制备化学国家重点实验室;长春水务集团中心化验室;
- 论文关键词：多级孔 ; 沸石分子筛 ; 铁 ; 烷基化 ; 多相催化
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十二分会： 多孔功能材料
- 语种：中文
- 分类号：TQ426
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十二分会 ; 多孔功能材料
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：141k
- 原文格式：D
- 会议级别：全国
摘要
最近,多级孔沸石分子筛的合成受到了研究者的广泛关注~[1]。在这项工作中,我们报道通过离子交换的方法合成了含铁的多级孔ZSM-5沸石分子筛,获得的样品通过芳香化合物与卞基氯的烷基化反应评价了其催化性能,结果表明含铁的多级孔ZSM-5沸石分子筛在这些反应中展现了较优异的催化性能,暗示了这类催化剂在傅克烷基化反应中有着潜在的应用,尤其朝向大分子的催化反应。
Recently,the synthesis of hierarchical zeolites has recieved much attention.In this work,we report that iron-containing hierarchical ZSM-5 was prepared by ion-exchange method and its catalytic performance was evaluated by the benzylation of aromatics by benzyl chloride.This result indicated that iron-containing hierarchical ZSM-5 exhibited superior catalytic performance in these reactions,suggesting that such catalyst has potential applications in Friedel-Crafts alkylations,especially of large molecules.
Recently,the synthesis of hierarchical zeolites has recieved much attention.In this work,we report that iron-containing hierarchical ZSM-5 was prepared by ion-exchange method and its catalytic performance was evaluated by the benzylation of aromatics by benzyl chloride.This result indicated that iron-containing hierarchical ZSM-5 exhibited superior catalytic performance in these reactions,suggesting that such catalyst has potential applications in Friedel-Crafts alkylations,especially of large molecules.
引文
[1]Na,K.;Jo,C.;Kim,J.;Cho,K.;Jung,J.;Seo,Y.;Messinger,R.J.;Chmelka,B.F.;Ryoo,R.Science,2011,333:328.