EDTA淋洗修复重金属污染土壤技术研究进展
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摘要
EDTA由于其稳定、高效等特点而被作为常用的螯合剂,在重金属污染土壤淋洗修复中具有重要作用。本文结合国内外研究成果,从EDTA淋洗重金属污染土壤的影响因素、淋洗前后土壤重金属形态的变化、淋洗废液和修复后土壤的处理几个方面论述EDTA淋洗修复重金属污染土壤的研究现状。总结其存在的问题,最后提出EDTA淋洗修复重金属污染土壤技术实施意见和研究方向。
引文
[1]朱清清,邵超英,张琢,等.生物表面活性剂皂角苷增效去除土壤中重金属的研究[J].环境科学学报,2010(12):2491-2498.
[2]蔡美芳,李开明,谢丹平,等.我国耕地土壤重金属污染现状与防治对策研究[J].环境科学与技术,2014(S2):223-230.
[3]Wasay S A,Barrington S,Tokunaga S.Organic Acids for the In Situ Remediation of Soils Polluted by Heavy Metals:Soil Flushing in Columns[J].Water,2001,127(1-4):301-314(14).
[4]Weihua Z,Tsang D C W,Lo I M C.Removal of Pb by EDTA-washing in the presence of hydrophobic organic contaminants or anionic surfactant.[J].Journal of Hazardous Materials,2008,155(3):433-439.
[5]Brian E.Reed,Patrick C.Carriere,John C.Thompson,et al.Electronic(EK)remediation of a contaminated soil at several Pb concentrations and applied voltages[J].Journal of Soil Contamination,19%,5(2):95-120.
[6]Wasay S A,Barrington S F,Tokunaga S.Remediation of Soils Polluted by Heavy Metals using Salts of Organic Acids and Chelating Agents[J].Environmental Technology,1998,volumel9(4):369-379.
[7]P.K.Andrew Hong,Chelsea Li,Shankha K.Banerji,et al.Extraction,Recovery,and Biostability of EDTA for Remediation of Heavy Metal-Contaminated Soil[J].Journal of Soil Contamination,1999,8(1):81-103.
[8]Sun B,Zhao F J,Lombi E,et al.Leaching of heavy metals from contaminated soils using EDTA[J].Environmental Pollution,2001,113(2):111-120.
[9]Fangueiro D,Bermond A,Santos E,et al.Heavy metal mobility assessment in sediments based on a kinetic approach of the EDTA extraction:search for optimal experimental conditions[J].AnalyticaChimicaActa,2002,459(2):245-256.
[10]杨冰凡,胡鹏杰,李柱,等.重金属高污染农田土壤EDTA淋洗条件初探[J].土壤,2013(5):928-932.
[11]周井刚,蔡信德,王永强,等.利用ElYrA溶液淋洗修复重金属污染土壤[J].广州环境科学,2009(2):32-36.
[12]可欣,李培军,张昀,等.利用乙二胺四乙酸淋洗修复重金属污染的土壤及其动力学[J].应用生态学报,2007,18(3):601-606.
[13]董汉英,仇荣亮,赵芝灏,等.EDTA淋洗修复Cu污染土壤的去除效率与适宜淋洗剂用量的选取[J].中山大学学报:自然科学版,2010,49(3):135-139.
[14]Zhang W,Hao H,Tan F,et al.Influence of EDTA washing on the species and mobility of heavy metals residual in soils[J].Journal of Hazardous Materials,2010,173(1-3):369-376.
[15]Reed B E,CarrierePC,Moore R.Flushing of a Pb(II)contaminated soil using HC1,EDTA,and CaCl{sub2[J].Journal of Environmental Engineering,19%,122(1):48-50.
[16]Bernd N,RainerS,Robinson B H.Critical assessment of chelant-enhanced metal phytoextraction.[J].Environmental Science&Technology,2006,40(17):5225-32.
[17]Alkorta I,Hernandez-Allica J,Becerril J M,et al.Chelate-Enhanced Phytoremediation of Soils Polluted with Heavy Metals[J].Reviews in Environmental Science&Biotechnology,2004,3(1):55-70.
[18]YuJ,Klarup D.Extraction kinetics of copper,zinc,iron,and manganese from contaminated sediment using Disodium Ethylenediaminetetraacetate[J].Water Air&Soil Pollution,1994,75(3-4):205-225.
[19]Kedziorek M A M,Dupuy A,Bourg A C M,et al.Leaching of Cd and Pb from a Polluted Soil during the Percolation of EDTA:?Laboratory Column Experiments Modeled with a Non-Equilibrium SolubilizationStep[J].Environ,sci.technol,1998,32(11):1609-1614.
