自组装策略构筑多核金属簇合物和配位聚合物
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摘要
<正>自组装是超分子化学研究的核心内容,化学家基于各种类型的非共价键作用建立自组装策略成功的实现了从小分子到复杂分子集合体的高效和定向的合成1。在可用于构筑超分子体系的众多非共价键相互作用中,金属配位具有键合能力强、方向性可控和配位模式多变等优点,引入的金属离子还赋予化合物丰富的氧化还原、发光、导电和磁等物理性质,有机配体单元
引文
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