CH键伸缩振动激发对于F+CHD_3反应的动力学影响
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- 英文论文题名：Effect of CH Stretching Excitation on the Reaction Dynamics of F + CHD_3
- 论文作者：吴国荣 ; 杨家岳 ; 张冬 ; 陈震 ; 姜波 ; 戴东旭 ; 张东辉 ; 杨学明
- 英文论文作者：Guorong Wu ; Jiayue Yang ; Dong Zhang ; Zhen Chen ; Bo Jiang ; Dongxu Dai ; Donghui Zhang ; Xueming Yang ; State Key Laboratory of Molecular Reaction Dynamics ; Dalian Institute of Chemical Physics
- 年：2016
- 作者机构：大连化学物理研究所分子反应动力学国家重点实验室;
- 论文关键词：分子反应动力学 ; 振动激发
- 会议召开时间：2016-07-01
- 会议录名称：中国化学会第30届学术年会摘要集-第四十四分会：化学动力学
- 语种：中文
- 分类号：O641.1;O643.1
- 学会代码：ZGHY
- 会议名称：中国化学会第30届学术年会-第四十四分会 ; 化学动力学
- 会议地点：中国辽宁大连
- 主办单位：中国化学会
- 学会名称：中国化学会
- 页数：1
- 文件大小：149k
- 原文格式：D
- 会议级别：全国
摘要
结合交叉分子束和时间切片离子速度成像技术,我们详细地研究了振动激发态的基元化学反应:F+CHD_3(v_1=1)。[1,2]通过精确测量分子束中振动激发态CHD_3(v_1=1)反应物的比例,我们定量地研究了CH键伸缩振动激发对于该反应动力学和反应性的影响。在高碰撞能下(9.0kcal/mol),我们研究了CH键伸缩振动激发对于该反应的两个反应通道(HF+CD_3和DF+CHD_2)的反应性,产物内能态分布和角分布的影响。同时我们还详细研究了CH键伸缩振动激发对于HF+CD_3反应通道反应性的影响随碰撞能的变化。在该报告中,我们将详细讨论我们的研究结果。
The vibrationally excited reaction of F + CHD_3(v_1=1) is investigated using the crossed-beams and time-sliced velocity map imaging techniques.Detailed and quantitative information of the CH stretching excitation effects on the dynamics of the title reaction is extracted with the help of an accurate determination of the fraction of the excited CHD_3 reagent in the crossed-beam region.At a high collision energy of 9.0 kcal/mol,the CH stretching excitation effects on the reactivities,internal state distributions and angular distribution of products are studied carefully for both reaction channels:F+CHD_3(v_1=1)→HF+CD_3 and F + CHD_3(v_1=1) →HF+CHD_2.The collision energy dependence of the relative reactivity of the vibrationally excited reaction over the ground-state one is also studied for the HF + CD_3 channel.In this talk,a detailed discussion on the experimental results will be presented.
The vibrationally excited reaction of F + CHD_3(v_1=1) is investigated using the crossed-beams and time-sliced velocity map imaging techniques.Detailed and quantitative information of the CH stretching excitation effects on the dynamics of the title reaction is extracted with the help of an accurate determination of the fraction of the excited CHD_3 reagent in the crossed-beam region.At a high collision energy of 9.0 kcal/mol,the CH stretching excitation effects on the reactivities,internal state distributions and angular distribution of products are studied carefully for both reaction channels:F+CHD_3(v_1=1)→HF+CD_3 and F + CHD_3(v_1=1) →HF+CHD_2.The collision energy dependence of the relative reactivity of the vibrationally excited reaction over the ground-state one is also studied for the HF + CD_3 channel.In this talk,a detailed discussion on the experimental results will be presented.
引文
[1]Yang,J.;Zhang,D.;Jiang,B.;Dai,D.;Wu,G.;Zhang,D.;Yang,X.J.Phys.Chem.Lett.2014,5:1790.
[2]Yang,J.;Zhang,D.;Chen,Z.;Blauert,F.;Jiang,B.;Dai,D.;Wu,G.;Zhang,D.;Yang,X.J.Chem.Phys.2015,143:044316.
[2]Yang,J.;Zhang,D.;Chen,Z.;Blauert,F.;Jiang,B.;Dai,D.;Wu,G.;Zhang,D.;Yang,X.J.Chem.Phys.2015,143:044316.