Synthesis,crystal structures and luminescence performance of a cage and a porous Pb~(2+) coordination polymer
详细信息 查看官网全文
- 英文论文题名：Synthesis,crystal structures and luminescence performance of a cage and a porous Pb~(2+) coordination polymer
- 论文作者：Xiang Jing
- 英文论文作者：Xiang Jing ; College of Chemistry and Environmental Engineering ; Yangtze University
- 年：2016
- 作者机构：College of Chemistry and Environmental Engineering,Yangtze University;
- 英文论文关键词：Porous structure ; Cage ; luminescence ; sensors
- 会议召开时间：2016-09-23
- 会议录名称：中部四省化学化工学会2016年学术年会摘要集
- 语种：英文
- 分类号：O641.4
- 学会代码：JXHX
- 会议名称：中部四省化学化工学会2016年学术年会
- 会议地点：中国江西南昌
- 主办单位：中国化学会湖北代表处
- 学会名称：江西省化学化工学会
- 页数：1
- 文件大小：225k
- 原文格式：D
- 会议级别：地方
摘要
Metal–organic frameworks(MOFs) are a rapidly growing class of hybrid materials with many multifunctional properties.As peculiar metal-organic molecular architectures,the constructing of cage molecules and porous structure is also of great interest for their remarkable structural characteristics and well-defined cavities.The nature of porosity in the MOFs plays a central role in their functional properties.In order to improve their functionality and application,the strategy of attaching some functional groups such as –NH2,-OH,-SH and –COOH to the selected ligands have been proven to be an very effective synthetic route to construct MOFs with these free-standing functional groups decorating their the cavities or porosities that will significantly enhance their functions.Recently,tetrazolate and their derivatives as five-membered N-heterocyclic azoles also have received extensive attention not only because of the richness of properties,but also for their excellent stabilities to construct the novel MOFs.Although tetrazole ligand(tz) has four available N atoms to bond the metal ions,not all the N atoms will take participation in the coordination in most reported tetrazole-based MOFs.It is expectable that the uncoordinated N atoms from tz ligand will functionalize their porosity and cavity if such type of MOF are obtained.
Metal–organic frameworks(MOFs) are a rapidly growing class of hybrid materials with many multifunctional properties.As peculiar metal-organic molecular architectures,the constructing of cage molecules and porous structure is also of great interest for their remarkable structural characteristics and well-defined cavities.The nature of porosity in the MOFs plays a central role in their functional properties.In order to improve their functionality and application,the strategy of attaching some functional groups such as –NH2,-OH,-SH and –COOH to the selected ligands have been proven to be an very effective synthetic route to construct MOFs with these free-standing functional groups decorating their the cavities or porosities that will significantly enhance their functions.Recently,tetrazolate and their derivatives as five-membered N-heterocyclic azoles also have received extensive attention not only because of the richness of properties,but also for their excellent stabilities to construct the novel MOFs.Although tetrazole ligand(tz) has four available N atoms to bond the metal ions,not all the N atoms will take participation in the coordination in most reported tetrazole-based MOFs.It is expectable that the uncoordinated N atoms from tz ligand will functionalize their porosity and cavity if such type of MOF are obtained.
Metal–organic frameworks(MOFs) are a rapidly growing class of hybrid materials with many multifunctional properties.As peculiar metal-organic molecular architectures,the constructing of cage molecules and porous structure is also of great interest for their remarkable structural characteristics and well-defined cavities.The nature of porosity in the MOFs plays a central role in their functional properties.In order to improve their functionality and application,the strategy of attaching some functional groups such as –NH2,-OH,-SH and –COOH to the selected ligands have been proven to be an very effective synthetic route to construct MOFs with these free-standing functional groups decorating their the cavities or porosities that will significantly enhance their functions.Recently,tetrazolate and their derivatives as five-membered N-heterocyclic azoles also have received extensive attention not only because of the richness of properties,but also for their excellent stabilities to construct the novel MOFs.Although tetrazole ligand(tz) has four available N atoms to bond the metal ions,not all the N atoms will take participation in the coordination in most reported tetrazole-based MOFs.It is expectable that the uncoordinated N atoms from tz ligand will functionalize their porosity and cavity if such type of MOF are obtained.
引文
[1]M.Zhu,X.-Z.Song,S.-Y.Song,S.-N.Zhao,X.Meng,L.-L.Wu,C.Wang,H.-J.Zhang,Adv.Sci.2015,2,1500012