不同印刷食品包装纸溶剂残留量及与存放时间相关性研究
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- 英文论文题名：Correlation of Solvent Residues and Storing Time of Different Printing Food Packaging Papers
- 论文作者：朱瑞芝 ; 刘凌璇 ; 刘志华 ; 张凤梅 ; 司晓喜 ; 王庆华 ; 白晓莉 ; 谢静 ; 詹建波
- 英文论文作者：ZHU Rui-Zhi ; LIU Ling-Xuan ; LIU Zhi-Hua ; ZHANG Feng-Mei ; SI Xiao-Xi ; WANG Qing-Hua ; BAI Xiao-Li ; XIE Jing ; ZHAN Jian-Bo ; Key Laboratory of Tobacco Chemistry ; R&D Center of China Tobacco Yunnan Industrial Co. ; Ltd. ; Yunnan Technician College
- 年：2016
- 作者机构：云南省烟草化学重点实验室云南中烟工业有限责任公司技术中心;云南技师学院;
- 论文关键词：印刷方式 ; 溶剂残留 ; 食品包装纸 ; 顶空-气相色谱/质谱联用法
- 英文论文关键词：Printing methods ; Solvent residues ; Food packing papers ; Headspace gas chromatography-mass spectrometry
- 会议召开时间：2016-12-01
- 会议录名称：中国烟草学会2016年度优秀论文汇编——烟草工业主题
- 语种：中文
- 分类号：TS206.4
- 学会代码：ZGYG
- 学会名称：中国烟草学会
- 页数：6
- 文件大小：327k
- 原文格式：D
摘要
采用顶空-气相色谱/质谱联用法对不同印刷方式(凹印、胶印、丝印和柔印)的食品包装纸中20种溶剂残留量进行了测定,分析了不同印刷方式食品包装纸中溶剂残留的差异及其随时间变化的规律。在优化的实验条件下,方法线性关系良好,20种溶剂相关系数均大于0.998,检出限在0.003~0.535 mg/m~2之间,回收率在84.8%~108.9%之间,相对标准偏差(n=5)在1.0%~5.1%之间。结果表明,采用凹印方式生产的食品包装纸溶剂残留总量远大于胶印、丝印和柔印的包装纸,且溶剂残留总量随存放时间的增加呈减小的趋势,前3天减小幅度较大。胶印、丝印和柔印的包装纸溶剂残留风险较低,印刷3天后可投入使用:对于采用凹印方式生产的产品,选择性地使用乙醇、乙酸乙酯等易挥发、低毒低污染溶剂,是提高凹印食品包装纸使用安全的有效途径。
A headspace gas chromatography/mass spectrometric(HS/GC-MS) method was used for the determination 20 solvent residues in food packing papers with different printing methods(gravure printing,offset printing,silk printing,and flexo printing).Under the optimized conditions,the linear calibration curves were obtained with correlation coefficients of more than 0.998 for twenty solvents.The detection limits were in the range of 0.003-0.535 mg/m~2.The recoveries were 84.8%-108.9%,and the RSD(n= 5) were1.0%-5.1%.Based on results,the solvent residues in gravure printing papers were much larger than other printing methods papers,and had a large decreasing in three days.A lower risk of solvent residues in food packing papers with offset,silk and flexo printing methods were found,and the product would be used after three days.The results showed that it was an effective way by using ethanol,ethyl acetate and other solvent that had the properties of easy volatile,low toxicity and low pollution to ensure the safety of the food packing paper with gravure printing method.
A headspace gas chromatography/mass spectrometric(HS/GC-MS) method was used for the determination 20 solvent residues in food packing papers with different printing methods(gravure printing,offset printing,silk printing,and flexo printing).Under the optimized conditions,the linear calibration curves were obtained with correlation coefficients of more than 0.998 for twenty solvents.The detection limits were in the range of 0.003-0.535 mg/m~2.The recoveries were 84.8%-108.9%,and the RSD(n= 5) were1.0%-5.1%.Based on results,the solvent residues in gravure printing papers were much larger than other printing methods papers,and had a large decreasing in three days.A lower risk of solvent residues in food packing papers with offset,silk and flexo printing methods were found,and the product would be used after three days.The results showed that it was an effective way by using ethanol,ethyl acetate and other solvent that had the properties of easy volatile,low toxicity and low pollution to ensure the safety of the food packing paper with gravure printing method.
