二次可充锌空气电池用La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3钙钛矿催化剂研究
详细信息 查看官网全文
- 英文论文题名：The Research of Perovskite Oxides La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3 Catalyst for Rechargeable Zinc-air Batteries
- 论文作者：崔龙 ; 韩建 ; 赵中令
- 英文论文作者：Cui Long ; Han Jian ; Zhao Zhongling ; R&D Center of China FAW Co. ; Ltd.
- 年：2016
- 作者机构：中国第一汽车股份有限公司技术中心;
- 论文关键词：二次可充锌空气电池 ; 钙钛矿 ; 催化剂
- 英文论文关键词：rechargeable zinc-air battery ; Perovskite ; catalyst
- 会议召开时间：2016-10-26
- 会议录名称：2016中国汽车工程学会年会论文集
- 英文会议录名称：Proceedings of 2016 SAE-China Congress
- 语种：中文
- 分类号：TM911.41
- 学会代码：QCGC
- 会议名称：2016中国汽车工程学会年会暨展览会
- 会议地点：中国上海
- 主办单位：中国汽车工程学会
- 学会名称：中国汽车工程学会
- 页数：4
- 文件大小：871k
- 原文格式：O
- 会议级别：全国
摘要
本文采用溶胶-凝胶法制备了用于二次锌空气电池空气阴极的钙钛矿型催化剂La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3,并对其进行了表征和电化学性能测试。测试结果表明,催化剂的晶体结构为钙钛矿型,晶粒平均尺寸约为100nm。电解液浓度为4mol/L时,电池电流密度可达60mA/cm~2以上,实现30个充放电循环,有利于实现二次锌空气电池的应用。
In this paper,the perovskite oxides La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3 catalyst were prepared by sol-gel process and characterized by TG-DSC,XRD and SEM.According to the test,the catalyst La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3 has the perovskite structure and showed a relatively diameter of approximately 100 nm.The current density could reach 60mA/cm~2 when theelectrolyte concentration is 4mol/L.The battery has reach 30 cycles of charge-discharge,this is advantageous to the realization of the secondary zinc air battery application.
In this paper,the perovskite oxides La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3 catalyst were prepared by sol-gel process and characterized by TG-DSC,XRD and SEM.According to the test,the catalyst La_(0.6)K_(0.2)Sr_(0.2)Co_(0.8)Fe_(0.2)O_3 has the perovskite structure and showed a relatively diameter of approximately 100 nm.The current density could reach 60mA/cm~2 when theelectrolyte concentration is 4mol/L.The battery has reach 30 cycles of charge-discharge,this is advantageous to the realization of the secondary zinc air battery application.
引文
[1]景义军,郭际,孟宪玲,等.汽车用锌空气动力电池研究现状[J].电源技术,2011,35(10).
[2]叶红齐,杨鹰.氧电极催化剂研究[J].电源技术,2002,26(2):1101.
[3]Wei Wang,Hong-bin Zhang,Guo-dong Lin,et al.Study of Ag/La_(0.6)Sr_(0.4)MnO_3 catalyst for complete oxidation of methanol and ethanol at low concentrations[J].Applied catalyst B:Environmental 24(2000)219-232.
[2]叶红齐,杨鹰.氧电极催化剂研究[J].电源技术,2002,26(2):1101.
[3]Wei Wang,Hong-bin Zhang,Guo-dong Lin,et al.Study of Ag/La_(0.6)Sr_(0.4)MnO_3 catalyst for complete oxidation of methanol and ethanol at low concentrations[J].Applied catalyst B:Environmental 24(2000)219-232.