[20]M.D.Andrade,Prasher S O,Hendershot W H.Optimizing the molarity of a EDTA washing solution for saturated-soil remediation of trace metal contaminated soils.[J].Environmental Pollution,2007,147(3):781-790.
[21]陈晓婷,王欣,陈新.几种螯合剂对污染土壤的重金属提取效率的研究[J].江苏环境科技,2005,18(2):9-10.
[22]A.迪乔登,张兴仁.用络合剂从污染土壤中除去重金属的化学法和电化学法[J].国外金属矿选矿,2001,38(4):40-43.
[23]张利香,侯明.土壤中有效态汞的最佳萃取条件研究[J].农业环境科学学报,2006(06):1675-1678.
[24]Barona A,Aranguiz I,Eli As A.Metal associations in soils before and after EDTA extractive decontamination:implications for the effectiveness of further clean-up procedures[J].Environmental Pollution,2001,113(1):79-85.
[25]王显海,刘云国,曾光明,等.EDTA溶液修复重金属污染土壤的效果及金属的形态变化特征[J].环境科学,2006(5):1008-1012.
[26]曾滔.污染土壤重金属在EDTA萃取前后的形态分布研究[J].湖南人文科技学院学报,2008(2):16-18.
[27]Li W,Peters R W,Brewster,M.D,et al.Sequential extraction evaluation of heavy-metal-contaminated soil:How clean is clean?[J].Chemistry,1995.
[28]Mulligan C N,Yong R N,Cibbs B F.Remediation Technologies for Metal-Contaminated Soils and Groundwater:An Evaluation[J].Engineering Geology,2001,60(1-4):193-207.
[29]雷鸣,田中干也,廖柏寒,等.EDTA及其回收溶液治理重金属污染土壤的研究[J].环境工程学报,2007(5):88-93.
[30]Nortemann B.Biodegradation of EDTA.[J].Applied Microbiology&Biotechnology,1999,51(6):751-759.
[31]Pociecha M,Kastelec D,Lestan D.Electrochemical EDTA recycling after soil washing of Pb,Zn and Cd contaminated soil[J].Journal of Hazardous Materials,2011,192(2):714-21.
[32]Neza F,Domen L.Heap leaching of Pb and Zn contaminated soil using ozone/UV treatment of EDTA extractants.[J].Chemosphere,2006,63(10):1736-1743.
[33]Chia Chi L,Marshall W D.Recycling of complexometricextractants to remediate a soil contaminated with heavy metals.[J].Journal of Environmental Monitoring,2002,4(2):325-329.
[34]Hong PK A,Li C,Jiang W,et al.Chelating Agents for Extraction of Heavy Metals from Soil[J].EmergingTechnologies in Hazardous Waste Management,2001:9-20.
[35]Zeng Q R,Sauve S,,Allen HE,et al.Recycling EDTA solutions used to remediate metal-polluted soils.[J].Environmental Pollution,2005,133(2):225-231.
[36]曾清如,廖柏寒,杨仁斌,等.EDTA溶液萃取污染土壤中的重金属及其回收技术[J].中国环境科学,2003,23(6):597-601.
[37]Wu L H,Luo Y M,Xing X R,et al.EDTA-enhanced phytoremediation of heavy metal contaminated soil with Indian mustard and associated potential leaching risk[J].Agriculture Ecosystems&Environment,2004,102(3):307-318.
[38]王平,李江山,薛强.淋洗剂乙二胺四乙酸对重金属污染土工程特性的影响[J].岩土力学,2014(04).
[39]Bucheli-WitschelM,EgliT,Environmental fate and microbial degradation of aminopolycarboxylic acids.[J].Ferns Microbiology Reviews,2001,25(1):69-106.
[40]Li Y,Hu X,Song X,et al.Remediation of cadmium-contaminated soil by extraction with para-sulphonatothiacalix[4]arene,a novel supramolecular receptor[J].Environmental Pollution,2012,167(6):93-100.
[41]Chunling L,Zhenguo S,Xiangdong L.Enhanced phytoextraction of Cu,Pb,Zn and Cd with EDTA and EDDS.[J].Chemosphere,2005,59(59):1-11.
[42]丁竹红,胡忻,尹大强.螯合剂在重金属污染土壤修复中应用研究进展[J].生态环境学报,2009,18(2):777-782.
[43]Jelusic M,Lestan D.Effect of EDTA washing of metal polluted garden soils.Parti:Toxicity hazards and impact on soil properties[J].Science of the Total Environment,2014,475;132-141.