引文
1 Mousavi S M,Desobry S,Hardy J.Food Eng.,1998,36:453-472
2 Lau O W,Wong S K.Anal.Chim.Acta,1997,347:249-256
3 HUANG Chong-Xing,WANG Zhi-Wei,WANG Shuang-Fei,XUE Mei-Gui.Packaging Engineering,2008,29(9):204-207黄崇杏,王志伟,王双飞,薛美贵.包装工程,2008,29(9):204-207
4 GB/T 26461-2011,Gravure Ink for Paper.National Standards of the People's Republic of China.纸张凹印油墨.中华人民共和国国家标准.GB/T 26461-2011
5 GB/T 26395-2011,Water Based Gravure Ink for Cigarette Packing.National Standards of the People's Republic of China水性烟包凹印油墨.中华人民共和国国家标准.GB/T 26395-2011
6 DAI Hong-Min,DAI Pei-Yan.China Packaging,2011,31(12):37-42戴宏民,戴佩燕.中国包装,2011,31(12):37-42
7 Nerin C,Asensio E.Anal.Bioanal.Chem.,2007,389:589-596
8 GB/T 18706-2008,Paper Based Laminated Material for Fresh-Keeping Packaging of Liquid Food.National Standards of the People's Republic of China液体食品保鲜包装用纸基复合材料.中华人民共和国国家标准.GB/T 18706-2008
9 GB/T 18192-2008,Paper Based Laminated Material using for Aseptic Packaging of Liquid Food.National Standards of the People's Republic of China.液体食品无菌包装用纸基复合材料.中华人民共和国国家标准.GB/T 18192-2008
10 WU Tian-Hua.Printing Field,2003,(7):15-16吴田骅.印刷杂志,2003,(7):15-16
11 SUN Shu-Jing.Printing Quality&Standardization,2014,(8):58-60孙书静.印刷质量与标准化,2014,(8):58-60
12 ZHAO Yun-Fang,LU She-Ming,QU Guo-Fu,LIU Chun-Bo,MENG Zhao-Yu,NI Chao-Min,CAO Qiu-E,MIAO MingMing.Journal of Instrumental Analysis,2009,28(8):954-957招云芳,陆舍铭,曲国福,刘春波,孟昭宇,倪朝敏,曹秋娥,缪明明.分析测试学报,2009,28(8):954-957
2 Lau O W,Wong S K.Anal.Chim.Acta,1997,347:249-256
3 HUANG Chong-Xing,WANG Zhi-Wei,WANG Shuang-Fei,XUE Mei-Gui.Packaging Engineering,2008,29(9):204-207黄崇杏,王志伟,王双飞,薛美贵.包装工程,2008,29(9):204-207
4 GB/T 26461-2011,Gravure Ink for Paper.National Standards of the People's Republic of China.纸张凹印油墨.中华人民共和国国家标准.GB/T 26461-2011
5 GB/T 26395-2011,Water Based Gravure Ink for Cigarette Packing.National Standards of the People's Republic of China水性烟包凹印油墨.中华人民共和国国家标准.GB/T 26395-2011
6 DAI Hong-Min,DAI Pei-Yan.China Packaging,2011,31(12):37-42戴宏民,戴佩燕.中国包装,2011,31(12):37-42
7 Nerin C,Asensio E.Anal.Bioanal.Chem.,2007,389:589-596
8 GB/T 18706-2008,Paper Based Laminated Material for Fresh-Keeping Packaging of Liquid Food.National Standards of the People's Republic of China液体食品保鲜包装用纸基复合材料.中华人民共和国国家标准.GB/T 18706-2008
9 GB/T 18192-2008,Paper Based Laminated Material using for Aseptic Packaging of Liquid Food.National Standards of the People's Republic of China.液体食品无菌包装用纸基复合材料.中华人民共和国国家标准.GB/T 18192-2008
10 WU Tian-Hua.Printing Field,2003,(7):15-16吴田骅.印刷杂志,2003,(7):15-16
11 SUN Shu-Jing.Printing Quality&Standardization,2014,(8):58-60孙书静.印刷质量与标准化,2014,(8):58-60
12 ZHAO Yun-Fang,LU She-Ming,QU Guo-Fu,LIU Chun-Bo,MENG Zhao-Yu,NI Chao-Min,CAO Qiu-E,MIAO MingMing.Journal of Instrumental Analysis,2009,28(8):954-957招云芳,陆舍铭,曲国福,刘春波,孟昭宇,倪朝敏,曹秋娥,缪明明.分析测试学报,2009,28(8):954-957