脂肪酸盐皂基体系的流变特性
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- 英文论文题名：Rheological properties of fatty acid soaps
- 论文作者：李芳芳 ; 陈明华 ; 张婉萍
- 英文论文作者：LI Fang-fang ; CHEN Ming-hua ; ZHANG Wan-ping ; School of Perfume and Aroma Technology ; Shanghai Institute of Technology ; JALA Corporation
- 年：2016
- 作者机构：上海应用技术学院香料香精技术与工程学院;伽蓝(集团)股份有限公司;
- 论文关键词：脂肪酸盐 ; 流变特性 ; 甘油 ; 表面活性剂 ; 乳化剂
- 英文论文关键词：Fatty acid salts ; rheological properties ; glycerin ; surfactants ; emlsifiers
- 会议召开时间：2016-06-15
- 会议录名称：第十一届中国化妆品学术研讨会论文集
- 英文会议录名称：The Proceedings of the 11th Seminar on Cosmetic China
- 语种：中文
- 分类号：TQ423
- 学会代码：ZGXE
- 会议名称：第十一届中国化妆品学术研讨会
- 会议地点：中国上海
- 主办单位：中国香料香精化妆品工业协会
- 学会名称：中国香料香精化妆品工业协会
- 页数：10
- 文件大小：1645k
- 原文格式：O
- 会议级别：全国
摘要
主要通过分析甘油、脂肪醇聚氧乙烯醚硫酸钠(SLES)、椰油酰胺丙基甜菜碱(CAPB)、烷基糖苷(APG)、肉豆蔻酸异丙酯(IPM)和硬脂酸甘油酯/PEG-100硬酯酸酯(Simulsol165)对皂基体系的稳态流变特性和动态流变特性的影响,研究了皂基体系微观结构的稳定性。研究表明,甘油、SLES、CAPB、APG、IPM、Simulsol 165单一的添加物不能同时改善皂基体系的稳态流变特性、动态流变特性和触变性,甘油、IPM和Simulsol165的混合物能够在使皂基体系剪切变稀过程中粘度整体增加的同时,储能和损耗模量减小,触变环面积变大,使体系的形变能力和触变性增强。
The rheological properties of fatty acid soaps with glycerin,sodium fatty alcohol ether sulfate(SLES),cocamidopropyl betaine(CAPB),alkylpolyglycoside(APG),isopropylmyristate(IPM),glyceyrl stearate and PEG-100 stearate(Simulsol 165) had been analyzed,and the stability of structure in the fatty acid soaps had been studied.There were no significant positive influence on all steady,oscillation and thixotropic rheological properties of fatty acid soaps with single additives,but the mixture of glycerin,isopropylmyristate,and glyceyrl stearate and PEG-100 stearate,with the results that apparent viscosity increased,energy storage modulus and loss modulus decreased,and the area of thixotropic ring changed larger,indicating that the steady stability,deformation stability and the stability of thixotropic structure were all improved.
The rheological properties of fatty acid soaps with glycerin,sodium fatty alcohol ether sulfate(SLES),cocamidopropyl betaine(CAPB),alkylpolyglycoside(APG),isopropylmyristate(IPM),glyceyrl stearate and PEG-100 stearate(Simulsol 165) had been analyzed,and the stability of structure in the fatty acid soaps had been studied.There were no significant positive influence on all steady,oscillation and thixotropic rheological properties of fatty acid soaps with single additives,but the mixture of glycerin,isopropylmyristate,and glyceyrl stearate and PEG-100 stearate,with the results that apparent viscosity increased,energy storage modulus and loss modulus decreased,and the area of thixotropic ring changed larger,indicating that the steady stability,deformation stability and the stability of thixotropic structure were all improved.
引文
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[14]J E Martin,G Moreno,C Valencia.Gallegos Influence of soap/polymer concentration ratio on the rheological properties of lithium lubricating greases modified with virgin LDPE[J].Journal of Industrial and Engineering Chemistry.2009,15,687-693.
[15]A S Mohamed,S Radimanc,S V Muniandyd.Rheological behaviours of the hexagonal and lamellar phases of glucopone(APG)surfactant[J],Colloids and Surfaces A:Physicochem.Eng.Aspects,2006,276,15-21.
[16]T Prachi,B S Carrie,J W Norman.Development of an in situ rheological method to characterize fatty acid crystallization in complex fluids[J].Colloids and Surfaces A:Physicochem.Eng.Aspects,2011,388,12-20.
