MOFs派生多孔碳负载AgPd纳米合金材料的制备及其室温下催化甲酸产氢反应的研究
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- 英文论文题名：Hydrogen generation at ambient conditions:AgPd bimetal supported on metal–organic framework derived porous carbon as an efficient synergistic catalyst
- 论文作者：张仁泽 ; 张晓雨 ; 候冉冉 ; 冯成 ; 王春
- 英文论文作者：Renze Zhang ; Xiaoyu Zhang ; Ranran Hou ; Cheng Feng ; Chun Wang ; Department of Chemistry ; College of Science ; Agricultural University of Hebei
- 年：2016
- 作者机构：河北农业大学;
- 论文关键词：MOFs衍生炭材料 ; 甲酸 ; 储氢材料
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十九分会：纳米碳材料
- 语种：中文
- 分类号：O643.36;TQ116.2
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十九分会 ; 纳米碳材料
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：214k
- 原文格式：D
- 会议级别：全国
摘要
氢气在未来能源系统中具有十分重要的作用,但是限制氢气应用的储存、运输问题却难以解决。在众多储氢方法中,甲酸储氢是一种具有巨大应用潜力的储氢技术。本文以MOF-5派生新型纳米多孔炭材料为载体,负载AgPd纳米合金(Ag Pd/MOF-5-C)用于催化甲酸产氢反应。实验证明,该催化剂对于甲酸产氢反应时具有很高的催化活性。在30℃时,该催化剂的初始转化频率可以达到854 h~(-1)。正是由于纳米粒子的高分散度以及金属与载体间的相互作用,导致该催化剂具有较高的催化性能。
An efficient synergistic catalyst, AgPd bimetal supported on metal-organic framework derived porous carbon(AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H_2 selectivity and high catalytic activity in hydrogen generation from formic acid at ambient conditions. The initial turnover frequency could reach as high as 854 h~(-1). The combination of distinct interaction among bimetal, support and high dispersion of nanoparticles drastically enhances the catalytic performance of the resulted catalyst.
An efficient synergistic catalyst, AgPd bimetal supported on metal-organic framework derived porous carbon(AgPd/MOF-5-C), was fabricated for the first time. The catalyst exhibited 100% H_2 selectivity and high catalytic activity in hydrogen generation from formic acid at ambient conditions. The initial turnover frequency could reach as high as 854 h~(-1). The combination of distinct interaction among bimetal, support and high dispersion of nanoparticles drastically enhances the catalytic performance of the resulted catalyst.
引文
[1]Feng,C.;Wang,Y.E.;Gao,S.T.;Shang,N.Z.;Wang,C.Catal.Commun.2016,78:17-21.
[2]Peti,C.;Bandosz,T.J.Adv.Mater.2009,21:4753-4757.
[2]Peti,C.;Bandosz,T.J.Adv.Mater.2009,21:4753-4757.