Synthesis,structure and luminescence properties of Tb_4 and Eu_4 clusters
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- 英文论文题名：Synthesis,structure and luminescence properties of Tb_4 and Eu_4 clusters
- 论文作者：Wen-Min Wang ; Cai-Feng Zhang
- 英文论文作者：Wen-Min Wang ; Cai-Feng Zhang ; Department of Chemistry ; Taiyuan Normal University ; Shanxi Engineering Research Center of Humic Acid
- 年：2016
- 作者机构：Department of Chemistry,Taiyuan Normal University;Shanxi Engineering Research Center of Humic Acid;
- 英文论文关键词：Tb_4 and Eu_4 clusters ; crystal structure ; Luminescence properties
- 会议召开时间：2016-12-19
- 会议录名称：中国晶体学会第六届学术年会暨会员代表大会（功能分子晶体分会）论文摘要集
- 英文会议录名称：Abstracts of the 6th Annual Conference of Chinese Crystallographic Society
- 语种：英文
- 分类号：O641.4
- 学会代码：ZGJY
- 会议名称：中国晶体学会第六届学术年会暨会员代表大会（功能分子晶体分会）
- 会议地点：中国广东广州
- 主办单位：中国晶体学会
- 学会名称：中国晶体学会
- 页数：1
- 文件大小：357k
- 原文格式：D
- 会议级别：全国
摘要
Currently,the study of lanthanide-based functional complexes has become one of the research hotspots owing to their potential properties in catalysis,magnetism and luminescence.[1-3] In this paper,two Ln4 clusters,[Ln4(dbm)4(L)6(μ3-OH)2]·[solvent](Ln = Tb(1) and Eu(2),HL = 5-(4-methylbenzylidene)-8-hydroxylquinoline,dbm = 1,3-diphenyl-1,3-propanedione)(Fig.1),have been synthesized by using solvent evaporation method.These complexes were characterized by the single crystal X-ray diffraction,elemental analysis(EA),powder X-ray diffraction(PXRD),TG investigated,and further studied them by using luminescent spectra.Luminescence properties studies reveal that 1 and 2 exhibit the characteristic emissions of TbIII and EuIII ions,respectively.(Fig.2).
Currently,the study of lanthanide-based functional complexes has become one of the research hotspots owing to their potential properties in catalysis,magnetism and luminescence.[1-3] In this paper,two Ln4 clusters,[Ln4(dbm)4(L)6(μ3-OH)2]·[solvent](Ln = Tb(1) and Eu(2),HL = 5-(4-methylbenzylidene)-8-hydroxylquinoline,dbm = 1,3-diphenyl-1,3-propanedione)(Fig.1),have been synthesized by using solvent evaporation method.These complexes were characterized by the single crystal X-ray diffraction,elemental analysis(EA),powder X-ray diffraction(PXRD),TG investigated,and further studied them by using luminescent spectra.Luminescence properties studies reveal that 1 and 2 exhibit the characteristic emissions of TbIII and EuIII ions,respectively.(Fig.2).
Currently,the study of lanthanide-based functional complexes has become one of the research hotspots owing to their potential properties in catalysis,magnetism and luminescence.[1-3] In this paper,two Ln4 clusters,[Ln4(dbm)4(L)6(μ3-OH)2]·[solvent](Ln = Tb(1) and Eu(2),HL = 5-(4-methylbenzylidene)-8-hydroxylquinoline,dbm = 1,3-diphenyl-1,3-propanedione)(Fig.1),have been synthesized by using solvent evaporation method.These complexes were characterized by the single crystal X-ray diffraction,elemental analysis(EA),powder X-ray diffraction(PXRD),TG investigated,and further studied them by using luminescent spectra.Luminescence properties studies reveal that 1 and 2 exhibit the characteristic emissions of TbIII and EuIII ions,respectively.(Fig.2).
引文
[1]Edelmann,F.T.Chem.Soc.Rev.2009,38,2253.
[2]Wang,W.M.;Zhang,H.X.;Wang,S.Y.;Shen,H.Y.;Gao,H.L.;Cui,J.Z.;Zhao,B.Inorg.Chem.2015,54,10610.
[3]Xu,H.;Cao,C.S.Zhao,B.Chem.Commun.2015,51,10280.
[2]Wang,W.M.;Zhang,H.X.;Wang,S.Y.;Shen,H.Y.;Gao,H.L.;Cui,J.Z.;Zhao,B.Inorg.Chem.2015,54,10610.
[3]Xu,H.;Cao,C.S.Zhao,B.Chem.Commun.2015,51,10280.