柔性线状电极与储能器件
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- 英文论文题名：Flexible Wire-Shaped Electrodes and Energy Storage Devices
- 论文作者：马延文 ; 冯晓苗 ; 刘瑞卿 ; 林秀婧 ; 李谊 ; 黄镇东 ; 刘杰
- 英文论文作者：Yanwen Ma ; Xiaomiao Feng ; Ruiqing Liu ; Xiujing Lin ; Yi Li ; Zhendong Huang ; Jie Liu ; Key Laboratory for Organic Electronics & Information Displays and Institute of Advanced Materials ; Nanjing University of Posts & Telecommunications ; Department of Chemistry ; Duke University
- 年：2016
- 作者机构：有机电子与信息显示国家重点实验室培育基地南京邮电大学信息材料与纳米技术研究院;Department of Chemistry, Duke University;
- 论文关键词：线状柔性电极 ; 超级电容器 ; 锂硫电池 ; 锂空气电池
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第四十一分会：纳米材料与器件
- 语种：中文
- 分类号：TM53;TM912
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第四十一分会 ; 纳米材料与器件
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：172k
- 原文格式：D
- 会议级别：全国
摘要
可纺织储能器件是可穿戴电子器件的重要构件单元之一,它对传统的电极结构提出了新的要求,其中线状电极与器件是这一方向的发展的重点。我们在碳基线状电极及储能器件方面开展了系统的研究,具体如下:(1)利用湿纺制备出高导电碳纳米管/石墨烯复合纤维用于线状超级电容器,揭示出电极电阻对储能的损耗,并给出了通过多根并联来降低内阻的方法~[1]。(2)通过在金属丝上预生长NiO纳米墙阵列为基底生长高密度的碳纳米管薄膜,以该线状电极构建的超级电容器展示了优秀的比容量和倍率性能~[2]。(3)提出了碳纳米管-石墨烯-金属丝线状电极平台的制备方法,以此平台构建金属氧化物、MOF和导电聚合物等多功能电极,用于超级电容器等器件。(4)利用毛细作用制备石墨烯等碳基柔性线状电极,构筑了线状锂硫和锂空气电池。在报告中,除了介绍本课题组的线状电极与器件工作外,对线状能源器件的未来发展提出分析和展望。
Wire-shaped supercapacitors and batteries open up a possibility to provide energy for wearable electronics and help these portable devices being developed with smaller, lighter and thinner configuration than ever before. One critical issue to construct such a type of energy storage devices is engineering traditional electrode materials into fiber, wire or yarn architectures. In this talk, we present our effort aimed at manufacturing flexible wire-shaped carbon-based electrodes, including the preparation of CNT/graphene fibers using wet spinning approach, directly growing carbon nanofibers on Kovar metal wires, step-wisely growing MnO_2-CNT-graphene hybrids on Ni wires and in tubes. These achievements provided us a powerful platform for the preparation of high-performance wire-shaped supercapacitors, lithium-sulfur batteries and lithium-air batteries. Besides, we will give an outlook of the future development of wire-shaped energy storage devices in summary.
Wire-shaped supercapacitors and batteries open up a possibility to provide energy for wearable electronics and help these portable devices being developed with smaller, lighter and thinner configuration than ever before. One critical issue to construct such a type of energy storage devices is engineering traditional electrode materials into fiber, wire or yarn architectures. In this talk, we present our effort aimed at manufacturing flexible wire-shaped carbon-based electrodes, including the preparation of CNT/graphene fibers using wet spinning approach, directly growing carbon nanofibers on Kovar metal wires, step-wisely growing MnO_2-CNT-graphene hybrids on Ni wires and in tubes. These achievements provided us a powerful platform for the preparation of high-performance wire-shaped supercapacitors, lithium-sulfur batteries and lithium-air batteries. Besides, we will give an outlook of the future development of wire-shaped energy storage devices in summary.
引文
[1]Ma,Y.;Li,P.;Sedloff,J.;Zhang,X.,Zhang,H.,Liu,J.ACS Nano 2015,9:1352.
[2]Zhu,G.;Chen,J.;Zhang,Z.;Kang,Q.;Feng,X.;Li,Y.;Huang,Z.;Wang,L.,Ma,Y.Chem.Commun.2016,52:2721.
[2]Zhu,G.;Chen,J.;Zhang,Z.;Kang,Q.;Feng,X.;Li,Y.;Huang,Z.;Wang,L.,Ma,Y.Chem.Commun.2016,52:2721.