酸溶碱融-标准加入-ICP-OES法测定铍铀伴生矿石中的铍
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- 英文论文题名：Acid soluble alkali melting-standard addition-ICP-OES method for the determination of beryllium in beryllium associated uranium ore
- 论文作者：杜桂荣 ; 赵杰 ; 郭国龙 ; 丁红芳 ; 刘扬 ; 王春叶
- 英文论文作者：DU Gui-rong ; ZHAO Jie ; GUO Guo-long ; DING Hong-fang ; LIU Yang ; WANG Chun-ye ; Beijing research Institute of Chemical Engineering and Metallurgy ; CNNC ; Xi-an Lantian Uranium Co. ; Ltd. ; CNNC
- 年：2015
- 作者机构：核工业北京化工冶金研究院;西安中核蓝田铀业公司;
- 论文关键词：铍 ; ICP-OES ; 标准加入 ; 酸溶碱融
- 英文论文关键词：beryllium ; ICP-OES ; standard addition ; acid soluble alkali melting
- 会议召开时间：2015-09-21
- 会议录名称：中国核科学技术进展报告（第四卷）——中国核学会2015年学术年会论文集第9册（核技术经济与管理现代化分卷、核电子学与核探测技术分卷、核测试与分析分卷）
- 语种：中文
- 分类号：O657.31;P575
- 学会代码：EGVD
- 会议名称：中国核学会2015年学术年会
- 会议地点：中国四川绵阳
- 主办单位：中国核学会
- 学会名称：中国核学会
- 页数：5
- 文件大小：179k
- 原文格式：O
- 会议级别：全国
摘要
本研究为了解决采用酸溶碱融法溶样,ICP-OES法测定铍铀伴生矿石中的铍含量过程中产生的基体干扰问题。酸溶碱融溶解铍铀伴生矿石中的铍,加入的焦硫酸钾对ICP-OES法测定存在基体干扰。本研究主要阐述消除基体干扰的一些措施。从实验数据可知,控制称样量、焦硫酸钾加入量、定容体积和加标稀释倍数,能够有效消除焦硫酸钾对ICP-OES法测定结果的基体干扰,6次平行测定结果的相对标准偏差为3.39%,3次加标回收率分别为:104.4%、98.7%、101.2%。酸溶碱融法溶样,采取相应措施消除基体干扰,能够采用ICP-OES法进行准确测定。
In this study,in order to solve the soluble alkali fusion method of sample dissolution by acid,matrix interference problems generated by the ICP-OES method determination of beryllium uranium associated ore in the process of beryllium content.Thawing dissolved uranium ore of beryllium in beryllium associated acid soluble alkali,of matrix disturbance added potassium pyrosulfate on Determination of ICP-OES method.This research mainly discusses some measures to eliminate the matrix interference.From the experimental data shows,control said Coke potassium sulfate addition amount,sample volume,constant volume and standard dilution,can effectively eliminate the interference of matrix potassium pyrosulfate on determination results of ICP-OES method,6 parallel determination of the relative standard deviation is 3.39%.recovery rate is respectively:104.4%,98.7%,101.2%.Thawing method of sample dissolution dissolved in acid and alkali,take corresponding measures to eliminate the matrix interference,can be accurately measured by ICP-OES method.
In this study,in order to solve the soluble alkali fusion method of sample dissolution by acid,matrix interference problems generated by the ICP-OES method determination of beryllium uranium associated ore in the process of beryllium content.Thawing dissolved uranium ore of beryllium in beryllium associated acid soluble alkali,of matrix disturbance added potassium pyrosulfate on Determination of ICP-OES method.This research mainly discusses some measures to eliminate the matrix interference.From the experimental data shows,control said Coke potassium sulfate addition amount,sample volume,constant volume and standard dilution,can effectively eliminate the interference of matrix potassium pyrosulfate on determination results of ICP-OES method,6 parallel determination of the relative standard deviation is 3.39%.recovery rate is respectively:104.4%,98.7%,101.2%.Thawing method of sample dissolution dissolved in acid and alkali,take corresponding measures to eliminate the matrix interference,can be accurately measured by ICP-OES method.
引文
[1]曹成东,魏轶.发射光谱法同时测定地球化学样品中微量银铍硼锡铋钼.岩矿测试,2010,29(4),458-460.
[2]邵鑫,李小丹,何启生.ICP-AES测定地质样品中铍、硼和镓.光谱实验室,2006,23(5),1012-1014.
[3]王水清.含锡地质矿样中铍的测定.江西化工,2013,29(2),177-178.
[4]陈妍妍,刘军.电感耦合等离子体原子发射光谱法测定水和废水中钡、铍、钴、钒.理化检验:化学分册,2008,46(7),689-690.
[5]GB/T 17414.1-2010铍矿石化学分析方法第一部分:铍量测定埃利罗菁R光度法。
[2]邵鑫,李小丹,何启生.ICP-AES测定地质样品中铍、硼和镓.光谱实验室,2006,23(5),1012-1014.
[3]王水清.含锡地质矿样中铍的测定.江西化工,2013,29(2),177-178.
[4]陈妍妍,刘军.电感耦合等离子体原子发射光谱法测定水和废水中钡、铍、钴、钒.理化检验:化学分册,2008,46(7),689-690.
[5]GB/T 17414.1-2010铍矿石化学分析方法第一部分:铍量测定埃利罗菁R光度法。