盐酸溶液中蛋氨酸对铜的缓蚀协同作用
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- 英文论文题名：Corrosion Inhibition of Methionine on Copper in HCl Solution and Synergistic Effect of Zinc Ion
- 论文作者：蔡奇睿 ; 高立新 ; 何先明 ; 张大全
- 英文论文作者：CAI Qi-rui ; GAO Li-xin ; HE Xian-ming ; ZHANG Da-quan ; Department of Environment Engineering ; Shanghai University of Electric Power ; College of Environmental and Chemical Engineering ; Shanghai University
- 年：2008
- 作者机构：上海电力学院国家电力公司热力设备腐蚀与防护重点实验室;上海大学环境与化工学院;
- 论文关键词：铜 ; 蛋氨酸 ; 缓蚀 ; 锌离子 ; 协同作用
- 英文论文关键词：copper ; methionine ; corrosion inhibition ; zinc ion ; synergistic effect
- 会议召开时间：2008-07-01
- 会议录名称：第十五届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TG174.42
- 学会代码：ZGHA
- 会议名称：第十五届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国辽宁沈阳
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：3
- 文件大小：191k
- 原文格式：O
- 会议级别：全国
摘要
通过采用循环伏安法、电化学极化曲线和电化学阻抗谱研究了0.5MHCl溶液中蛋氨酸单一组分及其与锌离子复配对铜的缓蚀作用。研究表明,单一蛋氨酸以12mmoL/L的浓度对铜缓蚀效果最佳。蛋氨酸和锌离子复配显示协同效应,提高了电极的膜电阻,降低了电极的膜电容。
Corrosion inhibition of methionine(Met) and the synergistic effects with zinc ion for copper were investigated in 0.5M HCl solution by cychc voltammetry(CV) 、potentiodynamic polarization and impedance spectroscope measurement.The results indicate that the most effective concentration of Met for copper is 12 mmol/L.Combined action of Met and zinc ion shows a significant synergetic inhibition effect on corrosion of copper.Increase of film resistance and decrease of film capacitance make better protection for copper.
Corrosion inhibition of methionine(Met) and the synergistic effects with zinc ion for copper were investigated in 0.5M HCl solution by cychc voltammetry(CV) 、potentiodynamic polarization and impedance spectroscope measurement.The results indicate that the most effective concentration of Met for copper is 12 mmol/L.Combined action of Met and zinc ion shows a significant synergetic inhibition effect on corrosion of copper.Increase of film resistance and decrease of film capacitance make better protection for copper.
引文
[1]Zhang D Q,Gao L X,Zhou G D et al.Lee.Undecyl substitution in imidazole and its action on corrosion inhibition of copper in aerated acidic chloride media[J].J Appl Electrochem,2008,38:71~76.
[2]Zhang D Q,Gao L X,Zhou G D.Inhibition of copper corrosion in aerated hydrochloric acid solution by amino-acid compounds[J].J.Appl.Electrochem,2005,35;1 081-1 085.
[3]张大全,朱瑞佳,高立新.氨基酸类缓蚀剂的研究开发进展[J].上海电力学院学报[J].2007,23(3):240~243.
[4]徐群杰,金雯静,周国定.复配聚天冬氨酸对不同条件模拟水中铜的缓蚀作用[J].精细化工,2007,24(5):504~507.
[5]Ismail K M.Evaluation of cysteine as environ-mentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions[J].Electrochim.Acta,2007,52:7 811~7 819.
[6]赵岩,林昌健,李彦,等.覆铜板在NaCI溶液中的腐蚀电化学行为[J].物理化学学,2007,3(9):1 342~1 346.
[7]李辉,张冰如,李风亭.绿色水处理剂聚天冬氨酸缓蚀协同效应的研究[J].净水技术,2006,25:7~9.
[8]张大全,高立新.苯并三氮唑和8~羟基喹啉对铜缓蚀作用的研究[J].物理化学学报,2002,35(4):10~11.
[2]Zhang D Q,Gao L X,Zhou G D.Inhibition of copper corrosion in aerated hydrochloric acid solution by amino-acid compounds[J].J.Appl.Electrochem,2005,35;1 081-1 085.
[3]张大全,朱瑞佳,高立新.氨基酸类缓蚀剂的研究开发进展[J].上海电力学院学报[J].2007,23(3):240~243.
[4]徐群杰,金雯静,周国定.复配聚天冬氨酸对不同条件模拟水中铜的缓蚀作用[J].精细化工,2007,24(5):504~507.
[5]Ismail K M.Evaluation of cysteine as environ-mentally friendly corrosion inhibitor for copper in neutral and acidic chloride solutions[J].Electrochim.Acta,2007,52:7 811~7 819.
[6]赵岩,林昌健,李彦,等.覆铜板在NaCI溶液中的腐蚀电化学行为[J].物理化学学,2007,3(9):1 342~1 346.
[7]李辉,张冰如,李风亭.绿色水处理剂聚天冬氨酸缓蚀协同效应的研究[J].净水技术,2006,25:7~9.
[8]张大全,高立新.苯并三氮唑和8~羟基喹啉对铜缓蚀作用的研究[J].物理化学学报,2002,35(4):10~11.