[44]赵景联.环境修复原理与技术[M].化学工业,2006.
[45]何泽能,李振山,籍国东.木质素盐在原油污染土壤清洗中的应用[J].环境污染治理技术与设备,2006(6):31-34.
[46]丁竹红,尹大强,胡忻,等.矿区附近农田土壤中重金属和矿质元素浸提研究[J].农业环境科学学报,2008。27(5):1774-1778.
[2]蔡美芳,李开明,谢丹平,等.我国耕地土壤重金属污染现状与防治对策研究[J].环境科学与技术,2014(S2):223-230.
[3]Wasay S A,Barrington S,Tokunaga S.Organic Acids for the In Situ Remediation of Soils Polluted by Heavy Metals:Soil Flushing in Columns[J].Water,2001,127(1-4):301-314(14).
[4]Weihua Z,Tsang D C W,Lo I M C.Removal of Pb by EDTA-washing in the presence of hydrophobic organic contaminants or anionic surfactant.[J].Journal of Hazardous Materials,2008,155(3):433-439.
[5]Brian E.Reed,Patrick C.Carriere,John C.Thompson,et al.Electronic(EK)remediation of a contaminated soil at several Pb concentrations and applied voltages[J].Journal of Soil Contamination,19%,5(2):95-120.
[6]Wasay S A,Barrington S F,Tokunaga S.Remediation of Soils Polluted by Heavy Metals using Salts of Organic Acids and Chelating Agents[J].Environmental Technology,1998,volumel9(4):369-379.
[7]P.K.Andrew Hong,Chelsea Li,Shankha K.Banerji,et al.Extraction,Recovery,and Biostability of EDTA for Remediation of Heavy Metal-Contaminated Soil[J].Journal of Soil Contamination,1999,8(1):81-103.
[8]Sun B,Zhao F J,Lombi E,et al.Leaching of heavy metals from contaminated soils using EDTA[J].Environmental Pollution,2001,113(2):111-120.
[9]Fangueiro D,Bermond A,Santos E,et al.Heavy metal mobility assessment in sediments based on a kinetic approach of the EDTA extraction:search for optimal experimental conditions[J].AnalyticaChimicaActa,2002,459(2):245-256.
[10]杨冰凡,胡鹏杰,李柱,等.重金属高污染农田土壤EDTA淋洗条件初探[J].土壤,2013(5):928-932.
[11]周井刚,蔡信德,王永强,等.利用ElYrA溶液淋洗修复重金属污染土壤[J].广州环境科学,2009(2):32-36.
[12]可欣,李培军,张昀,等.利用乙二胺四乙酸淋洗修复重金属污染的土壤及其动力学[J].应用生态学报,2007,18(3):601-606.
[13]董汉英,仇荣亮,赵芝灏,等.EDTA淋洗修复Cu污染土壤的去除效率与适宜淋洗剂用量的选取[J].中山大学学报:自然科学版,2010,49(3):135-139.
[14]Zhang W,Hao H,Tan F,et al.Influence of EDTA washing on the species and mobility of heavy metals residual in soils[J].Journal of Hazardous Materials,2010,173(1-3):369-376.
[15]Reed B E,CarrierePC,Moore R.Flushing of a Pb(II)contaminated soil using HC1,EDTA,and CaCl{sub2[J].Journal of Environmental Engineering,19%,122(1):48-50.
[16]Bernd N,RainerS,Robinson B H.Critical assessment of chelant-enhanced metal phytoextraction.[J].Environmental Science&Technology,2006,40(17):5225-32.
[17]Alkorta I,Hernandez-Allica J,Becerril J M,et al.Chelate-Enhanced Phytoremediation of Soils Polluted with Heavy Metals[J].Reviews in Environmental Science&Biotechnology,2004,3(1):55-70.
[18]YuJ,Klarup D.Extraction kinetics of copper,zinc,iron,and manganese from contaminated sediment using Disodium Ethylenediaminetetraacetate[J].Water Air&Soil Pollution,1994,75(3-4):205-225.
[19]Kedziorek M A M,Dupuy A,Bourg A C M,et al.Leaching of Cd and Pb from a Polluted Soil during the Percolation of EDTA:?Laboratory Column Experiments Modeled with a Non-Equilibrium SolubilizationStep[J].Environ,sci.technol,1998,32(11):1609-1614.
[20]M.D.Andrade,Prasher S O,Hendershot W H.Optimizing the molarity of a EDTA washing solution for saturated-soil remediation of trace metal contaminated soils.[J].Environmental Pollution,2007,147(3):781-790.
[21]陈晓婷,王欣,陈新.几种螯合剂对污染土壤的重金属提取效率的研究[J].江苏环境科技,2005,18(2):9-10.
