Covalent Organic Polymers(COPS):synthesis, design and clean energy application
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- 英文论文题名：Covalent Organic Polymers(COPS):synthesis, design and clean energy application
- 论文作者：Jianing Guo ; Yuanhui Cheng ; Zhonghua Xiang
- 英文论文作者：Jianing Guo ; Yuanhui Cheng ; Zhonghua Xiang ; Department of Chemical Engineering ; Beijing University of Chemical Technology
- 年：2016
- 作者机构：Department of Chemical Engineering, Beijing University of Chemical Technology;
- 英文论文关键词：covalent organic polymers ; energy conversion and storage ; oxygen reduction reaction ; electrocatalyst
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十六分会：纳米材料合成与组装
- 语种：英文
- 分类号：O634
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十六分会 ; 纳米材料合成与组装
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：129k
- 原文格式：D
- 会议级别：全国
摘要
The unique structure and properties make graphene very promise for a wide range of potential applications, including energy storage and conversion, electronics, sensors, and electrocatalysis[1-3]. Similar to grapheme, we developed series of covalent organic polymers(COPs), which were constructed from covent bonds(C-C coupling) between the ever-changing organic linkers by homo- or hetero-polymerization[4, 5]. Moreover, we have developed a class of covalent organic polymers(COPs) incorporating a metal(such as Fe, Co, Mn) with precisely controlled locations of nitrogen heteroatoms and holes were synthesized from various N-containing metal–organic complexes[2, 6]. Owing to their high porosity, precisely-controlled molecular structures and multi-functionalities, COPs hold great potential for efficient energy conversion and storage, particularly as efficient metal-free electrocatalysts for oxygen reduction reaction(ORR) in fuel cells[1, 5, 7]. As to the energy storage, the synthesized N-CPAF-1 possesses large capacitance(385 F/g) and excellent performance stability without any loss in capacitance after 9000 charge–dischargecycles[8].
The unique structure and properties make graphene very promise for a wide range of potential applications, including energy storage and conversion, electronics, sensors, and electrocatalysis[1-3]. Similar to grapheme, we developed series of covalent organic polymers(COPs), which were constructed from covent bonds(C-C coupling) between the ever-changing organic linkers by homo- or hetero-polymerization[4, 5]. Moreover, we have developed a class of covalent organic polymers(COPs) incorporating a metal(such as Fe, Co, Mn) with precisely controlled locations of nitrogen heteroatoms and holes were synthesized from various N-containing metal–organic complexes[2, 6]. Owing to their high porosity, precisely-controlled molecular structures and multi-functionalities, COPs hold great potential for efficient energy conversion and storage, particularly as efficient metal-free electrocatalysts for oxygen reduction reaction(ORR) in fuel cells[1, 5, 7]. As to the energy storage, the synthesized N-CPAF-1 possesses large capacitance(385 F/g) and excellent performance stability without any loss in capacitance after 9000 charge–dischargecycles[8].
The unique structure and properties make graphene very promise for a wide range of potential applications, including energy storage and conversion, electronics, sensors, and electrocatalysis[1-3]. Similar to grapheme, we developed series of covalent organic polymers(COPs), which were constructed from covent bonds(C-C coupling) between the ever-changing organic linkers by homo- or hetero-polymerization[4, 5]. Moreover, we have developed a class of covalent organic polymers(COPs) incorporating a metal(such as Fe, Co, Mn) with precisely controlled locations of nitrogen heteroatoms and holes were synthesized from various N-containing metal–organic complexes[2, 6]. Owing to their high porosity, precisely-controlled molecular structures and multi-functionalities, COPs hold great potential for efficient energy conversion and storage, particularly as efficient metal-free electrocatalysts for oxygen reduction reaction(ORR) in fuel cells[1, 5, 7]. As to the energy storage, the synthesized N-CPAF-1 possesses large capacitance(385 F/g) and excellent performance stability without any loss in capacitance after 9000 charge–dischargecycles[8].
引文
[1]Z.Xiang,R.Mercado,J.M.Huck,H.Wang,Z.Guo,W.Wang,D.Cao,M.Haranczyk,B.Smit,J Am Chem Soc,137(2015)13301-13307.
[2]Z.Xiang,Y.Xue,D.Cao,L.Huang,J.-F.Chen,L.Dai,Angewandte Chemie International Edition,53(2014)2433-2437.
[3]Z.Xiang,Z.Hu,D.Cao,W.Yang,J.Lu,B.Han,W.Wang,Angew Chem Int Ed Engl,50(2011)491-494.
[4]Z.Xiang,D.Cao,J.Mater.Chem.A,1(2013)2691-2718.
[5]Z.Xiang,D.Cao,L.Huang,J.Shui,M.Wang,L.Dai,Advanced materials,26(2014)3315-3320.
[6]Z.Xiang,D.Cao,Macromolecular rapid communications,33(2012)1184-1190.
[7]Z.Xiang,X.Zhou,C.Zhou,S.Zhong,X.He,C.Qin,D.Cao,Journal of Materials Chemistry,22(2012)22663.
[8]Z.Xiang,D.Wang,Y.Xue,L.Dai,J.F.Chen,D.Cao,Scientific reports,5(2015)8307.
[2]Z.Xiang,Y.Xue,D.Cao,L.Huang,J.-F.Chen,L.Dai,Angewandte Chemie International Edition,53(2014)2433-2437.
[3]Z.Xiang,Z.Hu,D.Cao,W.Yang,J.Lu,B.Han,W.Wang,Angew Chem Int Ed Engl,50(2011)491-494.
[4]Z.Xiang,D.Cao,J.Mater.Chem.A,1(2013)2691-2718.
[5]Z.Xiang,D.Cao,L.Huang,J.Shui,M.Wang,L.Dai,Advanced materials,26(2014)3315-3320.
[6]Z.Xiang,D.Cao,Macromolecular rapid communications,33(2012)1184-1190.
[7]Z.Xiang,X.Zhou,C.Zhou,S.Zhong,X.He,C.Qin,D.Cao,Journal of Materials Chemistry,22(2012)22663.
[8]Z.Xiang,D.Wang,Y.Xue,L.Dai,J.F.Chen,D.Cao,Scientific reports,5(2015)8307.