气-液传感界面的构建及其对化学毒剂的气相传感
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- 英文论文题名：Development of the Gas-Liquid Sensing Interface and its Application in Organophosphorus Nerve Agent Mimics(DCP) Vapors Detection
- 论文作者：刘自如 ; 马原 ; 雷海瑞 ; 严军林 ; 刘静
- 英文论文作者：Ziru Liu ; Hairui Lei ; Yuan Ma ; Junlin Yan ; Jing Liu ; Key Lab of Applied Surface and Colloid Chemistry ; MOE ; School of Chemistry & Chemical Engineering ; Shaanxi Normal University
- 年：2016
- 作者机构：应用表面与胶体化学教育部重点实验室陕西师范大学化学化工学院;
- 论文关键词：界面组装 ; 两亲性荧光分子 ; 单分子薄膜 ; 传感 ; 氯磷酸二乙酯
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第二十四分会：超分子组装与软物质材料
- 语种：中文
- 分类号：O647
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第二十四分会 ; 超分子组装与软物质材料
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：299k
- 原文格式：D
- 会议级别：全国
摘要
本工作中,我们设计合成了两亲性BODIPY衍生物(BN1),并利用微转印技术制备了离子液体微阵列担载的气液传感界面。基于BN1的氨基与DCP之间的特异性化学反应,分子内的PET效应消失,荧光强度增强,从而实现了对DCP的"turn-on"传感。由于两亲分子BN1在微阵列化的离子液体气液界面上的表面富集特性,使得气体分子和荧光物种直接作用,提高了传感薄膜的响应速度和灵敏度。
In this work, an amphiphilic BODIPY derivative(BN1) was designed and synthesized. The gas-liquid sensing interface which loads on ionic liquid microarrays was fabricated by the microcontact printing technology. The sensing mechanism is based on a specific reaction between phosphoryl halides and the fluorescent probe BN1. When BN1 functionalized ILs microarrays are dipped in the DCP vapor, the reaction of amino unit with phosphorus oxychloride moiety blocks the PET process between amino group and BODIPY structure, leading a rapid and obvious increase in fluorescence intensity. The interfacial self-assembling of the amphiphilic molecule, BN1, can avoid the mass transfer limitation and improve the response speed and sensitivity of the sensing films largely.
In this work, an amphiphilic BODIPY derivative(BN1) was designed and synthesized. The gas-liquid sensing interface which loads on ionic liquid microarrays was fabricated by the microcontact printing technology. The sensing mechanism is based on a specific reaction between phosphoryl halides and the fluorescent probe BN1. When BN1 functionalized ILs microarrays are dipped in the DCP vapor, the reaction of amino unit with phosphorus oxychloride moiety blocks the PET process between amino group and BODIPY structure, leading a rapid and obvious increase in fluorescence intensity. The interfacial self-assembling of the amphiphilic molecule, BN1, can avoid the mass transfer limitation and improve the response speed and sensitivity of the sensing films largely.
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