[17]M K Jaroslav,J S Verica,B P Lidija.Rheological investigation on dynamic and structure of separated phases in polymer mixture-ionic surfactant ternary system[J].Carbohydrate Polymers.2008,74,193-200.
[18]雷屹.混合表面活性剂水体系的相行为与结构特性的研究[D].扬州大学硕士学位论文.2009.
[19]李翌.表面活性素在溶液中胶束化行为的研究[D].华东理工大学博士学位论文.2009.
[20]王菲.离子液体广友面活性荆棍合体和}生质研究[D].华东理工大学硕士学位论文.2010.
[21]李宁.正负离子表面活性剂双水相体系相区拓宽及萃取作用研究[D].山东科技大学硕士学位论文.2010.
[2]A B Herrick,J Eric.Manufacture of soap from fatty acids[J].The Journal of the American Oil Chemists'Society[J],1963,40:615-618.
[3].J W Mcbain,M C Field.Phase rule equilibria of acid soaps.I.Anhydrous Acid Potassium Laurate[J].J.Phys.Chem.,1932,37(6),675-684.
[4].M J Vold.The phase behavior of dodecyl sulfonic acid and of its alkali salts with water[J].J.Am.Chem.Soc,1941,63(5),1427-1432.
[5].M Tsuchiya,K Tsujii,K Maki.Statistical mechanical theory of the coagel-gel phase transition in ionic surfactant/water systems[J].J.Phys.Chem.,1994,98(24),6187-6194.
[6]W C Robert.Metal organic framework(MOF)liquid crystals.ID,2D and 3D ionic coordination polymer structures in the thermotropic mesophases of metal soaps,including alkaline earth,transition metal and lanthanide soaps[J].Curr Opin Colloid In,2008,13(4),288-302.
[7]冯尚华,王红霞,张高勇等.表面活性剂溶致液晶的流变学性质[J].化学进展.2004,16(5),687-695.
[8]赵静,表面活性剂聚集体流变性质的研究[D].山东师范大学,2011.
[9]游一兰.正负离子表面活性剂复配系统全相图、流变性质以及在萃取中的应用[D].湖南师范大学硕士学位论文.2009.
[10]刘高令,杜志平,王国永.LAS/AEO-9/肥皂/水拟三元体系的相行为和流变性能[J].日用化学工业.2010,40(1),1-5.
[11]R Claire,M S Mohammadi,J T Tiddy.Formulating liquid detergents with naturally derived surfactants-Phase behaviour,crystallisation and rheo-stability of primary alkyl sulphates based on coconut oil[J].Colloid Surface A.2009,338,119-128.
[12]J M Katona,V J Sovilj,L B Petrovic.Rheological investigation on dynamic and structure of separated phases in polymer mixture-ionic surfactant ternary system[J].Carbohyd Polym.2008,74,193-200.
[13]王红霞,张高勇.脂肪醇聚氧乙烯醚(15)/水体系相行为及流变性研究[J].日用化学工业.2001,31(2),1~4.
[14]J E Martin,G Moreno,C Valencia.Gallegos Influence of soap/polymer concentration ratio on the rheological properties of lithium lubricating greases modified with virgin LDPE[J].Journal of Industrial and Engineering Chemistry.2009,15,687-693.
[15]A S Mohamed,S Radimanc,S V Muniandyd.Rheological behaviours of the hexagonal and lamellar phases of glucopone(APG)surfactant[J],Colloids and Surfaces A:Physicochem.Eng.Aspects,2006,276,15-21.
[16]T Prachi,B S Carrie,J W Norman.Development of an in situ rheological method to characterize fatty acid crystallization in complex fluids[J].Colloids and Surfaces A:Physicochem.Eng.Aspects,2011,388,12-20.
[17]M K Jaroslav,J S Verica,B P Lidija.Rheological investigation on dynamic and structure of separated phases in polymer mixture-ionic surfactant ternary system[J].Carbohydrate Polymers.2008,74,193-200.
[18]雷屹.混合表面活性剂水体系的相行为与结构特性的研究[D].扬州大学硕士学位论文.2009.
[19]李翌.表面活性素在溶液中胶束化行为的研究[D].华东理工大学博士学位论文.2009.
[20]王菲.离子液体广友面活性荆棍合体和}生质研究[D].华东理工大学硕士学位论文.2010.
[21]李宁.正负离子表面活性剂双水相体系相区拓宽及萃取作用研究[D].山东科技大学硕士学位论文.2010.