染料分子在MOF孔道中的取向组装:偏振的多光子泵浦微腔激光
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- 英文论文题名：Oriented Assembly of Dye Molecules within MOF Channels:Polarized Multi-photon Pumped Micro-cavity Laser
- 论文作者：何桦浚 ; 马恩 ; 崔元靖 ; 郁建灿 ; 杨雨 ; 陈学元 ; 陈邦林 ; 钱国栋
- 英文论文作者：Huajun He ; En Ma ; Yuanjing Cui ; Jiancan Yu ; Yu Yang ; Xueyuan Chen ; Banglin Chen ; Guodong Qian ; State Key Laboratory of Silicon Materials ; Cyrus Tang Center for Sensor Materials and Applications ; School of Materials Science & Engineering ; Zhejiang University ; Key Laboratory of Optoelectronic Materials Chemistry and Physics ; Fujian Institute of Research on the Structure of Matter ; Chinese Academy of Sciences ; Department of Chemistry ; University of Texas at San Antonio
- 年：2016
- 作者机构：硅材料国家重点实验室,浙江大学材料科学与工程学院;光电材料化学与物理重点实验室,中国科学院福建物质结构研究所;德克萨斯大学圣安东尼奥分校化学系;
- 论文关键词：金属有机框架材料 ; 取向组装 ; 多光子泵浦激光 ; 偏振
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十二分会： 多孔功能材料
- 语种：中文
- 分类号：TN24;O627
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十二分会 ; 多孔功能材料
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：119k
- 原文格式：D
- 会议级别：全国
摘要
具有高偏振度的多光子泵浦激光由于兼具偏振光和多光子泵浦激光的优势因而在医学成像等生物光子学领域有着重要的应用前景~[1,2]。然而,由于现有激光增益材料难以同时满足大的多光子吸收截面和激射效率以及高度一致的取向性等要求,目前仍无法获得高偏振度的多光子泵浦激光。我们创新性地提出在金属-有机框架材料的孔道中取向组装有机激光染料来获得高偏振度多光子泵浦激光的设计思路:采用锌离子与多齿有机配体7-(4-羧基苯基)-3-羧基-喹啉配位合成了具有一维孔道的金属-有机框架材料ZJU-68,并利用孔道的限域作用原位高度取向组装有机激光染料分子,同时利用框架材料单晶的天然晶面作为谐振腔的反射镜面,获得了高偏振度(大于99.9%)的多光子泵浦激光。
To make use of the uniqueness of both polarization and multiphoton excitation~([1,2]),the polarized multi-photon pumped laser in single microcrystal is potentially useful for biological imaging,but has never been realized.The daunting challenge is that the existing laser gain material is difficult to simultaneously satisfy requirements of large multi-photon absorption cross section,high lasing efficiency and highly consistent orientation.We innovatively put forward the design idea of in situ oriented assembling dye molecules in MOF Channels to solve these difficulties:highly efficient pore confinement of ZJU-68 for highly orienting DMASM dye molecules,and suitable refraction index as well as perfect crystal morphology have enabled us to target the first example of polarized multi-photon-pumped laser in single solid-state microcrystal(degree of polarization > 99.9%).
To make use of the uniqueness of both polarization and multiphoton excitation~([1,2]),the polarized multi-photon pumped laser in single microcrystal is potentially useful for biological imaging,but has never been realized.The daunting challenge is that the existing laser gain material is difficult to simultaneously satisfy requirements of large multi-photon absorption cross section,high lasing efficiency and highly consistent orientation.We innovatively put forward the design idea of in situ oriented assembling dye molecules in MOF Channels to solve these difficulties:highly efficient pore confinement of ZJU-68 for highly orienting DMASM dye molecules,and suitable refraction index as well as perfect crystal morphology have enabled us to target the first example of polarized multi-photon-pumped laser in single solid-state microcrystal(degree of polarization > 99.9%).
引文
[1]Jameson,D.M.;Ross,J.A.;Chem.Rev.2010,110:2685.
[2]He,G.S.;Tan,L.S.;Zheng,Q.;Prasad,P.N.;Chem.Rev.2008,108:1245.
[2]He,G.S.;Tan,L.S.;Zheng,Q.;Prasad,P.N.;Chem.Rev.2008,108:1245.