[22]A.迪乔登,张兴仁.用络合剂从污染土壤中除去重金属的化学法和电化学法[J].国外金属矿选矿,2001,38(4):40-43.
[23]张利香,侯明.土壤中有效态汞的最佳萃取条件研究[J].农业环境科学学报,2006(06):1675-1678.
[24]Barona A,Aranguiz I,Eli As A.Metal associations in soils before and after EDTA extractive decontamination:implications for the effectiveness of further clean-up procedures[J].Environmental Pollution,2001,113(1):79-85.
[25]王显海,刘云国,曾光明,等.EDTA溶液修复重金属污染土壤的效果及金属的形态变化特征[J].环境科学,2006(5):1008-1012.
[26]曾滔.污染土壤重金属在EDTA萃取前后的形态分布研究[J].湖南人文科技学院学报,2008(2):16-18.
[27]Li W,Peters R W,Brewster,M.D,et al.Sequential extraction evaluation of heavy-metal-contaminated soil:How clean is clean?[J].Chemistry,1995.
[28]Mulligan C N,Yong R N,Cibbs B F.Remediation Technologies for Metal-Contaminated Soils and Groundwater:An Evaluation[J].Engineering Geology,2001,60(1-4):193-207.
[29]雷鸣,田中干也,廖柏寒,等.EDTA及其回收溶液治理重金属污染土壤的研究[J].环境工程学报,2007(5):88-93.
[30]Nortemann B.Biodegradation of EDTA.[J].Applied Microbiology&Biotechnology,1999,51(6):751-759.
[31]Pociecha M,Kastelec D,Lestan D.Electrochemical EDTA recycling after soil washing of Pb,Zn and Cd contaminated soil[J].Journal of Hazardous Materials,2011,192(2):714-21.
[32]Neza F,Domen L.Heap leaching of Pb and Zn contaminated soil using ozone/UV treatment of EDTA extractants.[J].Chemosphere,2006,63(10):1736-1743.
[33]Chia Chi L,Marshall W D.Recycling of complexometricextractants to remediate a soil contaminated with heavy metals.[J].Journal of Environmental Monitoring,2002,4(2):325-329.
[34]Hong PK A,Li C,Jiang W,et al.Chelating Agents for Extraction of Heavy Metals from Soil[J].EmergingTechnologies in Hazardous Waste Management,2001:9-20.
[35]Zeng Q R,Sauve S,,Allen HE,et al.Recycling EDTA solutions used to remediate metal-polluted soils.[J].Environmental Pollution,2005,133(2):225-231.
[36]曾清如,廖柏寒,杨仁斌,等.EDTA溶液萃取污染土壤中的重金属及其回收技术[J].中国环境科学,2003,23(6):597-601.
[37]Wu L H,Luo Y M,Xing X R,et al.EDTA-enhanced phytoremediation of heavy metal contaminated soil with Indian mustard and associated potential leaching risk[J].Agriculture Ecosystems&Environment,2004,102(3):307-318.
[38]王平,李江山,薛强.淋洗剂乙二胺四乙酸对重金属污染土工程特性的影响[J].岩土力学,2014(04).
[39]Bucheli-WitschelM,EgliT,Environmental fate and microbial degradation of aminopolycarboxylic acids.[J].Ferns Microbiology Reviews,2001,25(1):69-106.
[40]Li Y,Hu X,Song X,et al.Remediation of cadmium-contaminated soil by extraction with para-sulphonatothiacalix[4]arene,a novel supramolecular receptor[J].Environmental Pollution,2012,167(6):93-100.
[41]Chunling L,Zhenguo S,Xiangdong L.Enhanced phytoextraction of Cu,Pb,Zn and Cd with EDTA and EDDS.[J].Chemosphere,2005,59(59):1-11.
[42]丁竹红,胡忻,尹大强.螯合剂在重金属污染土壤修复中应用研究进展[J].生态环境学报,2009,18(2):777-782.
[43]Jelusic M,Lestan D.Effect of EDTA washing of metal polluted garden soils.Parti:Toxicity hazards and impact on soil properties[J].Science of the Total Environment,2014,475;132-141.
[44]赵景联.环境修复原理与技术[M].化学工业,2006.
[45]何泽能,李振山,籍国东.木质素盐在原油污染土壤清洗中的应用[J].环境污染治理技术与设备,2006(6):31-34.
[46]丁竹红,尹大强,胡忻,等.矿区附近农田土壤中重金属和矿质元素浸提研究[J].农业环境科学学报,2008。27(5):1774-1778.