钙钛矿类碳烟氧化催化剂研究
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- 英文论文题名：Study on the Catalytic Performance of Perovskite Catalysts for Diesel Soot Combustion
- 论文作者：张苡铭 ; 王丹 ; 赵中令 ; 于力娜 ; 张斌 ; 韩建
- 英文论文作者：Zhang Yiming ; Wang Dan ; Zhao Zhongling ; Yu Lina ; Zhang Bin ; Han Jian ; R&D Center of FAW Group Corporation
- 年：2016
- 作者机构：中国第一汽车股份有限公司技术中心;
- 论文关键词：后处理 ; 炭烟燃烧 ; 柴油车尾气 ; 钙钛矿
- 英文论文关键词：after treatment ; carbon soot combustion ; diesel emission ; perovskite
- 会议召开时间：2016-10-26
- 会议录名称：2016中国汽车工程学会年会论文集
- 英文会议录名称：Proceedings of 2016 SAE-China Congress
- 语种：中文
- 分类号：U464.172
- 学会代码：QCGC
- 会议名称：2016中国汽车工程学会年会暨展览会
- 会议地点：中国上海
- 主办单位：中国汽车工程学会
- 学会名称：中国汽车工程学会
- 页数：4
- 文件大小：896k
- 原文格式：O
- 会议级别：全国
摘要
本文采用溶胶凝胶法制备了多种钙钛矿类复合金属氧化物,并采用XRD、SEM、EDX以及TG对其结构、形貌、组成以及催化性能进行了表征。XRD和EDX测试结果表明,合成的物质以类钙钛矿型金属氧化物结构存在;SEM表明,合成的材料微观尺寸在纳米级;TG实验表明,La_(0.8)Sr_(0.2)Cu_(0.16)Fe_(0.84)O_3复合氧化物对模拟炭烟燃烧具有最大催化活性,甚至高于贵金属Rh掺杂的La_(0.7)Sr_(0.3)Fe_(0.7)Co_(0.24)Rh_(0.06)O_3型复合氧化物,降低燃烧温度幅度达到45℃,具有进一步研究与应用的价值。
Citric method was used to prepare several diesel soot combustion catalysts,La_(0.7) Sr_(0.3) Fe_(0.7) Co_(0.3) O_3,La_(0.8) Sr_(0.2) Cu_(0.16)Fe_(0.84)O_3 and La_(0.7) Sr_(0.3) Fe_(0.7) Co_(0.24) Rh_(0.06)O_3,and XRD,SEM,EDX,and TG were adopted to characterize the morphology,structure,components,and catalytic activity.Results show that nano scale catalyst with perovskite structure is obtained.The catalyst,La_(0.8)Sr_(0.2)Cu_(0.16)Fe_(0.84)O_3 has the lowest combustion temperature,45 ℃ lower than the noble metal,Rh composited catalyst,La_(0.7)Sr_(0.3)Fe_(0.7)Co_(0.24)Rh_(0.06)O_3.
Citric method was used to prepare several diesel soot combustion catalysts,La_(0.7) Sr_(0.3) Fe_(0.7) Co_(0.3) O_3,La_(0.8) Sr_(0.2) Cu_(0.16)Fe_(0.84)O_3 and La_(0.7) Sr_(0.3) Fe_(0.7) Co_(0.24) Rh_(0.06)O_3,and XRD,SEM,EDX,and TG were adopted to characterize the morphology,structure,components,and catalytic activity.Results show that nano scale catalyst with perovskite structure is obtained.The catalyst,La_(0.8)Sr_(0.2)Cu_(0.16)Fe_(0.84)O_3 has the lowest combustion temperature,45 ℃ lower than the noble metal,Rh composited catalyst,La_(0.7)Sr_(0.3)Fe_(0.7)Co_(0.24)Rh_(0.06)O_3.
引文
[1]Yi Ming Zhang,Zhongling Zhao,Dan Wang,etc.Study of A-and B-Substituted Perovskite CDPF Catalyst and Its'Catalytic Activity[C].Proceeding of SAE-China Congress2015;Selected Papers,101-108.
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[3]B.R.Stanmore,J.F.Brilhac,P.GiloL The oxidation of soot:a review of experiments,mechanisms and models[J].Carbon,2001,39,2247-2268.
[4]Yuxin Wen,Changbin Zhang,Hong He,etc.Catalytic oxidation of nitrogen monoxide over La_(1-x)Ce_xCoO_3 perovskites[J].Catalysis Today,2007,126,400-405.
[5]吴迪,柴油车尾气碳烟颗粒的催化燃烧[D].南京:南京理工大学,2012.
[6]周见红,王金兴,王丹,等.La_(0.7)Sr_(0.3)Co_(0.3)Fe_(0.7)O_3纳米纤维的合成及其NO气敏特性研究[J].汽车工程,2011,33,10,907-910
[2]Lu Gang,B.G.Anderson,J.van Grondelle,R.A.van Santen,et al.Allunina-Supported Cu-Ag Catalysts for Ammonia Oxidation to Nitrogen at Low Temprature[J].J.Catal.,2002,206,60-70.
[3]B.R.Stanmore,J.F.Brilhac,P.GiloL The oxidation of soot:a review of experiments,mechanisms and models[J].Carbon,2001,39,2247-2268.
[4]Yuxin Wen,Changbin Zhang,Hong He,etc.Catalytic oxidation of nitrogen monoxide over La_(1-x)Ce_xCoO_3 perovskites[J].Catalysis Today,2007,126,400-405.
[5]吴迪,柴油车尾气碳烟颗粒的催化燃烧[D].南京:南京理工大学,2012.
[6]周见红,王金兴,王丹,等.La_(0.7)Sr_(0.3)Co_(0.3)Fe_(0.7)O_3纳米纤维的合成及其NO气敏特性研究[J].汽车工程,2011,33,10,907-910