新型光功能离子凝胶材料的制备和功能研究
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- 英文论文题名：The preparation of new optical functional ionogel materials and functional studies
- 论文作者：杨芳芳 ; 罗智勇 ; 林晓晓 ; 彭露 ; 谢在来
- 英文论文作者：Fang-Fang Yang ; Zhi-Yong Luo ; Xiao-Xiao Lin ; Lu Peng ; Zai-Lai Xie ; College of Chemistry ; Fuzhou University
- 年：2016
- 作者机构：福州大学化学学院;
- 论文关键词：PMMA-SiO2 ; 离子液体 ; 发光离子凝胶
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十七分会：光化学
- 语种：中文
- 分类号：TQ427.26
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十七分会 ; 光化学
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：276k
- 原文格式：D
- 会议级别：全国
摘要
离子凝胶材料集合了离子液体自身的化学、热稳定性和优良导电性以及固体材料的机械稳定性,是一类新型功能杂化材料。功能离子凝胶的开发已经成为该领域研究的热点[1]。已有研究表明离子液凝胶不但可用于电化学装置,还可作为功能膜材料用于催化反应、环境响应和药物分析及生物传感器等领域[2]。本课题组设计与合成了一系列基于PMMA-SiO_2有机-无机杂化材料,并用于固定含染料离子液体,构筑pH响应离子凝胶薄膜材料。
Ionogels are a class of functional hybrid materials, which enable the development of solid devices combining the properties of the IL(e.g. ionic conductivity or thermal stability) and those of a host(e.g. transparency or mechanical stability). The exploration of new functional ionogels has been one of the major driving forces of its research[1]. In preliminary research, inoic-gel can be applied in electriochemical device, but also in catalysis, gas separation, pharmaceutical analysis and biosensor as funtional menbrane materials[2]. In present work, we have designed and synthesized a series of organic-inorganic hybrid matrials based on PMMA-SiO2 as a solid matrix. Such solid material was used to immobilize a dye-functional ionic lquids to fabricate pH responsive ionogel film materials.
Ionogels are a class of functional hybrid materials, which enable the development of solid devices combining the properties of the IL(e.g. ionic conductivity or thermal stability) and those of a host(e.g. transparency or mechanical stability). The exploration of new functional ionogels has been one of the major driving forces of its research[1]. In preliminary research, inoic-gel can be applied in electriochemical device, but also in catalysis, gas separation, pharmaceutical analysis and biosensor as funtional menbrane materials[2]. In present work, we have designed and synthesized a series of organic-inorganic hybrid matrials based on PMMA-SiO2 as a solid matrix. Such solid material was used to immobilize a dye-functional ionic lquids to fabricate pH responsive ionogel film materials.
引文
[1]A.Vioux,L.Viau,S.Volland,J.Le Bideau,Use of ionic liquids in sol-gel;ionogels and applications.C.R.Chim.2010,13,242-255.
[2]J.Lee,M.J.Panzer,Y.Y.He,T.P.Lodge,C.D.Frisbie,Ion gel gated polymer thin-film transistors.J.Am.Chem.Soc.2007,129,4532-4533.
[2]J.Lee,M.J.Panzer,Y.Y.He,T.P.Lodge,C.D.Frisbie,Ion gel gated polymer thin-film transistors.J.Am.Chem.Soc.2007,129,4532-4533.