“生菜”形貌硫化铜微米结构的合成及在异质纳米通道中的应用
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- 英文论文题名：Colloidal Synthesis of Lettuce-Like Copper Sulphide for Light-gating Heterogeneous Nanochannels
- 论文作者：王欢 ; 谢苏菲 ; 张力仁 ; 李文华 ; 薄志山
- 英文论文作者：Huan Wang ; Sufei Xie ; Liren Zhang ; Wenhua Li ; Zhishan Bo ; College of Chemistry ; Beijing Normal University
- 年：2016
- 作者机构：北京师范大学化学学院;
- 论文关键词：硫化铜 ; 异质纳米通道
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第四十一分会：纳米材料与器件
- 语种：中文
- 分类号：TB383.1;O614.121
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第四十一分会 ; 纳米材料与器件
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：285k
- 原文格式：D
- 会议级别：全国
摘要
通过胶体热注射法成功合成了具有"生菜"形貌的硫化铜微米结构。这些"生菜"形貌的硫化铜微米结构由硫化铜纳米片通过自组装形成,而这些纳米片实际上又是由硫化铜纳米球组成。该形貌硫化铜结构的形成与反应物用量以及反应温度有关,同时我们还进一步探究了其形成过程及机理。该硫化铜微米结构具有大的比表面积,同时具有油溶性的特点。基于粒子的这两种特性,其可以很好地吸附具有光响应性的有机分子:螺吡喃分子。将吸附了螺吡喃分子的硫化铜溶液旋涂在商业化的阳极氧化铝表面,成功构筑了阳极氧化铝-硫化铜/螺吡喃异质纳米通道。该异质纳米通道在紫外可见光的相互转换下,具有很好的开关性质且具有可循环性以及稳定性。
Lettuce-like Cu_xS micron particles were successfully prepared by a colloidal hot-injection method. A probably underlying mechanism behind the formation of lettuce architecture was tentatively proposed via monitoring the evolution process. These particles were formed via the self-assembly of the nanosheets as the basic building blocks. These lettuce-like Cu_xS particles are hydrophobic and simultaneously possess a high surface area which can readily absorb the light-responsive 1,3,3-trimethylindolino-6'-nitrobenzopyrylospiran(Spiro) molecules. Finally, the AAO-Cu_xS/Spiro heterogeneous nanochannels are constructed by spin-coating the pre-prepared Cu_xS particles loaded with Spiro onto the commercially available anodic alumina(AAO) substrate. The nanochannel exhibits regulated ionic transport property with good responsive switchability and stability.
Lettuce-like Cu_xS micron particles were successfully prepared by a colloidal hot-injection method. A probably underlying mechanism behind the formation of lettuce architecture was tentatively proposed via monitoring the evolution process. These particles were formed via the self-assembly of the nanosheets as the basic building blocks. These lettuce-like Cu_xS particles are hydrophobic and simultaneously possess a high surface area which can readily absorb the light-responsive 1,3,3-trimethylindolino-6'-nitrobenzopyrylospiran(Spiro) molecules. Finally, the AAO-Cu_xS/Spiro heterogeneous nanochannels are constructed by spin-coating the pre-prepared Cu_xS particles loaded with Spiro onto the commercially available anodic alumina(AAO) substrate. The nanochannel exhibits regulated ionic transport property with good responsive switchability and stability.
引文
[1]Li,W.;Shavel,A.;Guzman,R.;Rubio-Garcia,J.;Flox,C.;Fan,J.;Cadavid,D.;Ibanez,M.;Arbiol,J.;Morante,J.R.;Cabot,A.Chem.Comm.2011,47:10332.