气相缓蚀剂的制备及其抗CO_2腐蚀性能评价
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- 英文论文题名：Preparation and Evaluation of Resistance to CO_2 Corrosion of Vapor Phase Corrosion Inhibitor
- 论文作者：徐任春 ; 陆原 ; 周琼 ; 赵璐 ; 芦义鹏 ; 陈清禹
- 英文论文作者：XU Ren-chun ; LU Yuan ; ZHOU Qiong ; ZHAO Lu ; LU Yi-peng ; CHEN Qing-yu ; China University of Petroleum(Beijing) ; CNOOC Energy Development Limited by Share Ltd. ; Engineering Branch
- 年：2014
- 作者机构：中国石油大学(北京);中海油能源发展股份有限公司工程技术分公司;
- 论文关键词：气相缓蚀剂 ; 吗啉衍生物 ; 量子化学 ; 腐蚀挂片 ; 电化学
- 英文论文关键词：vapor phase inhibitor ; morpholine derivative ; quantum chemistry ; corrosion coupon ; electrochemical
- 会议召开时间：2014-07-28
- 会议录名称：第十八届全国缓蚀剂学术讨论会论文集
- 语种：中文
- 分类号：TG174.42
- 学会代码：ZGHA
- 会议名称：第十八届全国缓蚀剂学术讨论及应用技术经验交流会
- 会议地点：中国四川成都
- 主办单位：中国腐蚀与防护学会缓蚀剂专业委员会
- 学会名称：中国腐蚀与防护学会缓蚀剂专业委员会
- 页数：3
- 文件大小：1624k
- 原文格式：O
- 会议级别：全国
摘要
采用气质联用研究了吗啉、二乙胺和甲醛反应产物的组成,确定了产物中双吗啉基甲烷、四乙基甲二胺和N,N-二乙基胺甲基吗啉的相对含量,并对比了这三种化合物抗CO_2气相腐蚀的性能。从分子能级结构推断双吗啉基甲烷和N,N-二乙基胺甲基吗啉同钢铁的结合较为紧密,挥发减量实验证明四乙基甲二胺具有较好的挥发性,腐蚀挂片和电化学研究表明N,N-二乙基胺甲基吗啉具有较高的缓蚀效率。结果表明,吗啉、二乙胺和甲醛三种主要反应产物之间有一定的相互弥补与增效作用。
GC-MS was used to study the reaction composition of morpholine、diethylamine and formaldehyde and confirm the relative content of three main compound containing bi-morpholine-methyl-alkyl,Methanediamine and N,N-diethyl-aminomethyl-morpholine.The resistance to CO_2 vapor phase corrosion properties of these three kinds compound was compared.The combination of bi-morpholine-methyl-alkyl and steel was most closely inferred from the molecular level structure.Methanediamine and N,N-diethyl-aminomethyl-morpholine had better volatile that was proved by volatile loss experiment.N,N-diethyl-aminomethyl- morpholine had better vapor phase corrosion rate which was showed by corrosion coupon and electrochemical experiment Therefore these three main product of morpholine、diethylamine and formaldehyde had a certain role in mutually complementary and synergistic.
GC-MS was used to study the reaction composition of morpholine、diethylamine and formaldehyde and confirm the relative content of three main compound containing bi-morpholine-methyl-alkyl,Methanediamine and N,N-diethyl-aminomethyl-morpholine.The resistance to CO_2 vapor phase corrosion properties of these three kinds compound was compared.The combination of bi-morpholine-methyl-alkyl and steel was most closely inferred from the molecular level structure.Methanediamine and N,N-diethyl-aminomethyl-morpholine had better volatile that was proved by volatile loss experiment.N,N-diethyl-aminomethyl- morpholine had better vapor phase corrosion rate which was showed by corrosion coupon and electrochemical experiment Therefore these three main product of morpholine、diethylamine and formaldehyde had a certain role in mutually complementary and synergistic.
引文
[1]张大全,俞路,陆柱.4-(N,N-二正丁基)-胺甲基吗啉的合成及其气相缓蚀性能[J].华东理工大学学报.1998,24(5):569-573.
[2]张大全,高立新,周国定.吗啉衍生物气相缓蚀剂的分子设计和缓蚀协同作用研究[J].中国腐蚀与防护学报.2006,26(2):120-123.
[3]颜红侠,张秋禹.吗啉衍生物抑制CO_2腐蚀性能的研究[J].应用化工.2003,32(2):35-37.
[4]罗一鸣,蒋江平,张复兴,等.三(邻溴苄基)锡3-吲哚丙烯酸酷的合成、结构和量子化学研究[J].化学试剂,2006,28(10):583-586.
[2]张大全,高立新,周国定.吗啉衍生物气相缓蚀剂的分子设计和缓蚀协同作用研究[J].中国腐蚀与防护学报.2006,26(2):120-123.
[3]颜红侠,张秋禹.吗啉衍生物抑制CO_2腐蚀性能的研究[J].应用化工.2003,32(2):35-37.
[4]罗一鸣,蒋江平,张复兴,等.三(邻溴苄基)锡3-吲哚丙烯酸酷的合成、结构和量子化学研究[J].化学试剂,2006,28(10):583-586.