单组分夺氢型光引发剂的合成与性能表征
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- 英文论文题名：Synthesis and characterization of one-component photoinitiator
- 论文作者：简凯 ; 李东兵 ; 聂俊 ; 杨金梁
- 英文论文作者：Kai Jian ; DongbingLi ; Jun Nie ; Jingliang Yang ; College of Materials Science and Engineering ; Beijing University of Chemical Technology ; College of Science ; Beijing University of Chemical Technology ; Changzhou Institute of Advanced Materials Research ; Beijing University of Chemical Technology
- 年：2016
- 作者机构：北京化工大学材料科学与工程学院;北京化工大学理学院;北京化工大学常州先进材料研究院;
- 论文关键词：二苯甲酮助引发剂 ; 单组分光 ; 引发剂
- 英文论文关键词：benzophenoneco-initiator ; one-component ; photoinitiator
- 会议召开时间：2016-09-07
- 会议录名称：2016第十七届中国辐射固化年会暨首届安庆市化工新材料产业高峰论坛论文报告集
- 语种：中文
- 分类号：TQ314.241
- 学会代码：GGXH
- 会议名称：2016第十七届中国辐射固化年会暨首届安庆市化工新材料产业高峰论坛
- 会议地点：中国安徽安庆
- 主办单位：中国感光学会辐射固化专业委员会、安庆市政府
- 学会名称：中国感光学会辐射固化专业委员会
- 页数：5
- 文件大小：417k
- 原文格式：O
- 会议级别：全国
摘要
二苯甲酮(BP)是光固化领域中应用较广泛的夺氢型光引发剂之一,它通常需要与胺类等助引发剂复配以应用于光固化体系。然而,当助引发剂添加量较高时,会产生一定的气味并影响固化膜性能。为了降低助引发剂带来的不良影响,本文通过设计并合成了单组分夺氢型光引发剂MBPMP,并对其吸光性能、光引发性能以及在固化膜中的残留量进行了研究。
Benzophenone(BP) is one of the widely used Type Ⅱ photoinitiators in the field of UV-curing.The co-initiators(amines) usuallyneed to be added intoUV-curing system,but the high concentration of co-initiators will cause odor and effect properties of curing film.In order to reduce the adverse effects caused by the co-initiators,the photoinitiator(MBPMP) was synthesized in this article.The kinetics of photopolymerization,absorption performance and residues analysisof MBPMPwere studied.
Benzophenone(BP) is one of the widely used Type Ⅱ photoinitiators in the field of UV-curing.The co-initiators(amines) usuallyneed to be added intoUV-curing system,but the high concentration of co-initiators will cause odor and effect properties of curing film.In order to reduce the adverse effects caused by the co-initiators,the photoinitiator(MBPMP) was synthesized in this article.The kinetics of photopolymerization,absorption performance and residues analysisof MBPMPwere studied.
引文
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[8]Yagci Y.,Jockusch S.,Turro N.J.Macromolecules,2010,43,6245-6260.
[9]Aydin M.,Arsu V.,Yagci Y.,et al,Macromolecules,2005,38,4133-4138.
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