噻吩官能化硅烷的聚集诱导发光性质及聚集行为研究
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- 英文论文题名：The Aggregation-induced emission Enhancement and Aggregation Behavior of Thiophene Functionalized Silanes
- 论文作者：王雪凤 ; 冯圣玉 ; 刘洪国
- 英文论文作者：Xuefeng Wang ; Shengyu Feng ; Hongguo Liu ; Laboratory for Colloid and Interface Chemistry of Education Ministry ; Shandong University ; Key Laboratory of Special Functional Aggregated Materials ; Shandong University
- 年：2016
- 作者机构：山东大学胶体与界面化学教育部重点实验室;山东大学特种功能聚集体材料教育部重点实验室;
- 论文关键词：硅效应 ; 聚集诱导发光 ; 纳米粒子
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十一分会：胶体与界面化学
- 语种：中文
- 分类号：O621.2
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十一分会 ; 胶体与界面化学
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：251k
- 原文格式：D
- 会议级别：全国
摘要
利用"硅效应"的荧光增强和颜色调节作用~(1-2),我们设计合成了两种噻吩官能化硅烷:DPTB-MPS和DPTB-TMS。分别在分散和聚集状态研究了其荧光性质和粒子尺寸。由于分子内旋转受限机理,两种硅烷表现出良好的聚集诱导发光性质,其发光强度和聚集尺寸均随水含量的增加而增强。此外,还研究了其对硝基芳香化合物的荧光猝灭效应。本文为合成新型诱导发光硅烷和硝基化合物荧光探针提供了依据。
Taking advantage of fluorescence enhancement and color adjustment of "Silicon Effect",two kinds of thiophene functionalized silanes,DPTB-TMS and DPTB-MPS were designed and synthesized.Their fluorescence properties and particle size were both studied in disperse and aggregate states.Both fluorescence intensity and aggregate size increased as the water content increased.They all exhibited AIEE properties on account of the restriction of intramolecular rotations.Fluorescence quenching behavior to nitroaromatic was investigated.This work may provide guidance for design novel silicon-containing AIEE molecular and fluorescence probe for explosives.
Taking advantage of fluorescence enhancement and color adjustment of "Silicon Effect",two kinds of thiophene functionalized silanes,DPTB-TMS and DPTB-MPS were designed and synthesized.Their fluorescence properties and particle size were both studied in disperse and aggregate states.Both fluorescence intensity and aggregate size increased as the water content increased.They all exhibited AIEE properties on account of the restriction of intramolecular rotations.Fluorescence quenching behavior to nitroaromatic was investigated.This work may provide guidance for design novel silicon-containing AIEE molecular and fluorescence probe for explosives.
引文
[1]Quartapelle Procopio,E.;Mauro,M.;Panigati,M.;Donghi,D.;Mercandelli,P.;Sironi,A.;D’Alfonso,G.;De Cola,L.,J.Am.Chem.Soc.2010,132(41),14397-14399.
[2]Wang,H.;Liang,Y.;Xie,H.;Feng,L.;Lu,H.;Feng,S.,J.Mater.Chem.C.2014,2(28),5601.
[2]Wang,H.;Liang,Y.;Xie,H.;Feng,L.;Lu,H.;Feng,S.,J.Mater.Chem.C.2014,2(28),5601.