聚砜膦酸的合成及其酸碱复合质子交换膜材料制备
详细信息 查看官网全文
- 英文论文题名：Synthesis of Polysulfone Phosphonic Acid and Preparation of Acid-Base Composite Proton Exchange Membrane
- 论文作者：胡益栋 ; 曾广波 ; 岳宝华 ; 严六明
- 英文论文作者：Yidong Hu ; Guangbo Zeng ; Baohua Yue ; Liuming Yan ; Department of Chemistry ; Shanghai University
- 年：2016
- 作者机构：上海大学化学系;
- 论文关键词：质子交换膜 ; 酸碱复合膜 ; 聚砜 ; 膦酸 ; 三氮唑
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十分会：化学电源
- 语种：中文
- 分类号：O634.51;TB383.2
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十分会 ; 化学电源
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：247k
- 原文格式：D
- 会议级别：全国
摘要
本文利用丙酮基膦酸二甲酯与苯酚反应制得含膦酸酯基团的双酚A单体,再与4,4′-二氟二苯砜缩聚、经水解合成聚砜膦酸。在此基础上,与聚砜三氮唑复合,得到酸碱复合质子交换膜材料。本文利用~1H NMR和~(13)C NMR表征了聚合物的结构,并表征了材料的热稳定性、抗氧化性、吸水性、质子电导率、抗甲醇穿透率等性质。结果表明,本文制备的复合膜,性能大大优于其组成材料的性能,具有协同效应,是一种优越的质子交换膜。
Phosphonated bisphenol A was synthesized from dimethyl 2-oxopropylphosphonate and phenol,and then condensed with 4,4'-difluorophenyl sulfone forming polysulfone phosphonate.Polysulfone phosphonic acid was obtained by the following hydrolysis,and was composited with polysulfone triazole resulting in an acid-base composite proton exchange membrane material.The molecular structures of monomers and polymers were characterized via ~1H NMR and ~(13)C NMR,and the thermal stability,oxidation stability,water uptake,proton conductivity and methanol permeability were characterized.It was concluded that the composite membrane was an outstanding proton conducting material,greatly outperform its components attributing to a synergistic effect between the phosphonic acid groups and triazolyl groups.
Phosphonated bisphenol A was synthesized from dimethyl 2-oxopropylphosphonate and phenol,and then condensed with 4,4'-difluorophenyl sulfone forming polysulfone phosphonate.Polysulfone phosphonic acid was obtained by the following hydrolysis,and was composited with polysulfone triazole resulting in an acid-base composite proton exchange membrane material.The molecular structures of monomers and polymers were characterized via ~1H NMR and ~(13)C NMR,and the thermal stability,oxidation stability,water uptake,proton conductivity and methanol permeability were characterized.It was concluded that the composite membrane was an outstanding proton conducting material,greatly outperform its components attributing to a synergistic effect between the phosphonic acid groups and triazolyl groups.
引文
[1]Y.Zhang,B.Yue,S.Han,L.Yan.RSC Advances,2014,4:33702-33712.
[2]X.Zhang,B.Yue,L.Yan,G.Zeng,S.Tao.Int.J.Hydrogen Energy,2016,41:4740-4750.
[3]D.Plazuk,J.Zakrzewski.Phosphorus,2006,180:2709-2715.
[2]X.Zhang,B.Yue,L.Yan,G.Zeng,S.Tao.Int.J.Hydrogen Energy,2016,41:4740-4750.
[3]D.Plazuk,J.Zakrzewski.Phosphorus,2006,180:2709-2715.