熔体电纺(PP+PEG)/PP核壳相变纤维及性能分析
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- 英文论文题名：The Preparation and Characterization of(PP+PEG) /PP Core-Shell Phase Change Fibers by Melt Electrospinning
- 论文作者：何万林 ; 丁玉梅 ; 马小路 ; 秦永新 ; 杨卫民 ; 谭晶 ; 李好义
- 英文论文作者：He Wanlin ; Ding Yumei ; Ma Xiaolu ; Qin Yongxin ; Yang Weimin ; Tan Jing ; Li Haoyi ; College of Mechanical and Electrical Engineering ; Beijing University of Chemical Technology
- 年：2016
- 作者机构：北京化工大学机电工程学院;
- 论文关键词：同轴电纺 ; 核壳机构 ; 相变纤维 ; PEG ; 相变 ; 热焓
- 英文论文关键词：coaxial electrospinning ; core-shell structure ; phase change fibers ; PEG ; phase change ; enthalpy
- 会议召开时间：2016-11-18
- 会议录名称：中国第四届静电纺丝大会（CICE 2016）摘要集
- 语种：中文
- 分类号：TQ340.64
- 学会代码：ZGNM
- 会议名称：中国第四届静电纺丝大会(CICE 2016)
- 会议地点：中国北京
- 主办单位：中国复合材料学会超细纤维材料分会（筹）
- 学会名称：中关村科创纳米技术创新研究会
- 页数：1
- 文件大小：1144k
- 原文格式：D
- 会议级别：全国
摘要
采用自制的熔体同轴电纺装置,通过改变熔体流量、核层PEG比例制备出结构均匀的PP+PEG/PP核壳结构纤维。研究表明:熔体流量增大,纤维直径增大;核层PEG共混比例增大,纤维直径增大。得到的核壳相变纤维相变焓热随着核层PEG的比例增大而提高,PEG比例为50%时,相变焓热为41.49J/g:不同比例的PEG不会影响核壳纤维的相变区间,也不会影响纤维的耐热性。
Based on self-made coaxial melt electrospinning device,PP+PEG/PP core-shell fiber was prepared under different melt flow rates and PEG ratios of the core layer.The results showed that the diameter of the fibers increased with the increasement of melt flow rate or PEG ratio.When the PEG ratio increased,the enthalpy of core-shell fibers increased,and when PEG ratio was 50%,the enthalpy was 41.49J/g.PEG ratio had no effect on the phase transition of core-shell fibers and the heat resistance of fibers.
Based on self-made coaxial melt electrospinning device,PP+PEG/PP core-shell fiber was prepared under different melt flow rates and PEG ratios of the core layer.The results showed that the diameter of the fibers increased with the increasement of melt flow rate or PEG ratio.When the PEG ratio increased,the enthalpy of core-shell fibers increased,and when PEG ratio was 50%,the enthalpy was 41.49J/g.PEG ratio had no effect on the phase transition of core-shell fibers and the heat resistance of fibers.
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