具有高催化活性的CoNiP纳米材料用于电解水析氧
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- 英文论文题名：Efficient Water Oxidation Using CoNiP Nanoparticles
- 论文作者：李钰皓 ; 田彦平 ; 晏玉华 ; 缪煜清
- 英文论文作者：Yuhao Li ; Yanping Tian ; Yuhua Yan ; Yuqing Miao ; Collage of Science ; USST
- 年：2016
- 作者机构：上海理工大学理学院;
- 论文关键词：磷化钴镍 ; 电催化 ; 析氧
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十九分会：电化学材料
- 语种：中文
- 分类号：TB383.1;TQ116.2
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十九分会 ; 电化学材料
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：186k
- 原文格式：D
- 会议级别：全国
摘要
报道了一种具有纳米尺寸的磷化钴镍(Co NiP)纳米材料,在碱性溶液电解水过程中显示出高催化析氧活性。实验结果表明,热分解法合成的CoNiP纳米材料的尺寸大约在20-25 nm(Fig.1a),高度分散且粒径均一。将该纳米材料与亲水多壁碳纳米管混合后,负载于玻碳电极上进行析氧催化活性评价。其电化学线性伏安结扫描果表明,当电流密度达到10 mA/cm~2时,其电位为1.69 V,塔菲斜率为75 mV/dec。稳定性研究表明,循环伏安扫描500圈后,该纳米材料表现出了极高的电化学稳定性。
We reported a CoN iP nanomaterials which shown very efficient water oxidation ability in alkaline solution. The experimental results shown that the thermal decomposition method synthesized Co NiP nanoparticle size between 20 and 25 nm with high dispersion ability. After mixing CoN iP with carbon nanotubes and modified them on the GCE, the catalytic ability can be evaluated. The LSV curves shown that the potential was 1.69 V at a current density of 10 mA /cm~2, and the Tafel slope of 75 mV /dec. After 500 cycle CV scan, CoN iP materials still shown very high stability.
We reported a CoN iP nanomaterials which shown very efficient water oxidation ability in alkaline solution. The experimental results shown that the thermal decomposition method synthesized Co NiP nanoparticle size between 20 and 25 nm with high dispersion ability. After mixing CoN iP with carbon nanotubes and modified them on the GCE, the catalytic ability can be evaluated. The LSV curves shown that the potential was 1.69 V at a current density of 10 mA /cm~2, and the Tafel slope of 75 mV /dec. After 500 cycle CV scan, CoN iP materials still shown very high stability.
引文
[1]Li,D;Baydoun,H;Verani,C;Brock,S.J.Am.Chem.Soc.2016,138:4006.
[2]Han,A;Chen,H;Sun,Z;Xu J;Du,P.Chem.Commun.2015,51:11626.
[2]Han,A;Chen,H;Sun,Z;Xu J;Du,P.Chem.Commun.2015,51:11626.