废水中放射性核素锶的吸附材料研究进展
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摘要
核能利用过程及核事故突发所产生的放射性核素锶将无可避免的被释放到环境中,通过各种途径直接或间接的对人体造成极大的危害,因此对放射性废水中锶的处理具有十分重要的意义。吸附法因其简单、高效、成本低而被广泛应用。本文对目前研究的典型吸附材料应用进行了综述,并针对热门的新型吸附材料例如金属有机骨架(MOFs)、石墨烯(GO)、SBA-15的开发进行了展望。本综述将为我国放射性废水的修复治理提供一些参考。
引文
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[3]林武辉等.Et本福岛核事故后的海洋放射性监测进展[J].中国环境科学,2015,35(1):269-276
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[5]侯若梦.放射性废水处理技术研究进展[J].环境工程,2014,32.
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[7]张思纬.放射性核素吸附行为的研究综述[J].铀矿冶,2011,30(4).
[8]Ma H,Wei X,Xiong X,et.al.Research progress of application of ion exchange technology on the removal of trace radionuclides from liquid radioactive waste innuclear power plant[J].Technology of Water Treatment,2016,01.
[9]Michal S,Tamara Z.Atmospheric deposition and riverine load of Sr and Cs to the Gulf of Gdansk(Southern Baltic Sea)in the period 2005-2011[J].Journal of Environmental Radioactivity,2016,151:1-11.
[10]Zhang A Y,Xiao C L,Kuraoka E,et al.Molecular modification of a novel macroporous silica-based impregnated polymeric composite by trin-butyl phosphate and its application in the adsorption for some metals contained in a typical simulated HLLW[J].Journal of Hazardous Materials.2007,147(1-2):601-609.
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[13]Volkovich V A,Grifiths T R,Thied R C.Treatment of molten salt wastes by phosphate precipitation:removal of fission product elements after pyro-chemical reprocessing of spent nuclear fuels in chloride melts[J].Journal of Nuclear Materials,2003,323(1):49-56.
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[16]Wang Z,Liu XT.Study on adsorption performance of zeolite from different mining area for strontium[J].Guangzhou Chemical Industry,2015,15.
[17]M.W.Munthali et al.Cs~+and Sr~(2+)adsorption selectivity of zeolites in relation to radioactive decontamination[J].Journal of Asian Ceramic Societies,2015(3):245-250.
[18]O.A.Abdel Moamen,et al.Journal of the Taiwan Institute of Chemical Engineers[J]2015(55);133-144.
[19]刘爱平.斜发沸石对模拟核素Sr~(2+)的吸附/解吸动力学研究[A].矿物学报,2012,32(2):227-232.
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[22]G(o|¨)nul Keceli.Adsorption kinetics and equilibria of strontium onto kaolinite[J].Separation Science and Technology,2015,50(1):72-80.
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[27]S.Choung,M.Kim,J.S.Yang,et al.Effects of radiation and temperature on iodide sorption by surfactant-modified bentonite[J].Environ.Sci.Technol.,2014,48:9684-9691.
[28]桑净净.不同制备条件对SBA-15介孔氧化硅的形貌、比表面积和孔径分布的影响[J].化学工程师,2011,195(12):1-5.
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[30]Alain Walcarius,Louis Mercier.Mesoporousorgano silica adsorbents:nanoengineered materials for removal of organic and inorganic pollutants[J].J.Mater.Chem.,2010,20:4478-4511.
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[33]Lee Y C,Yang J W.Self-assembled flower-like TiO_2 on exfoliated graphite oxide or heavy metal removal[J].Journal of Industrial and Engineering Chemistry,2012,18(3):1178-1185.
[34]Wang XH,Zhu GR,Guo F.Removal of uranium(Ⅵ)ion from aqueous solution by SBA-15[J].Annals of Nuclear Energy,2013,56(6):151-157.
[35]Liu Y,Yuan L,Yuan Y,et al.A high efficient sorption of U(Ⅵ)from aqueous solution using amino-functionalzied SBA-15[J].J Radioanal Nucl Chem.2012,292:803-810.
[36]Yuan LY,Liu Ya L,Shi WQ.A novel mesoporous material for uranium extraction,dihydroimidazole functionalized SBA-15[J].J.Mater.Chem.,2012,22:17019-17026.
[37]Hang,Li J H.Ordered SBA-15 mesoporous silica with high amino functionalization for adsorption of heavy metal[J].Chin Sci Bull,2013.58(8):879-883.
[38]Owsari,Mohammad Reza,Sepehrian,et al.Cobalt(Ⅱ)Adsorption from aqueous solution using alginate-SBA-15nano-composite:Kinetic,Isotherm,Thermodynamic Studies and Neural Network Modeling[J].Materials Focus,2016.5(2).
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[49]Yin Z,He Q,Huang X,Zhang J,et al.Real-time DNA detection using Pt nanoparticle-decorated reduced graphene oxide field-effect transistors[J].Nanoscale,2012,4:293-297.
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[51]Zhang YK,Yan T,Yan LG,et al.Preparation of novel cobalt ferrite/chitosan grafted with graphene composite as effective adsorbents for mercury ions[J].J.Mol.Liq.,2014,198,:381-387.
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[53]Romanchuk AY,Slesarev AS,Kalmykov SN,et al.Graphene oxide for effective radionuclide removal[J].Phys Chem Chem Phys.2013,15(7):2321-2327.
[54]Chen H,Li JX,Zhang SW,et al.Study on the acid-base surface property of the magnetite graphene oxide and its usage for the removal of radiostrontium from aqueous solution[J].Radiochim.Acta,2013,101:785-794.
[55]Sun Y B,Shao DD,Chen CL,et al.Highly efficient enrichment of radionuclides on graphene oxide-supported polyaniline[J].Sci.Technol.,2013(47):9904-9910.
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