线性-树枝状表面活性剂的合成及加脂应用
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- 英文论文题名：Synthesis and Application of Linear-dendritic Polymer with Fatliquoring Functions for Leather Procession
- 论文作者：王学川 ; 郭笑笑 ; 王海军
- 英文论文作者：WANG Xue-chuan ; GUO Xiao-xiao ; WANG Hai-jun ; College of Light Industry Science and Engineering ; Shaanxi University of Science and Technology
- 年：2016
- 作者机构：陕西科技大学轻工科学与工程学院;
- 论文关键词：树枝状聚合物 ; 表面张力 ; 加脂剂
- 英文论文关键词：linear-dendritic polymer ; surface tension ; fatliquoring agen
- 会议召开时间：2016-07-27
- 会议录名称：2016第十一届全国皮革化学品学术交流会暨中国皮革协会技术委员会第21届年会摘要集
- 英文会议录名称：Abstracts of 2016 the 11th National Conference on Leather Chemicals & 21st Annual Convention of China Leather Science and Technology Commission
- 语种：中文
- 分类号：TQ423;TS544
- 学会代码：ZGHG
- 会议名称：2016第十一届全国皮革化学品学术交流会暨中国皮革协会技术委员会第21届年会
- 会议地点：中国山东济南
- 主办单位：中国皮革协会技术委员会、中国皮革协会皮革化工专业委员会、中国化工学会精细化工专业委员会
- 学会名称：中国化工学会
- 页数：1
- 文件大小：58k
- 原文格式：O
- 会议级别：全国
摘要
利用月桂酰氯对聚酰胺-胺(PAMAM-OH)进行改性,合成了一种线性-树枝状聚合物(PAMAM-3),其PAMAM和月桂酰氯的摩尔比为1:3,使用FT-IR、~1H NMR、GPC、羟值测定和动态光散射(DLS)等手段研究了PAMAM-3的结构和粒径。结果表明,产物的接枝率为37.14%,乳液平均粒径为161.3 nm。PAMAM-3能够在较低浓度下降低水的表面张力,其表面张力为26.32 mN/m。将合成的PAMAM-3应用于皮革加脂工序中,使用FT-IR、XPS、SEM和TG等手段研究了PAMAM-3处理后的蓝湿革的结构、物理机械性能和热力学性能。研究证实,处理后的蓝湿革中PAMAM-3与胶原纤维之间有较强的物理化学作用,加脂后的皮革柔软性和增厚性有所提高。
The liner-dendritic polymer(PAMAM-3) has been synthesized successfully by the reaction of poly(amido) amine(PAMAM) and lauroyl chloride in N,N-dimethylformamide(DMF).The mole ratio of PAMAM and lauroyl chloride was 1:3.The structures and size of PAMAM-3 were characterized by FT-IR,~1H NMR,GPC,DLS and the value of hydroxyl.The result showed that the grafting rate was 37.14%and the average particle size of PAMAM-3 was 161.3 nm.The surface tension of water could decrease by the low concentration of the PAMAM-3,and the surface tension basically tended to 26.32 mN/m.The influence of the PAMAM-3 on the structure,thermal stability and mechanical properties of the wet blue leather with fatliquoring procession was investigated by FT-IR,XPS,SEM and TG The result indicated that the introduced PAMAM-3 was linked the collagen fibers by strong interaction and the thickening rate and flexibility of leather could improve.
The liner-dendritic polymer(PAMAM-3) has been synthesized successfully by the reaction of poly(amido) amine(PAMAM) and lauroyl chloride in N,N-dimethylformamide(DMF).The mole ratio of PAMAM and lauroyl chloride was 1:3.The structures and size of PAMAM-3 were characterized by FT-IR,~1H NMR,GPC,DLS and the value of hydroxyl.The result showed that the grafting rate was 37.14%and the average particle size of PAMAM-3 was 161.3 nm.The surface tension of water could decrease by the low concentration of the PAMAM-3,and the surface tension basically tended to 26.32 mN/m.The influence of the PAMAM-3 on the structure,thermal stability and mechanical properties of the wet blue leather with fatliquoring procession was investigated by FT-IR,XPS,SEM and TG The result indicated that the introduced PAMAM-3 was linked the collagen fibers by strong interaction and the thickening rate and flexibility of leather could improve.
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