一步法合成可调双介孔孔道Fe-SBA-1
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- 英文论文题名：One-step Synthesis of Tunable Double Mesoporous Fe-SBA-15
- 论文作者：赵会玲 ; 宋江闯 ; 胡军 ; 刘洪来
- 英文论文作者：Huiling Zhao ; Jiangchuang Song ; Jun Hu ; Honglai Liu ; Laboratory for Advanced Materials ; Department of Chemistry ; East China University of Science and Technology
- 年：2016
- 作者机构：华东理工大学化学系;教育部先进材料及其制备重点实验室;
- 论文关键词：双介孔孔道 ; SBA-15 ; 铁掺杂 ; 形貌
- 英文论文关键词：dual mesoporous stucture ; SBA-15 ; Fe-Doped ; morphology
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第三十二分会： 多孔功能材料
- 语种：中文
- 分类号：TB383.4
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第三十二分会 ; 多孔功能材料
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：290k
- 原文格式：D
- 会议级别：全国
摘要
采用简单的一步法合成了具有双介孔孔道的铁掺杂介孔材料Fe-SBA-15,反应体系中无机盐FeCl_3加剂量对介孔材料SBA-15的孔道结构、形貌和性能产生了显著的影响。N_2吸脱附等温线(BET)结果表明,系列Fe-SBA-15样品均具有规整的孔道结构和较高的比表面积,且随加入铁盐量的增加比表面积有所下降。随着FeCl_3含量增加,样品中出现两种尺寸的介孔孔道结构,在3.5 nm左右有一规整孔道,而另一孔道随着FeCl_3加入量的增大而逐渐增大,从7.8 nm增大到15.6 nm。
The synthesis and properties of Fe-SBA-15 mesoporous materials influenced by the addition of FeCl_3are investigated.Powder X-ray diffraction(XRD) pattern indicates that samples are structured hexagonal pore structure,N_2 adsorption-desorption isothermals,SEM and TEM images show that after doped samples still preserved the ordered hexagonal structure and high BET surface area,and the surface area decreased with the increase the amounts of FeCl_3.These samples exhibit structures with dual mesoporous pore sizes.One is about 3.5nm and the other increases from 7.8 nm to 15.6 nm with the increase the amounts of FeCl_3.
The synthesis and properties of Fe-SBA-15 mesoporous materials influenced by the addition of FeCl_3are investigated.Powder X-ray diffraction(XRD) pattern indicates that samples are structured hexagonal pore structure,N_2 adsorption-desorption isothermals,SEM and TEM images show that after doped samples still preserved the ordered hexagonal structure and high BET surface area,and the surface area decreased with the increase the amounts of FeCl_3.These samples exhibit structures with dual mesoporous pore sizes.One is about 3.5nm and the other increases from 7.8 nm to 15.6 nm with the increase the amounts of FeCl_3.
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